Embodiments in accordance with the present invention encompass compositions encompassing a latent organo-ruthenium compound and a pyridine compound along with one or more monomers which undergo ring open metathesis polymerization (ROMP) when said composition is exposed to suitable actinic radiation to form a substantially transparent film. Surprisingly, the compositions are very stable at ambient conditions to temperatures up to 80° C. for several days and undergo mass polymerization when subject only to actinic radiation. Accordingly, compositions of this invention are useful in various opto-electronic applications, including as 3D printing materials, coatings, encapsulants, fillers, leveling agents, among others.

Methods for fabricating three-dimensional objects by 3D-inkjet printing technology are provided. The methods utilize a combination of curable materials that polymerize via ring-opening metathesis polymerization (ROMP) and curable materials that polymerize via free-radical polymerization (FRP) for fabricating the object. Systems suitable for performing these methods, kits containing modeling material formulations usable in the methods and objects obtained thereby are also provided.

The present invention provides a metal-oxo complex represented by the following general formula (1),

##STR00001## wherein in the general formula (1) above, “M” represents a molybdenum atom or a tungsten atom; “A” represents a carbon atom, a silicon atom, a germanium atom, a tin atom or a lead atom; X.sup.1 and X.sup.2 each independently represent a halogen atom; R.sup.1 to R.sup.5 each independently represent a hydrogen atom, a straight or branched chain alkyl group that is substituted or unsubstituted and has 1 to 20 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 20 carbon atoms; each of R.sup.1 to R.sup.3 may be bonded to one another to form a ring.

The present application is directed to a nanocomposite organo gel having a continuous polymeric network structure, wherein polymer chains are held together by ionic interaction between polymer chain ends, interparticle chain entanglements, layered silicate surface modifier, ionic salt, and layered silicate. The present application is also directed to methods of making and using the nanocomposite organo gel.

The invention relates to ring-opening metathesis polymerization (ROMP) reactions of making polymers suitable for the electronic industry. Particularly, the invention relates to novel polymers with low dielectric constant (D.sub.k) and low dielectric loss (D.sub.f) suited for smaller, lighter, higher speeds and higher frequency transmission electronic products. Such polymers can be used in a variety of materials and composites of the printed circuit board (PCB) industry.

A method of forming polymeric proppants in-situ during a fracturing operation. The method includes the steps of delivering reagents downhole and combining the reagents in a first mixing chamber to initiate polymerization; atomizing the combined reagents by passing them through an atomizer as they exit the first mixing chamber to form partially polymerized polymeric bodies; pumping water down a production casing; mixing the partially polymerized polymeric bodies and the water in a second mixing chamber; completing polymerization and forming solid polymeric proppants upon exiting the second mixing chamber; and passing the solid polymeric proppants through perforations in the casing and into fractures within the formation. A system for forming polymeric proppants in-situ during a fracturing operation and a method for forming solid polymeric proppants at the surface of a formation for use in a fracturing operation is also provided.

Disclosed herein are embodiments of a nanohoop-functionalized polymer and methods of making and using the same. In particular embodiments, polymer comprises one or more nanohoops that extend from the polymer backbone. Also disclosed herein are polymerizable nanohoop monomer embodiments that can be used to make the polymer embodiments disclosed herein.

A composition of matter including a crosslinked bottlebrush polymer, wherein the crosslinker units in the composition of matter are soluble with the bottlebrush polymer. In one example, the crosslinked bottlebrush polymer is tailored as a single phase (solvent free) elastomer useful in a capacitive pressure sensing device. A novel embodiment of the present invention further includes demonstration of a universal approach to form solvent-free bottlebrush polymer networks by photo-crosslinking mixtures of well-defined bottlebrush precursors and bis-benzophenone-based additives. This method has been proven effective with a wide variety of different side-chain chemistries.

A cyclic olefin polymer, a cyclic olefin polymer monomer, and an optical product using the foregoing cyclic olefin polymer are provided.

##STR00001##

The cyclic olefin polymer includes a repeat unit shown in Formula (1) and/or a repeat unit shown in Formula (2). In Formula (1), 0≤p, and q≤6; x≥0, and y≥0; 0≤p.sub.1, q.sub.1≤6, and p.sub.1 and q.sub.1 are not 0 at the same time; R.sub.1 to R.sub.12, R.sub.a, R.sub.b, R.sub.c, R.sub.d, R.sub.13, R.sub.14, R.sub.15, and R.sub.16 are separately and independently selected from a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an alkoxy group, a hydroxy group, an ester group, a cyano group, an amino group, a thiol group, and an atom or an atomic group that can replace the foregoing group; and any two, three, or four of R.sub.13, R.sub.14, R.sub.15, and R.sub.16 may be connected to form a cyclic structure.

The polymerization of cycloalkenamer is stopped by adding an alkyl vinyl derivative. Subsequently compound A is added, wherein compound A has at least one of the features i) or ii): i) at least one functional group or ii) at least one saturated or unsaturated aliphatic or aromatic heterocyclic ring having 3 to 14 ring atoms, wherein the ring atoms contain at least one carbon atom and at least one atom selected from oxygen, nitrogen and sulfur. A membrane filtration is subsequently carried out. This type of production produces polyalkenamers which are temperature-stable at 180° C.