C08G2261/418

Hydrogenated tetracyclododecene-based ring-opening polymer and method for producing same
10253137 · 2019-04-09 · ·

The present invention is: a hydrogenated tetracyclododecene-based ring-opening polymer comprising a repeating unit (A) derived from tetracyclododecene in a ratio of 40 wt % or more based on a total amount of repeating units, a ratio of meso diads in the repeating unit (A) being 65% or more; and a method for producing the same. By means of the present invention, provided are: a crystalline hydrogenated tetracyclododecene-based ring-opening polymer having a high melting point and a high glass transition temperature, and exhibiting excellent heat resistance and excellent processability even after forming due to melt forming; and a method for producing the same.

Catalyst-lean, microcapsule-based self-healing materials via ring-opening metathesis polymerization (ROMP)

A self-healing composite material includes a polymer matrix, microcapsules filled with a ring-opening metathesis-active monomer (e.g., norbornene, norbornene derivatives such as ethylidene norbornene, or cyclooctadiene), and polymeric particles comprised of a polymer that is soluble in the monomer with which the microcapsules are filled and having catalytic endgroups derived from an olefin metathesis catalyst, such as a Grubbs'-type catalyst. In some embodiments, the polymer having catalytic endgroups is synthesized via solution polymerization of a ring-opening metathesis-active monomer (e.g., norbornene, norbornene derivatives, or cyclooctadiene) in the presence of an olefin metathesis catalyst (e.g., Grubbs' 1st generation catalyst). The polymer having catalytic endgroups may then be processed via a grinding operation, for example, to prepare the small polymeric particles. In other embodiments, the polymeric particles are synthesized directly as microparticles (e.g., microspheres, granules, beads, etc.) utilizing an analogous suspension polymerization.

MOLECULAR SIEVES MEDIATED UNSATURATED HYDRCARBON SEPARATION AND RELATED COMPOSITIONS, MATERIALS, METHODS AND SYSTEMS

Described herein are compositions having an eight-membered monocyclic unsaturated hydrocarbon, methods and system to separate the eight-membered monocyclic unsaturated hydrocarbon at from a hydrocarbon mixture including additional nonlinear unsaturated C.sub.8H.sub.2m hydrocarbons with 4?m?8, by contacting the hydrocarbon mixture with a 10-ring pore molecular sieve having a sieving channel with a 10-ring sieving aperture with a minimum crystallographic free diameter greater than 3 ? and a ratio of the maximum crystallographic free diameter to the minimum crystallographic free diameter between 1 and 2, the molecular sieve having a T1/T2 ratio?20:1 wherein T1 is an element independently selected from Si and Ge, and T2 is an element independently selected from Al, B and Ga, the 10-ring pore molecular sieve further having a counterion selected from NH.sub.4.sup.+, Na.sup.+, K.sup.+ and Ca.sup.++.

PREPARATION OF METALLOCENE CONTAINING CATIONIC POLYMERS FOR ANION EXCHANGE APPLICATIONS
20190099723 · 2019-04-04 · ·

Chemically inert, mechanically tough, cationic metallo-polyelectrolytes designed as durable anion-exchange membranes (AEMs) via ring-opening metathesis polymerization (ROMP) of cobaltocenium-containing cyclooctene with triazole as the only linker group, followed by backbone hydrogenation to provide a new class of AEMs with a polyethylene-like framework and alkaline-stable cobaltocenium cation for ion transport, which exhibit excellent thermal, chemical and mechanical stability, as well as high ion conductivity.

Resin composition and resin molded article
10246582 · 2019-04-02 · ·

The present invention is a resin composition comprising a cycloolefin resin and at least two hydrogenated styrene-based thermoplastic elastomers, wherein a content of the cycloolefin resin is 50 to 90 wt % based on a total amount of the cycloolefin resin and the hydrogenated styrene-based thermoplastic elastomers, and a melt volume rate of the resin composition at 260 C. is higher than that of the cycloolefin resin at 260 C., and a resin formed article. One aspect of the invention provides a resin composition that exhibits excellent transparency, impact resistance and melt fluidity, as well as a resin formed article obtained by forming this resin composition. The resin formed article of the present invention is preferably used as a drug container, a medical instrument or the like, since it exhibits excellent transparency and impact resistance.

COPOLYMER AND COMPOSITION
20190092899 · 2019-03-28 · ·

A copolymer includes a repeating unit represented by Formula (I); and a repeating unit represented by Formula (II), in Formula (I), R.sup.1 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; R.sup.2 represents an alkyl group having 1 to 20 carbon atoms and having at least one fluorine atom as a substituent, or a group including Si(R.sup.a3)(R.sup.a4)O; L represents a divalent linking group as defined herein; and R.sup.a3 and R.sup.a4 each independently represent an alkyl group as defined herein, in Formula (II), R.sup.10 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; R.sup.11 and R.sup.12 each independently represent a hydrogen atom, a substituted or unsubstituted aliphatic hydrocarbon group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group; R.sup.11 and R.sup.12 may be linked to each other; and X.sup.1 represents a divalent linking group.

FABRICATION OF DENTAL APPLIANCES
20190090984 · 2019-03-28 ·

A dental appliance made of an olefin polymer is directly formed via rapid prototyping without the use of an intermediary physical mold. A polymer precursor solution includes one or more olefin-containing monomers and/or oligomers, an olefin polymerization catalyst, and a UV absorbing agent to limit penetration of the UV light through the polymer precursor solution. One or more reactions of the polymer precursor solution are modulated in response to UV light, and the polymer precursor solution may further include an inhibitor (quenching agent) configured to modulate those reactions. The polymer precursor solution can be deposited using UV-cured stereolithographic or 3D printing methods to form appliances exhibiting improved elongation at break characteristics and suitable stress resistance.

PROTEIN TRANSDUCTION DOMAINS MIMICS

The invention generally relates to synthetic mimics of cell penetrating peptides. More particularly, the invention relates to certain novel monomers, oligomers and polymers (e.g., co-polymers) that are useful for the preparation of synthetic mimics of cell penetrating peptides, their compositions, preparations and use.

Cyclic olefin resin compositions comprising functional elastomers

This invention relates to compositions and methods for improving the impact properties of polymer-matrix composites and to improving the adhesion of resin compositions to substrate materials. More particularly, the invention relates to compositions and methods for improving the impact properties of ring opening metathesis polymerization (ROMP) polymer-matrix composites and to improving the adhesion of ROMP compositions to substrate materials using adhesion promoters containing at least two isocyanate groups and functional elastomers comprising a maleic anhydride grafted styrene-ethylene/butylene-styrene hydrogenated copolymer in a resin composition. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.

FLEXIBLE COLOR FILTER

The present invention relates to a flexible color filter. More specifically, the present invention is characterized in that a separation layer, a protective layer, a black matrix layer and a pixel layer are sequentially laminated, wherein the protective layer comprises one or more polymers selected from polymers represented by chemical formula 1 or chemical formula 2.