A method for providing an image on or in a substrate is provided, and comprises applying to the substrate: (i) ammonium octamolybdate (AOM) in the form of the alpha-isomer, obtainable by thermal decomposition of ammonium molybdate at 215-225° C. for 180 mins, and which has an anhydrous loss on ignition in the range 8.00 to 8.80; or (ii) a composition comprising ammonium octamolybdate as defined in (i), and a binder; followed by irradiation. Also provided are liquid ink compositions comprising AOM as defined above, and a binder.

A method for providing an image on or in a substrate is provided, and comprises applying to the substrate: (i) ammonium octamolybdate (AOM) in the form of the alpha-isomer, obtainable by thermal decomposition of ammonium molybdate at 215-225° C. for 180 mins, and which has an anhydrous loss on ignition in the range 8.00 to 8.80; or (ii) a composition comprising ammonium octamolybdate as defined in (i), and a binder; followed by irradiation. Also provided are liquid ink compositions comprising AOM as defined above, and a binder.

The present invention relates to formulations comprising at least one organic semiconductor and at least one organic solvent, characterized in that the formulation contains less than 10,000 particles per liter formulation having an average size in the range from 0.1 to 20 μm, to their use for the preparation of electronic devices, to methods for preparing electronic devices using the formulations of the present invention, and to electronic devices prepared from such methods and formulations.

The present invention relates to [1] a process for producing pigment-containing modified polymer particles, including the step of reacting pigment-containing polymer particles (A) containing a functional group and a compound (B) containing a reactive group capable of reacting with the functional group of the polymer particles (A) in a medium under such a condition that a ratio [(B)/(A)] of total moles of the reactive group of the compound (B) to total moles of the functional group of the polymer particles (A) is from 0.10 to 0.62; [2] a pigment water dispersion including an aqueous medium and the modified polymer particles produced by the aforementioned process which are dispersed in the aqueous medium; and [3] an ink including the aforementioned pigment water dispersion and an organic solvent. The modified polymer particles are free from formation of coarse particles upon production of pigment particles, so that an ink obtained by using the modified polymer particles can be prevented from suffering from increase in viscosity thereof when the ink is being concentrated by evaporation of water from the ink, and is excellent in rub fastness when printed on a low-water absorbing recording medium.

The present invention relates to [1] a process for producing pigment-containing modified polymer particles, including the step of reacting pigment-containing polymer particles (A) containing a functional group and a compound (B) containing a reactive group capable of reacting with the functional group of the polymer particles (A) in a medium under such a condition that a ratio [(B)/(A)] of total moles of the reactive group of the compound (B) to total moles of the functional group of the polymer particles (A) is from 0.10 to 0.62; [2] a pigment water dispersion including an aqueous medium and the modified polymer particles produced by the aforementioned process which are dispersed in the aqueous medium; and [3] an ink including the aforementioned pigment water dispersion and an organic solvent. The modified polymer particles are free from formation of coarse particles upon production of pigment particles, so that an ink obtained by using the modified polymer particles can be prevented from suffering from increase in viscosity thereof when the ink is being concentrated by evaporation of water from the ink, and is excellent in rub fastness when printed on a low-water absorbing recording medium.

An ink composition for high-speed screen printing, includes a solvent with a boiling point of not less than 170° C. at not less than 70 wt % of the total solvent, and a prepolymer or polymer with a weight-average molecular weight of not less than 2000 at not less than 7 wt % with respect to the total ink composition, and having a viscosity of not less than 6 Pa.Math.s and less than 30 Pa.Math.s as measured with a BH-type rotating viscosimeter at 25° C., and a thixotropic index (TI value) of 2.0 to 8.0, the measured flow radius value of 14.0 to 24.0 mm after 1 minute from the start of measurement by a flow property measuring method using a spread meter at 25° C. according to JIS K5701-1:2000.

An ink composition for high-speed screen printing, includes a solvent with a boiling point of not less than 170° C. at not less than 70 wt % of the total solvent, and a prepolymer or polymer with a weight-average molecular weight of not less than 2000 at not less than 7 wt % with respect to the total ink composition, and having a viscosity of not less than 6 Pa.Math.s and less than 30 Pa.Math.s as measured with a BH-type rotating viscosimeter at 25° C., and a thixotropic index (TI value) of 2.0 to 8.0, the measured flow radius value of 14.0 to 24.0 mm after 1 minute from the start of measurement by a flow property measuring method using a spread meter at 25° C. according to JIS K5701-1:2000.

A method of synthesis of two-dimensional (2D) nanoflakes comprises the cutting of prefabricated nanoparticles. The method allows high control over the shape, size and composition of the 2D nanoflakes, and can be used to produce material with uniform properties in large quantities. Van der Waals heterostructure devices are prepared by fabricating nanoparticles, chemically cutting the nanoparticles to form nanoflakes, dispersing the nanoflakes in a solvent to form an ink, and depositing the ink to form a thin film.

A method of synthesis of two-dimensional (2D) nanoflakes comprises the cutting of prefabricated nanoparticles. The method allows high control over the shape, size and composition of the 2D nanoflakes, and can be used to produce material with uniform properties in large quantities. Van der Waals heterostructure devices are prepared by fabricating nanoparticles, chemically cutting the nanoparticles to form nanoflakes, dispersing the nanoflakes in a solvent to form an ink, and depositing the ink to form a thin film.

Graphene ink compositions comprising nitrocellulose and related methods of use comprising either thermal or photonic annealing.