A method is used to prepare silver nanoparticles or copper nanoparticles in the form of a silver nanoparticle cellulosic polymeric composite or a copper nanoparticle cellulose polymeric composite, respectively. A cellulosic polymer, organic solvent having a boiling point at atmospheric pressure of 100 C. to 500 C. and a Hansen parameter (.sub.T.sup.Polymer) equal to or greater than that of the cellulosic polymer, ascorbic acid, and a nitrogenous base are mixed to form a premix solution. At room temperature or upon heating the premix solution to a temperature of at least 40 C., a solution of reducible silver ions or reducible copper ions is added. The resulting silver or copper nanoparticle composite is cooled, isolated, and re-dispersed in an organic solvent, providing a non-aqueous silver-containing or copper-containing dispersion that can be disposed on a substrate to form an article.

The invention relates to a substrate intended in use to contact a fouling agent, the substrate including a coating comprising polysaccharide, which coating serves to reduce or prevent fouling of the substrate caused by contact from the fouling agent, in comparison to an equivalent uncoated substrate. The invention also relates to the anti-fouling coating, to apparatus comprising such coating and to related methods of reducing or preventing fouling of a substrate intended in use to contact a fouling agent.

The invention relates to a substrate intended in use to contact a fouling agent, the substrate including a coating comprising polysaccharide, which coating serves to reduce or prevent fouling of the substrate caused by contact from the fouling agent, in comparison to an equivalent uncoated substrate. The invention also relates to the anti-fouling coating, to apparatus comprising such coating and to related methods of reducing or preventing fouling of a substrate intended in use to contact a fouling agent.

A method is designed to prepare foamed, opacifying elements each having a target light blocking value (LBV.sub.T) of at least 3, using a textile fabric substrate with a light blocking value (LBV.sub.S). The LBV.sub.T-S difference is calculated; a foamable aqueous composition is chosen; a dry coating weight for the foamable aqueous composition (when foamed) is determined to form a single dry opacifying layer that is foamed, dried, and densified to provide a dry thickness at least 20% less than the original dry thickness. The single dry opacifying layer a has light blocking value that is equal to LBV.sub.T-S, 15%. The desired foamable aqueous composition can be chosen from a set of similar compositions to achieve the desired LBV.sub.T with the noted textile fabric substrate using suitable mathematical formula relating dry coating weight to light blocking value and a suitable data processor.

A method is designed to prepare foamed, opacifying elements each having a target light blocking value (LBV.sub.T) of at least 3, using a textile fabric substrate with a light blocking value (LBV.sub.S). The LBV.sub.T-S difference is calculated; a foamable aqueous composition is chosen; a dry coating weight for the foamable aqueous composition (when foamed) is determined to form a single dry opacifying layer that is foamed, dried, and densified to provide a dry thickness at least 20% less than the original dry thickness. The single dry opacifying layer a has light blocking value that is equal to LBV.sub.T-S, 15%. The desired foamable aqueous composition can be chosen from a set of similar compositions to achieve the desired LBV.sub.T with the noted textile fabric substrate using suitable mathematical formula relating dry coating weight to light blocking value and a suitable data processor.

The invention is directed to plastisol coating formulations for agricultural uses. The plastisol-coated agrochemicals comprise a coating formed from a plastisol formulation, wherein the plastisol formulation comprises a suspension of polymer particles in a liquid plasticizer, and a solid agrochemical, wherein the coating is applied to the solid agrochemical and cured to form a film thereupon.

The invention is directed to plastisol coating formulations for agricultural uses. The plastisol-coated agrochemicals comprise a coating formed from a plastisol formulation, wherein the plastisol formulation comprises a suspension of polymer particles in a liquid plasticizer, and a solid agrochemical, wherein the coating is applied to the solid agrochemical and cured to form a film thereupon.

A method is used to prepare silver nanoparticles or copper nanoparticles in the form of a silver nanoparticle cellulosic polymeric composite or a copper nanoparticle cellulose polymeric composite, respectively. A cellulosic polymer, organic solvent having a boiling point at atmospheric pressure of 100 C. to 500 C. and a Hansen parameter (.sub.T.sup.Polymer) equal to or greater than that of the cellulosic polymer, ascorbic acid, and a nitrogenous base are mixed to form a premix solution. At room temperature or upon heating the premix solution to a temperature of at least 40 C., a solution of reducible silver ions or reducible copper ions is added. The resulting silver or copper nanoparticle composite is cooled, isolated, and re-dispersed in an organic solvent, providing a non-aqueous silver-containing or copper-containing dispersion that can be disposed on a substrate to form an article.

Water vapor transport membranes for ERV and other water vapor transport applications are provided. The membranes include a substrate and an air impermeable selective layer coated on the substrate, the selective layer including a cellulose derivative and a sulfonated polyaryletherketone. In some embodiments the sulfonated polyaryletherketone is in a cation form and/or the selective layer includes sPEEK and CA in an sPEEK:CA (wt.:wt.) ratio in the range of about 7:3 to 2:3. Methods for making such membranes are provided. The methods include applying a coating solution/dispersion to a substrate and allowing the coating solution/dispersion to dry to form an air impermeable selective layer on the substrate, the coating solution/dispersion including a cellulose derivative and a sulfonated polyarylether ketone. In some embodiments the sulfonated polyaryletherketone is in a cation form and/or the coating solution/dispersion includes sPEEK and CA in an sPEEK:CA (wt.:wt.) ratio in the range of about 7:3 to 2:3.

Water vapor transport membranes for ERV and other water vapor transport applications are provided. The membranes include a substrate and an air impermeable selective layer coated on the substrate, the selective layer including a cellulose derivative and a sulfonated polyaryletherketone. In some embodiments the sulfonated polyaryletherketone is in a cation form and/or the selective layer includes sPEEK and CA in an sPEEK:CA (wt.:wt.) ratio in the range of about 7:3 to 2:3. Methods for making such membranes are provided. The methods include applying a coating solution/dispersion to a substrate and allowing the coating solution/dispersion to dry to form an air impermeable selective layer on the substrate, the coating solution/dispersion including a cellulose derivative and a sulfonated polyarylether ketone. In some embodiments the sulfonated polyaryletherketone is in a cation form and/or the coating solution/dispersion includes sPEEK and CA in an sPEEK:CA (wt.:wt.) ratio in the range of about 7:3 to 2:3.