Sol-gel coating formulations including metal oxide particles such as aluminum oxide, calcium oxide, zinc oxide, magnesium oxide, and molybdenum oxide embedded in a hybrid polymer matrix based on a reacted form of a resin composition containing a tetraalkylorthosilicate, an aminoalkylsilane, a dialkoxysilane, and a silanol terminated polydimethylsiloxane. The sol-gel coating formulations are suitable for applications such as anticorrosive protective coatings of metal substrates (e.g. mild steel). These anticorrosive coated metal substrates are evaluated on their hydrophobicity (water contact angle), surface roughness, mechanical strength (e.g. hardness), adhesiveness to the substrate (e.g. critical load), and anticorrosiveness upon exposure to a saline solution (e.g. impedance value).

Sol-gel coating formulations including metal oxide particles such as aluminum oxide, calcium oxide, zinc oxide, magnesium oxide, and molybdenum oxide embedded in a hybrid polymer matrix based on a reacted form of a resin composition containing a tetraalkylorthosilicate, an aminoalkylsilane, a dialkoxysilane, and a silanol terminated polydimethylsiloxane. The sol-gel coating formulations are suitable for applications such as anticorrosive protective coatings of metal substrates (e.g. mild steel). These anticorrosive coated metal substrates are evaluated on their hydrophobicity (water contact angle), surface roughness, mechanical strength (e.g. hardness), adhesiveness to the substrate (e.g. critical load), and anticorrosiveness upon exposure to a saline solution (e.g. impedance value).

A gel is provided which is the condensation reaction product of the following composition: (i) at least one condensation curable silyl terminated polymer having at least one hydrolysable and/or hydroxyl functional group(s) per molecule; (ii) a cross-linker selected from the group of a silicone, an organic polymer, a silane or a disilane molecule which contains at least two hydrolysable groups per molecule; and (iii) a condensation catalyst selected from the group of titanates, zirconates or tin (II). The molar ratio of hydroxyl and/or hydrolysable groups in polymer (i) to hydrolysable groups from component (ii) is between 0.5:1 and 1:1 using a monosilane cross-linker or 0.75:1 to 3:1 using disilanes, and the molar ratio of M-OR or tin (II) functions to the hydroxyl and/or hydrolysable group(s) in polymer (i) is comprised between 0.01:1 and 0.5:1, where M is titanium or zirconium. The composition, and uses for the gel are also disclosed.

A gel is provided which is the condensation reaction product of the following composition: (i) at least one condensation curable silyl terminated polymer having at least one hydrolysable and/or hydroxyl functional group(s) per molecule; (ii) a cross-linker selected from the group of a silicone, an organic polymer, a silane or a disilane molecule which contains at least two hydrolysable groups per molecule; and (iii) a condensation catalyst selected from the group of titanates, zirconates or tin (II). The molar ratio of hydroxyl and/or hydrolysable groups in polymer (i) to hydrolysable groups from component (ii) is between 0.5:1 and 1:1 using a monosilane cross-linker or 0.75:1 to 3:1 using disilanes, and the molar ratio of M-OR or tin (II) functions to the hydroxyl and/or hydrolysable group(s) in polymer (i) is comprised between 0.01:1 and 0.5:1, where M is titanium or zirconium. The composition, and uses for the gel are also disclosed.

A gel is provided which is the condensation reaction product of the following composition: (i) at least one condensation curable silyl terminated polymer having at least one hydrolysable and/or hydroxyl functional group(s) per molecule; (ii) a cross-linker selected from the group of a silicone, an organic polymer, a silane or a disilane molecule which contains at least two hydrolysable groups per molecule; and (iii) a condensation catalyst selected from the group of titanates, zirconates or tin (II). The molar ratio of hydroxyl and/or hydrolysable groups in polymer (i) to hydrolysable groups from component (ii) is between 0.5:1 and 1:1 using a monosilane cross-linker or 0.75:1 to 3:1 using disilanes, and the molar ratio of M-OR or tin (II) functions to the hydroxyl and/or hydrolysable group(s) in polymer (i) is comprised between 0.01:1 and 0.5:1, where M is titanium or zirconium. The composition, and uses for the gel are also disclosed.

A composition crosslinkable by condensation reaction and producible using (A) organopolysiloxanes of the formula (R.sup.2O).sub.3-aSiR.sup.1.sub.aO(SiR.sub.2O).sub.nSiR.sup.1.sub.a(OR.sup.2).sub.3-a (I), (B1) silanes of the formula R.sup.3.sub.4-b(R.sup.4O).sub.bSi (II), and optionally (B2) silicon compounds consisting of units of the formula R.sup.7.sub.c(R.sup.8O).sub.dSiO.sub.(4-c-d)/2 (III). The composition contains organosilicon compounds having a molecular weight of less than or equal to 195 g/mol maximally in amounts of less than 0.5 wt%, based on organopolysiloxane (A).

A composition crosslinkable by condensation reaction and producible using (A) organopolysiloxanes of the formula (R.sup.2O).sub.3-aSiR.sup.1.sub.aO(SiR.sub.2O).sub.nSiR.sup.1.sub.a(OR.sup.2).sub.3-a (I), (B1) silanes of the formula R.sup.3.sub.4-b(R.sup.4O).sub.bSi (II), and optionally (B2) silicon compounds consisting of units of the formula R.sup.7.sub.c(R.sup.8O).sub.dSiO.sub.(4-c-d)/2 (III). The composition contains organosilicon compounds having a molecular weight of less than or equal to 195 g/mol maximally in amounts of less than 0.5 wt%, based on organopolysiloxane (A).

There are disclosed methods for producing curable elastomeric compositions comprising carbon black particles, as well as their corresponding cured products. Such compositions, once cured, can be used for the preparation of numerous articles of wide industrial applicability.

There are disclosed methods for producing curable elastomeric compositions comprising carbon black particles, as well as their corresponding cured products. Such compositions, once cured, can be used for the preparation of numerous articles of wide industrial applicability.

A polysiloxane-polyester block copolymer is provided, which comprises: (i) a siloxane resin block comprising: a siloxane unit represented by the formula: R.sup.1SiO.sub.3/2, wherein R.sub.1 is a monovalent hydrocarbon group, and comprising optionally a siloxane unit represented by the formula: SiO.sub.4/2; (ii) a siloxane linear block represented by the formula: (R.sup.2.sub.2SiO.sub.2/2).sub.n, wherein each R.sup.2 is independently a monovalent hydrocarbon group, and “n” is a positive number of at least 5; and (iii) a polyester block. The polysiloxane-polyester block copolymer can be used for a protective coating on a substrate which is made of aluminum, stainless steel, iron, plastics or glass to provide durable heat-resistance, hot hardness, release and anti-graffiti properties.