Patent classifications
G03G9/097
TONER
A toner including a toner particle containing a binder resin and an ester compound, wherein the binder resin contains a styrene-acrylic-based resin, the styrene-acrylic-based resin contains a specific unit, the ester compound has a specific structure, and a molar ratio of the specific unit to the ester compound is 0.5 to 1.5.
Image forming apparatus and image forming method
An image forming apparatus is provided. The image forming apparatus includes an image bearer and a cleaning blade configured to remove toner particles remaining on the image bearer. The cleaning blade includes an elastic member in contact with a surface of the image bearer to remove the toner particles. The elastic member has a Martens hardness of from 3 to 8 N/mm.sup.2 when measured by a nanoindentation method with a load of 1 μN. The toner particles comprise toner base particles and an external additive, and the external additive comprise silica particles. A liberation ratio (Xs) of the silica particles liberated from the toner particles is from 40% to 75% when measured by an ultrasonic vibration method. A proportion (R70) of the silica particles having a volume-based particle diameter of 70 nm or more in the silica particles liberated from the toner particles is from 70% to 90% by number.
TONER
A toner having high rub resistance is provided. A toner including a toner particle containing a binder resin and a calcium carbonate particle, wherein in X-ray diffractometry of the toner particle by CuKα radiation, when the Bragg angle is defined as θ, (i) the calcium carbonate particle has peaks at 2θ of 26.5°±0.5° and 29.5°±0.5°, (ii) a crystallite diameter of crystals thereof attributed to 2θ=29.5°±0.5° is 10 nm or more and 45 nm or less, and (iii) the ratio (a/b) of a peak intensity “a” at 2θ=26.5°±0.5° to a peak intensity “b” at 20θ=29.5°±0.5° is 0.15 or more and 0.24 or less.
TONER FORMULATIONS HAVING IMPROVED TONER USAGE EFFICIENCY
A toner composition having improved toner usage efficiency, wherein toner particles having an average size range of 1-25 μm may be mixed with an extra particulate additive package including a first small silica surface treated with both a silane and an aminosilane having a primary particle size of about 5 nm-20 nm, a second fumed silica having a primary particle size of 30 nm-60 nm, a third silica having a primary particle size of about 70 nm-120 nm, an electro-conductive titania having a primary particle size of 30 nm-60 nm and an acicular titania having a size of about 1.6 μm to 1.7 μm in length and about 130 nm in diameter. An alternative embodiment of the extra particulate additive package does not include a third silica having a primary particle size of about 70 nm-120 nm.
TONER
A toner including a toner particle which contains: a resin component containing a binder resin; and an inorganic fine particle, the inorganic fine particle is at least one inorganic fine particle selected from the group consisting of (i) a particle containing CaCO.sub.3, (ii) a particle containing BaSO.sub.4, (iii) a particle containing Mg.sub.3Si.sub.4O.sub.10(OH).sub.2, and (iv) a particle containing Al.sub.2Si.sub.2O.sub.5(OH).sub.4, a number average particle diameter Dc of a primary particle of the inorganic fine particle is 100 nm or more and 1000 nm or less, when a cross section of the toner particle is observed, an inorganic fine particle domain A having a dispersion diameter of 2.0 times or more of Dc is present in the cross section, and the inorganic fine particle and the inorganic fine particle domain A occupy a specific percentage of an area in the cross section of the toner particle.
TONER HAVING EXTRA PARTICULAR ADDITIVES
A toner composition having improved toner usage efficiency, wherein toner particles having an average size range of 1-25 μm may be mixed with an extra particulate additive package including a first small silica surface treated with both a silane and an aminosilane having a primary particle size of about 5 nm-20 nm, a second fumed silica having a primary particle size of 30 nm-60 nm, a third silica having a primary particle size of about 70 nm-120 nm, an electro-conductive titania having a primary particle size of 30 nm-60 nm and an acicular titania having a size of about 1.6 μm to 1.7 μm in length and about 130 nm in diameter. An alternative embodiment of the extra particulate additive package does not include a third silica having a primary particle size of about 70 nm-120 nm.
EXTERNAL ADDITIVE FOR TONER, TONER AND IMAGE FORMING APPARATUS
An external additive for toner, wherein the external additive is an organosilicon polymer particle, and defining A (nm) as the number-average particle diameter of primary particles of the external additive measured using a scanning electron microscope, and defining B (nm) as the number-average particle diameter of the external additive measured in accordance with a centrifugal sedimentation method, the A and the B satisfy a following Expression (1):
1.5≤B/A≤3.0 (1).
Toner and method for producing toner
A toner comprising a toner particle that contains a binder resin and fine particles A at the surface of the toner particle, wherein the fine particles A are organosilicon polymer fine particles, the organosilicon polymer fine particles have a number-average primary particle diameter of 30 nm to 500 nm, the organosilicon polymer fine particles have an attachment index for a polycarbonate film of not more than 3.5, the organosilicon polymer fine particles penetrate into the toner particle in a penetration depth b (nm), and protrude from the toner particle in a protrusion height c (nm), and b and c satisfy 0.05≤b/(b+c)≤0.40.
EXTERNAL ADDITIVE PARTICLES, TONER, AND METHOD FOR PRODUCING EXTERNAL ADDITIVE PARTICLES
External additive particles including a polymer containing a sulfur atom and a nitrogen atom, wherein the polymer includes a vinyl polymer moiety and a siloxane moiety, relative to a total number of carbon atoms, oxygen atoms, and silicon atoms constituting the external additive particles, a ratio of a number of the silicon atoms constituting the external additive particles is 4.0% or more and 25.0% or less, and in surfaces of the external additive particles analyzed by X-ray photoelectron spectroscopy, relative to a total number of carbon atoms, nitrogen atoms, oxygen atoms, silicon atoms, and sulfur atoms, a ratio of a number of the nitrogen atoms is 0.40% or more and 2.50% or less, and a ratio of a number of the sulfur atoms is 0.05% or more and 0.25% or less.
TONER
The toner is a toner including a toner particle comprising a binder resin, a crystalline material, wherein, when a ratio of an area occupied by the crystalline material in a toner surface observed with a scanning electron microscope after ruthenium-staining the toner under a specific condition (1) is represented by S.sub.1 (%), a ratio of an area occupied by the crystalline material in the toner surface observed with the scanning electron microscope after ruthenium-staining the toner under a condition (2) is represented by S.sub.2 (%), and a dispersion diameter of a plurality of domains formed of the crystalline material on the toner surface observed with the scanning electron microscope after the ruthenium-staining the toner under the condition (2) is represented by R.sub.2 (nm), the following expressions (1), (2), and (3) are satisfied.