An object of the present invention is to provide a catalyst capable of improving the selectivity of unsaturated aldehydes and unsaturated carboxylic acids, and a catalyst containing molybdenum, antimony, bismuth, and iron, wherein an atom ratio of the antimony to the molybdenum on a surface of the catalyst is greater than an atom ratio of the antimony to the molybdenum in the entire catalyst is provided.

An object of the present invention is to provide a catalyst capable of improving the selectivity of unsaturated aldehydes and unsaturated carboxylic acids, and a catalyst containing molybdenum, antimony, bismuth, and iron, wherein an atom ratio of the antimony to the molybdenum on a surface of the catalyst is greater than an atom ratio of the antimony to the molybdenum in the entire catalyst is provided.

A method of converting one or more alkanes to one or more alkenes that includes a) providing a first stream containing one or more alkanes and oxygen to an oxidative dehydrogenation reactor; b) converting at least a portion of the one or more alkanes to one or more alkenes in the oxidative dehydrogenation reactor to provide a second stream exiting the oxidative dehydrogenation reactor containing one or more alkanes, one or more alkenes, oxygen, carbon monoxide and optionally acetylene; and c) providing the second stream to a second reactor containing a catalyst that includes a group 11 metal to convert a least a portion of the carbon monoxide to carbon dioxide and reacting the acetylene.

A method of converting one or more alkanes to one or more alkenes that includes a) providing a first stream containing one or more alkanes and oxygen to an oxidative dehydrogenation reactor; b) converting at least a portion of the one or more alkanes to one or more alkenes in the oxidative dehydrogenation reactor to provide a second stream exiting the oxidative dehydrogenation reactor containing one or more alkanes, one or more alkenes, oxygen, carbon monoxide and optionally acetylene; and c) providing the second stream to a second reactor containing a catalyst that includes a group 11 metal to convert a least a portion of the carbon monoxide to carbon dioxide and reacting the acetylene.

Provided is a composition for catalyst production which is used in the production of a catalyst for gas phase catalytic oxidation reaction or a catalyst for gas phase catalytic ammoxidation reaction, wherein the composition for catalyst production is an aqueous solution containing a niobium compound and hydrogen peroxide and optionally containing an organic acid, a molar ratio (organic acid/Nb) of a concentration of the organic acid to a Nb concentration is 0.00 or more and 2.00 or less, and a molar ratio (hydrogen peroxide/Nb) of a concentration of the hydrogen peroxide to a Nb concentration is 0.01 or more and 50 or less.

Provided is a composition for catalyst production which is used in the production of a catalyst for gas phase catalytic oxidation reaction or a catalyst for gas phase catalytic ammoxidation reaction, wherein the composition for catalyst production is an aqueous solution containing a niobium compound and hydrogen peroxide and optionally containing an organic acid, a molar ratio (organic acid/Nb) of a concentration of the organic acid to a Nb concentration is 0.00 or more and 2.00 or less, and a molar ratio (hydrogen peroxide/Nb) of a concentration of the hydrogen peroxide to a Nb concentration is 0.01 or more and 50 or less.

The present disclosure relates to an ammoxidation catalyst for propylene, a manufacturing method of the same, and an ammoxidation method of propylene using the same. Specifically, in one embodiment of the present disclosure, there is provided a catalyst having a structure in which a metal oxide is supported on a silica support having a narrow particle size distribution, and excellent wear resistance.

The present disclosure relates to an ammoxidation catalyst for propylene, a manufacturing method of the same, and an ammoxidation method of propylene using the same. Specifically, in one embodiment of the present disclosure, there is provided a catalyst having a structure in which a metal oxide is supported on a silica support having a narrow particle size distribution, and excellent wear resistance.

Provided is a method of preparing a pure M1 phase MoVTeNb-oxide catalyst with a high specific surface area, including S1) mixing and dissolving a molybdenum-containing compound, a vanadium-containing compound, a tellurium-containing compound, a niobium-containing compound and a protective agent to obtain a precursor-protective agent mixed solution, in which the protective agent is a surfactant or a small molecule organic acid and a salt thereof; S2) subjecting the precursor-protective agent mixed solution to a hydrothermal reaction to separate out a solid; S3) calcining the solid in an air atmosphere, followed by calcining the same in an inert gas, and then performing a hydrogen peroxide purification treatment to obtain a pure M1 phase MoVTeNb-oxide catalyst. This catalyst exhibits an excellent conversion rate, selectivity, space time yield and stability in the oxidative dehydrogenation reaction of ethane for preparing ethylene.

Provided is a method of preparing a pure M1 phase MoVTeNb-oxide catalyst with a high specific surface area, including S1) mixing and dissolving a molybdenum-containing compound, a vanadium-containing compound, a tellurium-containing compound, a niobium-containing compound and a protective agent to obtain a precursor-protective agent mixed solution, in which the protective agent is a surfactant or a small molecule organic acid and a salt thereof; S2) subjecting the precursor-protective agent mixed solution to a hydrothermal reaction to separate out a solid; S3) calcining the solid in an air atmosphere, followed by calcining the same in an inert gas, and then performing a hydrogen peroxide purification treatment to obtain a pure M1 phase MoVTeNb-oxide catalyst. This catalyst exhibits an excellent conversion rate, selectivity, space time yield and stability in the oxidative dehydrogenation reaction of ethane for preparing ethylene.