B01D2255/20723

Method for production of sulfur and sulfuric acid

A process plant and a process for production of sulfur from a feedstock gas including from 15% to 100 vol % H.sub.2S and a stream of sulfuric acid, the process including a) providing a Claus reaction furnace feed stream with a substoichiometric amount of oxygen, b) directing to a Claus reaction furnace operating at elevated temperature, c) cooling to provide a cooled Claus converter feed gas, d) directing to contact a material catalytically active in the Claus reaction, e) withdrawing a Claus tail gas and elementary sulfur, f) directing a stream comprising said Claus tail gas to a Claus tail gas treatment, wherein sulfuric acid directed to said Claus reaction furnace is in the form of droplets with 90% of the mass of the droplets having a diameter below 500 μm, with the associated benefit of such a process efficiently converting all liquid H.sub.2SO.sub.4 to gaseous H.sub.2SO.sub.4 and further to SO.sub.2.

Denitration device, heat recovery steam generator having the same, gas turbine combined cycle power plant and method of denitration

A denitration device comprising a duct (22) that leads and distributes exhaust gas from a turbine (56) of a gas turbine (50) including a compressor (52) and the turbine (56), an ammonia injection grid (24) that sprays, into the duct (22), an mixed gas in which ammonia gas and dilution air are mixed with each other, and a denitration catalyst (26) that is installed on a downstream side of flow of the exhaust gas of the ammonia injection grid in the duct (22), and there is provided an air bleeding line (76) that is connected to a low compression portion of the compressor (52) of the gas turbine (50) and supplies air bled of the compressor (52) into the ammonia injection grid (24) as the dilution air.

Thermal oxidation of volatile organic compounds using a catalyst layer within a waste heat recovery unit

Methods and systems for treating volatile organic compounds (VOCs) generated in a hydrocarbon treating process are disclosed. An effluent stream containing the VOCs, as well as carbon dioxide (CO.sub.2) is combined with hot exhaust gas from a turbine and provided to a waste heat recovery unit (WHRU). The WHRU is adapted to contain a catalyst bed containing oxidation catalyst capable of effecting the oxidation of the VOCs. The temperature of the catalyzing reaction can be tailored based on the position of the catalyst bed within the temperature gradient of the WHRU. The methods and systems described herein solve the problem of effecting the removal of VOCs from the effluent. Heating the CO.sub.2-containing effluent in the WHRU also lend buoyancy to the effluent, thereby facilitating its dispersal upon release.

PGM catalyst coupled with a non-PGM catalyst with HC oxidation capability
11517854 · 2022-12-06 · ·

The present invention relates to a diesel oxidation catalyst comprising a substrate and a wash-coat comprising a first layer and a second layer, wherein the substrate has a substrate length, a front end and a rear end, the washcoat comprising the first layer comprising a first metal oxide and comprising a platinum group metal supported on a metal oxide support material; the second layer comprising a second metal oxide and comprising one or more of an oxidic compound of vanadium, an oxidic compound of tungsten and a zeolitic material comprising one or more of Fe and Cu; wherein the first layer is at least partially disposed directly on the substrate, or is at least partially disposed directly on an intermediate layer which is disposed directly on the substrate over the entire length of the substrate, on x % of the length of the substrate from the front end of the substrate, and wherein the second layer is at least partially disposed directly on the substrate, or is at least partially disposed directly on the intermediate layer which is disposed directly on the substrate over the entire length of the substrate, on y % of the length of the substrate from the rear end of the substrate, wherein x is in the range of from 25 to 75 and y is in the range of from 25 to 75 and wherein x+y is in the range of from 95 to 105, wherein the intermediate layer comprises alumina.

Aftertreatment system, dual fuel system, and dual fuel apparatus

Systems and apparatuses include a selective catalytic reduction system structured to receive exhaust gases from a dual fuel engine system and include a diesel exhaust fluid dosing unit, an ammonia slip catalyst positioned directly downstream of the selective catalytic reduction catalyst, an oxidation catalyst positioned directly downstream of the ammonia slip catalyst, and one or more processing circuits. The circuits receive a system out NOx value, a space velocity, an ammonia to NOx ratio, an exhaust temperature, a substitution rate, and a conversion efficiency target. The circuits determine a conversion efficiency differential, adjust the substitution rate based on the system out NOx value, adjust the ammonia to NOx ratio based on the space velocity, the ammonia to NOx ratio, the exhaust temperature, the substitution rate, the conversion efficiency target, and the conversion efficiency differential, and determine a diesel exhaust fluid dosing rate for the diesel exhaust fluid dosing unit.

EXHAUST GAS SAMPLE COLLECTOR AND MIXER FOR AFTERTREATMENT SYSTEM
20220381170 · 2022-12-01 ·

An exhaust gas treatment system includes an exhaust gas pathway configured to receive exhaust gas from an internal combustion engine. The exhaust gas treatment system further includes a treatment element configured to reduce an emissions component of the exhaust gas, and a sample collector positioned within the exhaust gas pathway downstream of the treatment element. The sample collector includes a plurality of inlet openings spaced about a periphery of the exhaust gas pathway and configured to receive a sample of exhaust gas from the exhaust gas pathway, and an outlet in fluid communication with the plurality of inlet openings. A sensor located at the outlet of the sample collector is configured to measure a characteristic of the sample.

Exhaust treatment system for a lean burn engine

The present invention relates generally to the field of exhaust treatment systems for purifying exhaust gas discharged from a lean burn engine. The exhaust treatment system comprises a Diesel Oxidation Catalyst (DOC), a Catalyzed Soot Filter (CSF), a reductant injector, an AEI zeolite based Selective Catalyzed Reduction (SCR) catalyst and an Ammonia Oxidation Catalyst (AMOX) downstream to the AEI zeolite based SCR catalyst.

INTEGRATED FILTER MATERIAL AND PREPARATION METHOD AND APPLICATION THEREOF

An integrated filter material, a preparation method and an application. The filter material is composed of a commercial dust removal filter material and a catalyst that is grown on the filter material and that has a function of simultaneously decomposing nitrogen oxides and dioxins. In the preparation method, a precursor solution of manganese and cerium oxides is impregnated on the filter material, and manganese and cerium oxides are grown on the filter material by means of a chemical reaction; and vanadium oxychloride is used as a precursor of vanadium oxide and is impregnated on the filter material, reacts in water, and prepared by drying, hydrothermal and other processes. The composite filter material may remove three kinds of pollutants in flue gas at the same time, and the catalyst is firmly loaded and does not easily fall off.

SCR catalyst

The present invention relates to a catalyst comprising at least one oxide of vanadium, at least one oxide of tungsten, at least one oxide of cerium, at least one oxide of titanium and at least one oxide of antimony, and an exhaust system containing said oxides.

REACTOR SYSTEM INCLUDING A CATALYST BED MODULE AND PROCESS FOR THE SELECTIVE CATALYTIC REDUCTION OF NITROGEN OXIDES CONTAINED IN GAS STREAMS
20220355247 · 2022-11-10 ·

A reactor that may contact a gas stream with a catalyst composition includes a catalyst bed module having a first grouping including a first plurality of foam catalyst blocks each bounded by a first front face having a first surface area with an opposing first back face, a first top side with an opposing first bottom side, and a first side face with an opposing first alternate side face and a second grouping adjacent to the first grouping and having a second plurality of foam catalyst blocks each bounded by a second front face having a second surface area with an opposing second back face, a second top side with an opposing second bottom side, and a second side face with an opposing second alternate side face. The first back face of the first plurality of foam catalyst blocks and the second back face of the second plurality of foam catalyst face each face the other in a spaced relationship. The reactor also includes a sealing frame disposed between the first and second groupings and that may maintain the spaced relationship and form a sealed volume between the first plurality of foam catalyst blocks and the second plurality of foam catalyst blocks and a support frame having a support surface and an opening and that may support the first grouping and the second grouping. The first grouping and the second grouping are secured to the support surface such that the opening is positioned between the first grouping and the second grouping and adjacent to the sealed volume, and the sealed volume and the opening provide a passage for gas flow.