Patent classifications
B01J20/3214
Particulate material and a method for removing one or more contaminants from hydrocarbon gas
A particulate material for removing an acid gas and/or mercury contaminant from a hydrocarbon gas is disclosed. The particulate material comprises a superabsorbent hydrogel comprising a cross-linked hydrophilic polymer network having from 0.1 mol % to 50 mol % cross-linking agent. The superabsorbent hydrogel has one or more compounds capable of binding the acid gas and/or mercury contaminant incorporated into the hydrophilic polymer network by absorbing said one or more compounds as a liquid phase or an aqueous solution. Methods for preparing the particulate material and using the particulate material to remove one or more acid gas and/or mercury contaminants from a hydrocarbon gas, dehydrating the hydrocarbon gas, and mitigating corrosion in gas flowlines are also disclosed.
OXYGENATED HIERARCHICALLY POROUS CARBON COMPOUNDS AS SCAFFOLDS FOR METAL NANOPARTICLES
In one aspect, an oxygenated hierarchically porous carbon (an “O-HPC”) is provided, the O-HPC comprising: a hierarchically porous carbon (an “HPC”), the HPC comprising a surface, the surface comprising: (A) first order pores having an average diameter of between about 1 μm and about 10 μm; and (B) walls separating the first order pores, the walls comprising: (1) second order pores having a peak diameter between about 7 nm and about 130 nm; and (2) third order pores having an average diameter of less than about 4 nm, wherein at least a portion of the HPC surface has been subjected to O.sub.2 plasma to oxygenate and induce a negative charge to the surface. In one aspect, the O-HPC further comprises metal nanoparticles dispersed within the first, second, and third order pores. Methods for making and using the metal nanoparticle-impregnated O-HPCs are also provided.
ABSORBENT BELT AND OIL SKIMMER INCLUDING THE SAME
An absorbent belt according to an embodiment is for absorbing an oil contained in a cleaning liquid, and the absorbent belt includes a sponge member coated with dopamine (DA) formed by immersing a sponge in a solution mixed with the dopamine in a preset range of 1 g/L or more and 16 g/L or less.
OLEOPHILIC HYDROPHOBIC MAGNETIC POROUS MATERIALS
Oleophilic-hydrophobic-magnetic (OHM) porous materials are provided. In embodiments, an OHM porous material comprises a porous substrate having a solid matrix defining a plurality of pores distributed through the solid matrix, the OHM porous material further comprising a coating of a nanocomposite on surfaces of the solid matrix. The nanocomposite comprises a multilayer stack of a plurality of layers of a two-dimensional, layered material having nucleation sites interleaved between a plurality of layers of magnetic nanoparticles, wherein individual layers of magnetic nanoparticles in the plurality of layers of magnetic nanoparticles are each directly anchored on a surface of a layer of the plurality of layers of the two-dimensional, layered material via the nucleation sites, and are each separated by multiple layers of the plurality of layers of the two-dimensional, layered material. Methods of making and using the OHM porous materials are also provided.
Hyperbranched polymer, metal recovery agent, metal recovery method, and catalytic activity inhibitor
There is provided a hyper-branched polymer represented by the following formula (1) and having a weight-average molecular weight in a range of 1,000 to 1,000,000. In the formula (1), A.sup.1 is a group containing an aromatic ring, A.sup.2 is a group containing an amide group, A.sup.3 is a group containing sulfur, R.sup.0 is hydrogen or a substituted or unsubstituted hydrocarbon group having 1 to 10 carbon atoms, ml is in a range of 0.5 to 11, and n1 is in a range of 5 to 100. ##STR00001##
MICROCRYSTALLINE CELLULOSE PARTICLE SUPPORTED SOL-GEL SORBENTS
Solid phase extraction (SPE) sorbents and liquid chromatography (LC) stationary phases are provided, as well as methods of fabricating the same. The SPE sorbents and LC stationary phases can use microcrystalline cellulose particles as the substrate and sol-gel sorbent coating technology as the polymer/sorbent immobilization technology. The SPE sorbents and LC stationary phases are stable in a pH range of 1-13 and at a temperature of up to 350 ° C.
Magnetically-controlled graphene-based micro-/nano-motor and fabrication method thereof
A method of fabricating a magnetically-controlled graphene-based micro-/nano-motor includes: (a) mixing FeCl.sub.3 crystal powder with deionized water to obtain a FeCl.sub.3 solution; (b) completely immersing a carbon-based microsphere in the FeCl.sub.3 solution; transferring the carbon-based microsphere from the FeCl.sub.3 solution followed by heating to allow crystallization of FeCl.sub.3 on the surface of the carbon-based microsphere to obtain a FeCl.sub.3-carbon-based microsphere; (c) heating the FeCl.sub.3-carbon-based microsphere in a vacuum chamber until there is no moisture in the vacuum chamber; continuously removing gas in the vacuum chamber and introducing oxygen; and treating the FeCl.sub.3-carbon-based microsphere with a laser in an oxygen-enriched environment to obtain the magnetically controlled graphene-based micro-/nano-motor. A magnetically-controlled graphene-based micro-/nano-motor is further provided.
ZEOLITE MEMBRANE COMPOSITE, AND METHOD FOR PRODUCING SAME
Provided is a zeolite membrane composite used for separation of a mixture, which has a high separation factor and is easily produced while maintaining a practically usable permeation flow rate. The zeolite membrane composite includes: a porous support; and an aluminosilicate zeolite membrane formed on a surface of the porous support and having a framework density of 10 or more and 17 or less. A Si/Al molar ratio of a surface of the zeolite membrane is 5 or more, and a ratio (A.sub.e/A.sub.0) of a developed membrane area A.sub.e in consideration of unevenness on the surface of the zeolite membrane to an apparent membrane area A.sub.0 not in consideration of the unevenness on the surface of the zeolite membrane is 2 or more and 20 or less.
REMOVAL OF VOCS AND FINE PARTICULATE MATTER BY METAL ORGANIC FRAMEWORKS COATED ELECTRET MEDIA (E-MOFILTER)
Provided herein are electret-MOF filter embedded with particles derived from metal-organic frameworks (MOF) and their methods of manufacturing. The methods of manufacturing the electret-MOF filter can include suspending MOF particles in a solvent to form a MOF particle mixture, contacting a charged polymeric fibrous web with the MOF particle mixture, and coating the charged polymeric fibrous web with the MOF particles by flowing the MOF particle mixture through an inverse side of the polymeric fibrous web. The disclosed coating method can deposit MOF particles uniformly, without formation of films at interstitial spaces between fibers. The electret-MOF filter can simultaneously remove fine particulate matters (PMs) and hazardous gaseous pollutants (including volatile organic compounds (VOCs)) with high particle holding and gas adsorption capacities, and with very low air resistance.
Magnesium oxide-polyamine adsorbent and a method of capturing carbon dioxide
An aminated magnesium oxide adsorbent containing a magnesium oxide matrix having disordered mesopores and a BET surface area of 320 to 380 m.sup.2/g, and a polyamine selected from the group consisting of an ethyleneamine having a molecular weight of up to 450 g/mol and a polyethylene imine having a number average molecular weight of greater than 500 g/mol and up to 20,000 g/mol, wherein the polyamine is impregnated within the disordered mesopores of the magnesium oxide matrix. A method of making the aminated magnesium oxide adsorbent and a method of capturing CO.sub.2 from a gas mixture with the aminated magnesium oxide adsorbent are also described.