The present disclosure provides a desulfurization and sulfur recovery method for sulfur dioxide flue gas, and belongs to the technical field of non-ferrous metal smelting. The method includes the following steps: desulfurizing the sulfur dioxide flue gas by taking slagging flux limestone or quicklime for smelting or converting process as a desulfurizer, and adsorbing SO.sub.2 in the gas to obtain gypsum residue, calcium sulfite, and the desulfurized flue gas, where SO.sub.2 in the sulfur dioxide flue gas before desulfurization is less than 1 vol %; and recycling the gypsum residue and the calcium sulfite to the smelting or converting furnace for slagging, resolving the SO.sub.2 into smelting off-gas, producing sulfuric acid in acid plant.

Atmospheric moisture harvester systems include two beds with water capture material, such as metal-organic framework (MOF), a heater, two fans, and a condenser having two sides, operatively configured into adsorption and desorption modes, wherein the MOF beds are interchangeable to cycle between the desorption and water adsorption modes. The systems may further include a photovoltaic panel powering the fans and condenser.

The present disclosure relates to systems and methods of making ammonia using stable ammonia absorbents. The system and method for producing ammonia, comprises a reactor comprising a catalyst that converts at least a portion of nitrogen feed gas and at least a portion of hydrogen feed gas to ammonia (NH3) forming a reaction mixture comprising the ammonia, unreacted nitrogen, and unreacted hydrogen. An absorber configured to selectively absorb ammonia from the reaction mixture at a temperature of about 180 deg. C. to 330 deg. C. and a pressure of about 1-20 bar, the absorber comprising a solid absorbent. Preferably the solid absorbent is at least one metal halide and a solid support. The unabsorbed ammonium, the unreacted nitrogen, and unreacted hydrogen gas are recycled to the reactor.

A method for recovering lithium is provided. The method includes the following steps. A lithium-containing solution is provided. A manganese oxide adsorbent is immersed in the lithium-containing solution, and a reducing agent is added to carry out an adsorption reaction, and the manganese oxide adsorbent is immersed in a solution containing an oxidizing agent to carry out a desorption reaction.

An adsorbent for phosphoric acid-based anionic substances, that contains foamed glass, and that has a Ca2p concentration of 7.5 atom % or more or a Na1s concentration of 5.0 atom % or less at the surface thereof as measured by XPS analysis, and a half-width of Si2p peak of 2.4 eV or more. The adsorbent can also have a specific surface area of 45 m.sup.2/g or more or a pore volume of 2.5 cm.sup.3/g or more as measured by mercury intrusion.

Disclosed are air-stable small-molecule adsorbents trimeric [Cu—Br].sub.3 and [Cu—H].sub.3 that undergo a reversible solid-state molecular rearrangements to [Cu—Br.(alkene)].sub.2 and [Cu—H.(alkene)].sub.2 dimers. The reversible solid-state rearrangement allows one to break adsorbent design trade-offs and achieve low heat of adsorption while retaining high selectivity and uptake.

The present invention is directed to a method, device and system to capture carbon dioxide in air using solid amine sorbents and using a radio frequency and/or microwave generator to desorb the carbon dioxide by directly exciting the amine-carbon bond thereby significantly reducing the energy cost of releasing the carbon dioxide.

The present invention relates yolk-shell nanoparticles having both a high stability towards sintering and high H.sub.25 adsorption capacities, the use of the yolk-shell nanoparticles in a method for H.sub.2S removal from gas streams, and a corresponding method for H.sub.2S removal from gas streams also comprising the regeneration of the yolk-shell nanoparticles, wherein the yolk-shell nanoparticles provide for high H.sub.2 adsorption capacities and/or high reusability.

The present invention relates to an adsorbent comprising an alumina support and at least one alkali element, said adsorbent being obtained by introducing at least one alkali element, identical to or different from sodium, onto an alumina support the sodium content of which, expressed as Na.sub.2O equivalent, before the introduction of the alkali element or elements, is comprised between 1000 and 5000 ppm by weight with respect to the total weight of the support. The invention also relates to processes for the preparation of said adsorbent and use thereof in a process for the elimination of acidic molecules such as COS and/or CO.sub.2.

A process for recovery of lithium ions from a lithium-bearing brine includes contacting the lithium-bearing brine with a lithium ion sieve (where that LIS includes an oxide of titanium or niobium) in a first stirred reactor to form a lithium ion complex with the lithium ion sieve, and decomplexing the lithium ion from the lithium ion sieve in a second stirred reactor to form the lithium ion sieve and an acidic lithium salt eluate.