A method for forming an integrated composite comprises providing a three-dimensional substrate having at least one channel; coating the substrate with a phenolic resin, wherein coating comprises dispersing the phenolic resin on the substrate, impregnating the phenolic resin in the substrate or a combination of both; curing the substrate and the phenolic resin; heating the cured substrate and cured phenolic resin to a temperature in a range of about 600? C. to about 1100? C. in an inert environment thereby pyrolyzing the phenolic resin, forming a conductive carbon network on, in, or both on and in the substrate; and coating a support material on, in, or both on and in the substrate to form an integrated composite.

This invention generally relates to a process for manufacturing a lithium selective adsorption/separation media, and more particularly, to a process for manufacturing a lithium selective adsorbent/separation media using a recycled and augmented intercalation reaction liquor. The recycled and augmented intercalation reaction liquor is formed during intercalation and neutralization of the adsorbent manufacturing process.

The invention provides highly reactive nano-sized alumina particle compositions, including alumina compositions with a BET surface areas on the order of 2000 m.sup.2/g. Also disclosed are impregnated alumina supports comprising materials that are metal oxides or carbonates. Methods for the synthesis and fabrication of these compositions are provided, along methods for the use of these compositions as sorbents.

The present invention relates to activated carbon sorbents including nitrogen. In various embodiments, the present invention provides an activated carbon sorbent including a halogen- or halide-promoted activated carbon, the activated carbon sorbent particles including nitrogen in a surface layer of the sorbent particles. In various embodiments, the present invention provides a method of reducing the pollutant content in a pollutant-containing gas using the activated carbon sorbent. In various embodiments, the activated carbon sorbent can remove mercury from a mercury-containing gas that includes sulfur(VI) such as SO.sub.3 more efficiently than other sorbents.

Provided is a production method for core-shell porous silica particles, the production method including: a preparation step of preparing an aqueous solution comprising non-porous silica particles, a cationic surfactant, a basic catalyst, an electrolyte, and an alcohol; a shell precursor formation step at adding a silica source to the aqueous solution to form a shell precursor on a surface of the non-porous silica particles; and a shell formation step of removing the cationic surfactant from the shell precursor to form a porous shell.

A method for producing core-shell porous silica particles including: a step of forming a shell precursor by continuously adding a silica source-containing liquid into an aqueous suspension containing non-porous silica particles, a cationic surfactant, a basic catalyst, and an alcohol under conditions that a pH of the reaction system is from 7 to 13 and a pH value change of the reaction system is 1.5/10 min to form a shell precursor on a surface of non-porous silica particles; and a step of forming a porous shell by removing the cationic surfactant from the shell precursor, to form a porous shell; wherein in the step of forming the shell precursor, when a specific surface area of the non-porous silica particles is Xm.sup.2/g, a used amount of the non-porous silica particles is Yg, and a used amount of the silica source is Zcm.sup.3, Z/(XY) being from 0.01 to 10.

The present invention provides novel chromatographic materials, e.g., for chromatographic separations, processes for their preparation and separations devices containing the chromatographic materials. The preparation of the inorganic/organic hybrid materials of the invention wherein a surrounding material is condensed on a superficially porous hybrid core material will allow for families of different hybrid packing materials to be prepared from a single core hybrid material. Differences in hydrophobicity, ion-exchange capacity, chemical stability, surface charge or silanol activity of the surrounding material may be used for unique chromatographic separations of small molecules, carbohydrates, antibodies, whole proteins, peptides, and/or DNA.

Compositing a gas adsorbant, macroporous object includes the immersion of a macroporous substrate into a charge stabilized suspension of nanoparticles that has been adapted for electrostatic repulsion. In this regard, the macroporous substrate includes a multiplicity of pores and demonstrates a compatibility with an adsorbant additive while lacking a repellant reaction to the charge stabilized solution. The nanoparticles are then positioned onto different walls of the pores resulting in the decoration of the macroporous structure with high surface volume materials. Finally, the macroporous substrate is removed from the suspension and dried. Thereafter, a gas adsorbant additive is introduced onto both surface portions of the macroporous substrate and also to the different walls of the pores of the macroporous substrate.

A sorbent bed may comprise a sorbent support comprising at least one of a carbon material, a polymeric material, or alumina, wherein the sorbent support comprises a plurality of pores; and an impregnant configured to absorb ammonia disposed within the plurality of pores in the sorbent support, wherein the sorbent bed comprises between 20% and 60% by weight impregnant.

In one aspect, the present invention provides a chromatographic stationary phase material for various different modes of chromatography represented by Formula 1: [X](W).sub.a(Q).sub.b(T).sub.c (Formula 1). X can be a high purity chromatographic core composition having a surface comprising a silica core material, metal oxide core material, an inorganic-organic hybrid material or a group of block copolymers thereof. W can be absent and/or can include hydrogen and/or can include a hydroxyl on the surface of X. Q can be a functional group that minimizes retention variation over time (drift) under chromatographic conditions utilizing low water concentrations. T can include one or more hydrophilic, polar, ionizable, and/or charged functional groups that chromatographically interact with the analyte. Additionally, b and c can be positive numbers, with the ratio 0.05?(b/c)?100, and a?0.