A two-reactor catalytic system including a catalytic membrane gasification reactor and a catalytic membrane water gas shift reactor. The catalytic system, for converting biomass to hydrogen gas, features a novel gasification reactor containing both hollow fiber membranes that selectively allow O.sub.2 to permeate therethrough and a catalyst that facilitates tar reformation. Also disclosed is a process of converting biomass to H2. The process includes the steps of, among others, introducing air into a hollow fiber membrane; mixing the O.sub.2 permeating through the hollow fiber membrane and steam to react with biomass to produce syngas and tar; and reforming the tar in the presence of a catalyst to produce more syngas.

An apparatus is provided that receives waste and generates electrical power or thermal energy with minimal NOx emissions. A gasifier is provided that receives the waste and air to produce fuel gas for delivery to a fluidly coupled reformer. The reformer receives the fuel gas, recycled flue gas, and air to auto-thermally produce a reformed fuel gas and destroy fuel gas pollutants at a first temperature without a catalyst. A burner is fluidly coupled to the reformer and receives recycled flue gas and air to oxidize the reformed fuel gas at a second temperature that prevents nitrogen oxide formation, the second temperature being lower than the first temperature. A quench chamber is fluidly coupled to the burner and receives flue gas from the burner for quenching with recycled flue gas. A heat recovery system is fluidly coupled to the reformer, burner, and quench chamber to extract usable energy.

Electric-powered, closed-loop, continuous-feed, endothermic energy-conversion systems and methods are disclosed. In one embodiment, the presently disclosed energy-conversion system includes a shaftless auger. In another embodiment, the presently disclosed energy-conversion system includes a drag conveyor. In yet another embodiment, the presently disclosed energy-conversion system includes a distillation and/or fractionating stage. The endothermic energy-conversion systems and methods feature mechanisms for natural resource recovery, refining, and recycling, such as secondary recovery of metals, minerals, nutrients, and/or carbon char.

A gas combustion treatment device that subjects an ammonia-containing gas, a hydrogen cyanide-containing gas, and a hydrogen sulfide-containing gas to combustion treatment includes: a first combustion unit configured to introduce therein fuel, the ammonia-containing gas, the hydrogen cyanide-containing gas, and air and burn and reduce the fuel and the gases at an air ratio lower than 1; a second combustion unit provided downstream of the first combustion unit and configured to burn and reduce, in a reducing atmosphere, nitrogen oxide in a first combustion gas sent from the first combustion unit; and a third combustion unit provided downstream of the second combustion unit and configured to introduce therein hydrogen sulfide-containing gas with air in addition to a second combustion gas sent from the second combustion unit.

Apparatus and methods to eliminate PFAS from wastewater biosolids through fluidized bed gasification. The gasifier decomposes the PFAS in the biosolids at temperatures of 900-1800° F. Syngas exits the gasifier which is coupled to a thermal oxidizer and combusts at temperatures of 1600-2600° F. This decomposes PFAS in the syngas and creates flue gas. Heat is recovered from the flue gas by cooling the flue gas to temperatures of 400-1200° F. in a heat exchanger coupled with the thermal oxidizer. Various methods inject moisture into the gas stream, controlling temperature through evaporative cooling and/or injecting chemicals that react with gas stream components. Cooled flue gas mixes with hydrated lime capturing decomposed PFAS molecules with spent lime filtered from the cooled flue gas using a filter system that may incorporate catalyst impregnated filter elements, eliminating PFAS from wastewater biosolids and controlling emissions in the resulting flue gas.

A process and apparatus for producing pure hydrogen from a syngas generated by the high temperature gasification of municipal, agricultural or industrial derived wastes. The process is able to make pure hydrogen to be further reacted with nitrogen to make ammonia and urea.

A gas purification device includes: a converter packed with a catalyst for hydrolyzing both carbonyl sulfide and hydrogen cyanide; an upstream heat exchanger for heat exchange between a gas to be introduced into the converter and a cooling fluid for cooling the gas; a reaction-temperature estimation member for estimating a reaction temperature inside the converter; and a flow-rate adjustment member for adjusting a flow rate of the cooling fluid flowing into the upstream heat exchanger based on an estimated value of the reaction-temperature estimation member to control the reaction temperature.

A gas purification device includes: a converter packed with a catalyst for hydrolyzing both carbonyl sulfide and hydrogen cyanide; an upstream heat exchanger for heat exchange between a gas to be introduced into the converter and a cooling fluid for cooling the gas; a reaction-temperature estimation member for estimating a reaction temperature inside the converter; and a flow-rate adjustment member for adjusting a flow rate of the cooling fluid flowing into the upstream heat exchanger based on an estimated value of the reaction-temperature estimation member to control the reaction temperature.

Disclosed is a method for reducing the tar content in pyrolysis gas generated in a pyrolysis reactor (1). The method comprises the steps of: guiding the pyrolysis gas through a filter (2) to remove at least 90% of all the particles in the pyrolysis gas having a particle size down to 7μ and preferably down to 4μ from the pyrolysis gas, partially oxidizing the pyrolysis gas in a partial oxidation reactor (3) to remove tar from the pyrolysis gas, and guiding the pyrolysis gas through a coke bed (4) to further remove tar from the pyrolysis gas. Furthermore, a two-stage gasifier (6) is disclosed.

Disclosed is a method for reducing the tar content in pyrolysis gas generated in a pyrolysis reactor (1). The method comprises the steps of: guiding the pyrolysis gas through a filter (2) to remove at least 90% of all the particles in the pyrolysis gas having a particle size down to 7μ and preferably down to 4μ from the pyrolysis gas, partially oxidizing the pyrolysis gas in a partial oxidation reactor (3) to remove tar from the pyrolysis gas, and guiding the pyrolysis gas through a coke bed (4) to further remove tar from the pyrolysis gas. Furthermore, a two-stage gasifier (6) is disclosed.