Lubricating compositions are described, the lubricating compositions comprising a base oil component and an additive component, wherein the additive component comprises a non-silicone anti-foaming agent.

The engine lubricating system can become contaminated with carbon deposits and sludge. Sludge is where the combustion by-products that have entered the oil base saturate this oil base, thus forming a thick carbon rich substance. Sludge is not wanted within the engine. Sludge and or carbon deposits in the motor oil cause problems. Such carbon deposits form in the motor oil from heat, pressure, and namely combustion gases that have leaked pasted the piston rings. Turpentine and terpenes, hereafter referred to as “terpenes”, have shown that these chemicals can breakdown carbon which has been deposited within the engine's oil base.

Aspects described herein generally relate to methods of making a phosphono paraffin comprising forming a reaction mixture by mixing a haloparaffin, a phosphite, and sodium iodide. Methods comprise heating the reaction mixture to form the phosphono paraffin. Aspects described herein further relate to a phosphono paraffin represented by formula (I):

##STR00001##

wherein each instance of R.sup.1 is independently —H or

##STR00002##

wherein each instance of R.sup.2 and R.sup.3 is independently linear or branched C.sub.1-20 alkyl, C.sub.1-20 cycloalkyl, or aryl; the number of instances where R.sup.1 is

##STR00003##

of formula (I) is between about 2 and about 8; and n is an integer between 4 and 22.

A lubricating oil composition may include a base oil (A), a zinc dithiophosphate (B) comprising a compound (B1) of formula (b-1), calcium sulfonate (C), and a seal sweller (D). In formula (b-1), R.sup.1 to R.sup.4 are each independently an alkyl group. However, at least one of R.sup.1 to R.sup.4 is a prescribed straight-chain alkyl group, and at least one of R.sup.1 to R.sup.4 is a prescribed branched chain alkyl group.

The present disclosure generally relates to processes to produce alpha-olefin oligomers and poly alpha-olefins. In an embodiment, a process to produce a poly alpha-olefin (PAO) includes introducing a first alpha-olefin and a first catalyst system comprising a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions to form a first reactor effluent. The alpha-olefin is introduced to the reactor at a flow rate of about 100 g/hr or more. The first reactor effluent includes PAO dimer comprising at least 96 mol % of vinylidene and 4 mol % or less of trisubstituted vinylene and disubstituted vinylene, based on total moles of vinylidene, trisubstituted vinylene, and disubstituted vinylene. The method includes introducing the first reactor effluent, a second alpha-olefin and a second catalyst composition comprising an acid catalyst into a second reactor under second reactor conditions to form a second reactor effluent comprising PAO trimer.

A transformer oil basestock is disclosed that includes at least 99 wt % of naphthenes and paraffins, based on the total weight of the transformer oil basestock, wherein the weight ratio of naphthenes to paraffins is at least 1, as measured by GC-MS, and wherein the paraffins consist essentially of isoparaffins, as determined by GC-FID. In addition, a transformer oil composition is disclosed that includes the transformer oil basestock, an anti-gassing agent and an antioxidant.

A lubricating oil composition including: a lubricating base oil; (A) a first defoaming agent, the first defoaming agent being (A1) a first polymer, or (A2) a second polymer, or any combination thereof; and (B) a second defoaming agent, the second defoaming agent being a silicone defoaming agent, the (A1) first polymer including: a first polymer chain including a polysiloxane structure, the polysiloxane structure having a polymerization degree of 5 to 2000 and being represented by the following general formula (1); and a second polymer chain bonded with the first polymer chain, the second polymer chain including a repeating unit represented by the following general formula (2), the (A2) second polymer being a copolymer of a first monomer component and a second monomer component, the first monomer component represented by the general formula (7) or (8), the second monomer component represented by the general formula (9). ##STR00001##

A fluid includes a base stock and one or more additives. The base stock has a viscosity index of at least 80, and either a kinematic viscosity at 40° C. of at least 320 cSt or a kinematic viscosity at 100° C. of at least 14 cSt. The base stock includes greater than or equal to about 90 wt % saturates, less than or equal to about 10 wt % aromatics, and a sum of terminal/pendant propyl groups and terminal/pendant ethyl groups of at least 1.7 per 100 carbon atoms. The fluid has a thermal conductivity measured according to ASTM D7896 at 140° C. of 0.12 W/m.Math.K or greater.

An ionic liquid composition having the following generic structural formula: ##STR00001##
wherein Z is N or P, and R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are independently selected from hydrogen atom and hydrocarbon groups having one to four carbon atoms with optional interconnection to form a cyclic group that includes Z, and wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are all hydrocarbon groups when Z is P, and X.sup.− is a phosphorus-containing or carboxylate anion, particularly an organophosphate, organophosphonate, or organophosphinate anion, or a thio-substituted analog thereof containing hydrocarbon groups with at least three carbon atoms. Also described are lubricant compositions comprising the above ionic liquid and a base lubricant, wherein the ionic liquid is dissolved in the base lubricant. Further described are methods for applying the ionic liquid or lubricant composition onto a mechanical device for which lubrication is beneficial, with resulting improvement in friction reduction, wear rate, and/or corrosion inhibition.

The present invention relates to a sulphur-containing polyester capable of being obtained by a process comprising esterification reactions between a polyol and a carboxylic acid and a thiolactic acid, or by a process comprising an esterification reaction between a partially esterified polyol and a thiolactic acid. It also concerns its use as a multiproperty additive, and compositions comprising it.