A macromonomer precursor is provided that includes a polymeric chain derived from farnesene and a single functional terminal end. The functional terminal end may include a hydroxyl group, an amino group, an epoxy group, an isocyanato group, or a carboxylic acid group. The terminal end of the macromonomer precursor may then be reacted with a (meth)acrylate to form a macromonomer having a (meth)acrylate functionalized terminal end that may be (co)polymerized with radically polymerizable monomers, such as alkyl(meth)acrylate monomers. Alternatively, a copolymer may be obtained by first deriving a poly(meth)acrylate from (meth)acrylate monomers having reactive groups that would allow the macromonomer precursors to be grafted onto the poly(meth)acrylate in a second step. The resulting copolymer may be incorporated as an additive in various formulations, such as a lubricant, a hydraulic fluid, a cosmetic composition, and an adhesive composition.

The invention relates to phosphorous-containing compounds useful as antiwear additive components, lubricant additive compositions and lubricant compositions each comprising such compounds, methods for making and using the same, including methods of lubricating machines and machine parts and methods of extending the useful life of elastomeric seal components of such machines.

There is provided a method of planning irrigation, comprising: performing for a certain interval of time: computing a value of a crop evapotranspiration parameter indicative of an amount of water consumed by a reference crop, computing a value of a potential evapotranspiration parameter indicative of weather conditions associated with the field of the reference crop, computing a value of a dynamic crop coefficient for the reference crop based on the crop evapotranspiration parameter and the potential evapotranspiration parameter, and providing the dynamic crop coefficient computed for the certain time interval of time of the reference crop that corresponds to a target time interval of a target growing season of the target crop, wherein the target crop is growing in a target field which is geographically distinct from the reference field, and outputting instructions for irrigation of the target crop according to an irrigation plan based on the dynamic crop coefficient.

The present disclosure generally relates to processes to produce alpha-olefin oligomers and poly alpha-olefins. In an embodiment, a process to produce a poly alpha-olefin (PAO) includes introducing a first alpha-olefin and a first catalyst system comprising a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions to form a first reactor effluent. The alpha-olefin is introduced to the reactor at a flow rate of about 100 g/hr or more. The first reactor effluent includes PAO dimer comprising at least 96 mol % of vinylidene and 4 mol % or less of trisubstituted vinylene and disubstituted vinylene, based on total moles of vinylidene, trisubstituted vinylene, and disubstituted vinylene. The method includes introducing the first reactor effluent, a second alpha-olefin and a second catalyst composition comprising an acid catalyst into a second reactor under second reactor conditions to form a second reactor effluent comprising PAO trimer.

The present disclosure provides processes for producing alkylated fatty acids and derivatives thereof. In at least one embodiment, a process includes introducing a terminal alkyl transferase and a fatty acid into a bioreactor. The process includes introducing an internal methyl transferase and internal methyl reductase into the bioreactor or a second bioreactor. The process includes obtaining an alkylated fatty acid having a methyl substituent located at an internal carbon atom of the fatty acid and a methyl substituent or ethyl substituent located at a carbon atom alpha to the terminal carbon atom of the fatty acid.

The invention provides a lubricant formulation comprising: (a) a base oil selected from API Group I to V oils and mixtures thereof; (b) 0.01 to 10 wt % on the basis of the total weight of the lubricant formulation of a friction modifier additive; and (c) other lubricant formulation additives. The friction modifier additive has a hydroxyl value in the range from 10 to 300 mg KOH/g and is the reaction product of reactants comprising: i) a dimer fatty acid; ii) a polyol; iii) optionally, a C2 to C12 dicarboxylic acid or diol; and iv) optionally, a C1 to C10 mono-carboxylic acid or mono-alcohol. The invention also provides a method of lubricating an internal combustion engine comprising a crankcase and a wet clutch and the use of a friction modifier additive.

The present invention relates to the field of multipurpose lubricants which may be used in the various components of automotive vehicles, notably in the engine, the transmission or the hydraulic circuit.

The invention relates to the use of at least one polymer which improves the viscosity index, chosen from hydrogenated copolymers of diene and of aromatic vinyl, in a lubricant composition for decreasing the viscosity of said lubricant composition in the course of the use of said lubricant composition during the lubrication of the various components of an industrial vehicle, notably of a diesel engine industrial vehicle, such as the engine, the gearbox and the hydraulic circuit, said lubricant composition undergoing at least one thermal shear during its use.

An additive composition for a hydraulic fluid, or a heat transfer fluid, comprises one or more phosphate esters derived from the esterification of phosphoric acid and one or more monomer glycols containing up to 18 carbon atoms, or combinations thereof. In addition, the additive composition may comprise one or more corrosion inhibitors selected from the group consisting of dicarboxylic acids, alkanolamines or combinations thereof; one or more antioxidants including selected from the group consisting of one or more organosulfur compounds, one or inorganic oxyanion salts or combinations thereof; and, one or more surfactants.

Provided herein are hydrocarbon mixtures with controlled structure characteristics that address the performance requirements for finished lubricants driven by the stricter environmental and fuel economy regulations. The branching characteristics of the hydrocarbon molecules are controlled to provide a composition that has a unique and superior viscosity-temperature relationship and Noack volatility. An important aspect of the present invention relates to a saturated hydrocarbon mixture with at least 80% of the molecules having an even carbon number, with the branching characteristic of BP/BI in the range≥−0.6037 (Internal alkyl branching)+2.0, where on average at least 0.3 to 1.5 of the internal methyl branches are located more than 4 carbons away from the terminal carbon when analyzed by carbon NMR. The saturated hydrocarbon mixture with such unique branching structure consistently exhibits a stand out performance in the cold crank simulated viscosity (CCS) vs Noack volatility relationship, which allows for the formulation of lower viscosity engine oils with improved fuel economies.

The present invention relates to a lubricant composition, and more particularly to a lubricant composition, which has superior oxidation stability and friction characteristics even under harsh conditions of high temperature and high pressure and is thus suitable for use in hydraulic oil. The lubricant composition of the present invention includes a base oil, a liquid olefin copolymer, a phosphorothioate compound, and phosphonium phosphate.