EDGE STRESS USING DIFFERENTIAL COOLING
20220185717 · 2022-06-16
Inventors
- Vikram Bhatia (Painted Post, NY, US)
- Ah-Young Park (Daejeon, KR)
- Yousef Kayed Qaroush (Painted Post, NY)
- Zheming Zheng (Horseheads, NY, US)
Cpc classification
C03C27/10
CHEMISTRY; METALLURGY
B32B17/10871
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10036
PERFORMING OPERATIONS; TRANSPORTING
C03B23/0307
CHEMISTRY; METALLURGY
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10889
PERFORMING OPERATIONS; TRANSPORTING
B32B17/06
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B17/06
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A cold-formed glass laminate may include a first ply of 3D formed glass with a first thickness and a first strength. The first ply may include pre-formed residual compressive stresses in a peripheral edge portion adapted to offset tensile stresses resulting from a cold-forming process. The laminate may also include a second ply of 3D formed glass with a second thickness less than the first thickness and a second strength greater than the first strength. An adhesive may be arranged between the first ply and the second ply and post-formed residual stresses in the peripheral edge portion of the first ply of the laminate may remain compressive. A method of forming a glass laminate with compressive edge stresses is also described.
Claims
1. A cold-formed glass laminate, comprising: a first ply of glass with a first thickness and a first strength, the first ply having pre-formed residual compressive stresses in a peripheral edge portion adapted to offset tensile stresses resulting from a cold-forming process; a second ply of glass with a second thickness less than the first thickness and a second strength greater than the first strength; an adhesive arranged between the first ply and the second ply; and wherein post-formed residual stresses in the peripheral edge portion of the first ply remain compressive.
2. The glass laminate of claim 1, wherein the pre-formed residual compressive stresses range from approximately 10 MPa to approximately 25 MPa.
3. The glass laminate of claim 1, wherein the post-formed residual compressive stress in the peripheral edge portion of the first ply after the cold-forming process ranges from approximately 7 MPa to approximately 28 MPa.
4. The glass laminate of claim 1, wherein the peripheral edge portion comprises a substantially uniform ribbon around the perimeter of the glass laminate.
5. The glass laminate of claim 4, wherein the ribbon has a width from approximately 3 mm to approximately 7 mm.
6. The glass laminate of claim 5, wherein the width is approximately 5 mm.
7. The glass laminate of claim 1, wherein the first ply is soda lime glass and the second ply is at least one of chemically strengthened glass, thermally strengthened glass, or mechanically strengthened glass.
8. The glass laminate of claim 1, wherein the glass laminate is configured as at least one of a roof or a windshield for a vehicle.
9. A method of forming a glass laminate, comprising: hot-forming a first ply of glass; inducing residual compressive stresses in a peripheral edge of the first ply of glass by cooling the first ply of glass and, during the cooling, establishing a temperature differential between a peripheral edge of the first ply of glass and a center portion of the first ply of glass, wherein a temperature of the peripheral edge is cooler than a temperature of the center portion; and after cooling, cold-forming a second ply of glass to the first ply of glass and adhering the second ply of glass to the first ply of glass with an adhesive, the cold-forming causing tensile stresses in the peripheral edge of the first ply of glass that are counteracted by the residual compressive stresses such that post-forming residual stresses in the first ply of glass remain compressive.
10. The method of claim 9, wherein the temperature differential ranges from approximately 10° C. to approximately 40° C.
11. The method of claim 10, wherein the temperature differential ranges from approximately 12° C. to approximately 30° C.
12. The method of claim 11, wherein the temperature differential ranges from approximately 14° C. to approximately 25° C.
13. The method of claim 9, wherein the hot-forming of the first ply of glass comprises heating the first ply of glass beyond the glass transition point.
14. The method of claim 13, wherein establishing a temperature differential comprises providing additional cooling at edges of the first ply of glass.
15. The method of claim 14, wherein providing additional cooling comprises blowing cold air on the edges.
16. The method of claim 15, wherein blowing cold air comprises blowing cold air with a cooling channel arranged at or near the edges.
17. The method of claim 16, wherein hot-forming the first ply of glass comprises hot-forming the first ply of glass into at least one of a roof or a windshield shape.
18. The method of claim 17, wherein the cold-forming the second ply of glass comprises heating the second ply of glass to an elevated temperature below 140° C.
19. The method of claim 18, wherein the cold-forming the second ply of glass comprises pressing the second ply of glass against the first ply of glass at the elevated temperature.
20. The method of claim 19, wherein a strength of the second ply of glass is greater than a strength of the first ply of glass.
21. The method of claim 9, further comprising partially hot-forming the second ply of glass prior to cold-forming the second ply of glass to the first ply of glass.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0014] While the specification concludes with claims particularly pointing out and distinctly claiming the subject matter that is regarded as forming the various embodiments of the present disclosure, it is believed that the disclosure will be better understood from the following description taken in conjunction with the accompanying Figures, in which:
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DETAILED DESCRIPTION
[0027] The present application, in one or more embodiments, relates to a glass laminate and a method of forming the glass laminate where particular residual stresses in the laminate are compressive and, as such, help to resist cracking, delamination, or other flaws. In one or more embodiments, a glass laminate may include an outer soda lime glass ply and an inner chemically treated glass ply. The outer ply may be hot-formed to a desired shape such as that of a roof or a windshield. At the end of the hot-forming process, particular cooling steps may be taken to cool the peripheral edge of the outer ply more quickly than the center portion of the ply to induce compressive stresses in the peripheral edge of the outer ply. An inner ply may be laminated to the outer ply using a cold-forming process. This process may normally create tensile stresses in the peripheral edge of the outer ply. However, having induced compressive stresses in the peripheral edge of the outer ply, the cold forming may reduce the compressive stresses, but may not fully overcome them. As such, the laminate may maintain compressive residual stresses in the peripheral outer edge of the outer ply, which may cause the laminate to be more resistant to flaw development.
[0028] Referring now to
[0029] With reference to
[0030] The inner ply 108 may be a relatively thin ply of glass material such as a chemically strengthened glass, thermally strengthened glass, or other glass material, such as non-strengthened soda lime glass, for example. In one or more embodiments, the inner ply 108 may include a mechanically strengthened glass utilizing a mismatch of the coefficient of thermal expansion between portions of the article to create a compressive stress region and a central region exhibiting a tensile stress. The inner ply 108 may be transparent, substantially transparent, or the inner ply 108 may include textures or coatings to create tinting or semi-transparent effects for particular applications. The inner ply 108 may be considered inner because it may face inwardly toward the interior cabin when the glass laminate is installed in a vehicle, for example. The inner ply 108 may have a thickness ranging from approximately 0.3 mm to 1.0 mm, or from 0.5 mm to 0.9 mm, or the inner ply may have a thickness of approximately 0.6 mm, 0.7 mm, or 0.8 mm. Still other thickness of the inner ply 108 of the laminate may be provided. Chemically strengthened glass may be a relatively high strength glass and may have a tensile capacity of approximately 90-110 MPa, or approximately 95-105 MPa, or approximately 100 MPa. The tensile strength of chemically strengthened glass may be relatively high when compared to that of soda lime glass, which may make the chemically strengthened glass suitable for use on the interior of automotive glazing where bending forces may be higher when an impact to the glass occurs.
[0031] The adhesive layer 112 may be arranged between the inner ply 108 and the outer ply 110 and may be adapted to secure the inner ply 108 to the outer ply 110. The adhesive 112 may be a transparent or a substantially transparent adhesive. For example, in one or more embodiments, the adhesive layer 112 may include one or more transparent synthetic sheets. Additionally or alternatively, the adhesive layer 112 may include a transparent or substantially transparent resin. The adhesive layer 112 may be placed between the outer ply 110 and the inner ply 108 during a lamination process and may secure the outer ply 110 to the inner ply 108 during and/or after the lamination is complete.
[0032] For purposes of this discussion and as shown in
[0033] Referring to
[0034] Particular approaches to manufacturing the laminate 100 may be provided herein to reduce and/or alleviate the risks of cracking and other problems in the outer ply 110 of the laminate 100. Referring to
[0035] In one or more embodiments, an edge cooling system 124 may be provided to increase the rate of cooling of the exterior surfaces of the pre-formed outer ply 110. The increased cooling of the exterior surfaces along the peripheral edge may cause compression in these surfaces due to the later pulling as the interior of the glass in these peripheral regions cools (e.g., similar to tempered glass), causing compression in the peripheral edge 102 of the outer ply 110. As shown in
[0036] While a cooling tube/channel system 124 has been described, still other approaches to cooling the peripheral edge 102 may be used. For example, a metal or other conductive material may be used to cool the edge 102 of the glass ply 110. In one or more embodiments, a relatively cold bar or tube may be placed adjacent or in contact with the peripheral edge 102 or edges of the glass ply 110. The bar or tube may include a circulating coolant, for example, that may maintain the bar or tube at a cool temperature and, as such, may create a reservoir for drawing the heat out of the peripheral edge 102 of the glass ply 110.
[0037] In any case, and as shown in
[0038] As shown in
[0039] Turning now to
[0040] The cold forming process together with the residual stresses already present in the pre-formed outer ply may result in a more suitable distribution of post-formed stresses in the completed laminate. In particular, the post-formed residual stresses at or near the peripheral edge 102 of the outer ply 110 may include compressive stresses ranging from approximately 7 MPa to approximately 28 MPa or from approximately 10 MPa to approximately 25 MPa, or from approximately 10 MPa to approximately 15 MPa. Moreover, the residual stresses in the peripheral edge 102 of the outer ply 110 of the laminate 100 may be selected by adjusting the cooling process to induce higher or lower residual compressive stresses in the outer peripheral edge 102 of the outer ply 110 during the cooling process after hot-forming the outer ply 110. For example, depending on the geometry of the glass ply and the desired locations of particular stresses, the cooling of the peripheral edge 102 may be uniform around the peripheral edge 102 or some areas may be cooled more than other areas. For example, and in general, where more or higher compressive stresses in the edge are desired, more cooling may be provided in those areas. Accordingly, and with knowledge of the effects of cold forming, a user may selectively induce compressive stresses in the outer ply 110 to combat, reduce, or alleviate effect of the cold-forming process on particular portions of the peripheral edge 102 of the outer ply 110. The additional cooling may be provided by providing cooler gas, more gas at a same or similar temperature, and through adjusting the amount of the peripheral edge 102 that the cooling is applied to. In one or more embodiments, additional cooling may be provided by providing cooling from both sides in one or more locations or throughout the full perimeter of the ply of glass.
[0041] A method 200 for forming a glass laminate that is resistant to breakage, cracking, crack propagation, and/or optical distortion may be provided. The method may include hot forming an outer ply of a glass laminate (202). The outer ply may be the same or similar to the outer ply described herein and, as such, may be relatively thick and relatively low in strength. The hot forming process may include heating the outer ply to a temperature meeting or exceeding the glass transition point of the outer ply and using a press with a die sized and shaped to form a desired glass shape such as a shape of a windshield or other automotive glazing. The method may also include differentially cooling the outer ply of glass laminate by cooling a peripheral edge of the outer ply more quickly than the central portion of the outer ply (204). Differentially cooling may include establishing a temperature differential between the peripheral edge and the central portion of the outer ply of glass and substantially maintaining that temperature differential throughout a large portion of the cooling process (206). In one or more embodiments, the temperature differential may range from approximately 14° C. to approximately 25° C. An inner ply of material may then be cold formed/laminated to the outer ply with an adhesive (208). The inner ply may be the same or similar to the inner ply described herein and, as such, may be relatively thin and relatively high in strength. The cold forming and laminating process may involve heating the inner ply of the laminate to a cold-forming temperature of less than 140° C., for example. The cold forming process may include placing the outer ply, an adhesive layer, and the inner ply in a press with a die designed to maintain the shape of the outer ply while pressing the inner ply to the outer ply and causing the inner ply to conform to the shape of the outer ply. The glass laminate may be suitable for installation into a vehicle or for other uses.
[0042] The resulting glass laminate may be more resistant to breakage during cold forming, cracking, delamination, crack propagation, optical distortion or breakage during shipping, installation, or use. That is, the compressive stresses induced during the hot-forming process may resist the otherwise tensile forces induced during cold-forming. That is, while potentially reduced, the residual stresses in the outer ply of the laminate may remain compressive after cold-forming and, as such, may make the outer ply more stable and less susceptible to the mentioned defects.
[0043] It is to be appreciated that while the application has been described in the context of automotive glazing and, as such, has suggested the outer ply may be thicker and less strong than the thinner and stronger inner ply, the laminate may be reversed. Moreover, particular properties of the inner ply and the outer ply may be swapped as well. For example, the outer ply may be thinner than the inner ply and/or the outer ply may be stronger than the inner ply. Still other reversals and substitutions may be provided. Still further, additional plies outside the mentioned plies or within the cross-section described may also be provided without departing from the present disclosure.
[0044] Various embodiments of the present disclosure may be described herein with reference to flowchart illustrations and/or block diagrams of methods, apparatus (systems), and computer program products. Although a flowchart or block diagram may illustrate a method as comprising sequential steps or a process as having a particular order of operations, many of the steps or operations in the flowchart(s) or block diagram(s) illustrated herein can be performed in parallel or concurrently, and the flowchart(s) or block diagram(s) should be read in the context of the various embodiments of the present disclosure. In addition, the order of the method steps or process operations illustrated in a flowchart or block diagram may be rearranged for some embodiments. Similarly, a method or process illustrated in a flow chart or block diagram could have additional steps or operations not included therein or fewer steps or operations than those shown. Moreover, a method step may correspond to a method, a function, a procedure, a subroutine, a subprogram, etc.
[0045] As used herein, the terms “substantially” or “generally” refer to the complete or nearly complete extent or degree of an action, characteristic, property, state, structure, item, or result. For example, an object that is “substantially” or “generally” enclosed would mean that the object is either completely enclosed or nearly completely enclosed. The exact allowable degree of deviation from absolute completeness may in some cases depend on the specific context. However, generally speaking, the nearness of completion will be so as to have generally the same overall result as if absolute and total completion were obtained. The use of “substantially” or “generally” is equally applicable when used in a negative connotation to refer to the complete or near complete lack of an action, characteristic, property, state, structure, item, or result. For example, an element, combination, embodiment, or composition that is “substantially free of” or “generally free of” an element may still actually contain such element as long as there is generally no significant effect thereof.
[0046] To aid the Patent Office and any readers of any patent issued on this application in interpreting the claims appended hereto, applicants wish to note that they do not intend any of the appended claims or claim elements to invoke 35 U.S.C. § 112(f) unless the words “means for” or “step for” are explicitly used in the particular claim.
[0047] Additionally, as used herein, the phrase “at least one of [X] and [Y],” where X and Y are different components that may be included in an embodiment of the present disclosure, means that the embodiment could include component X without component Y, the embodiment could include the component Y without component X, or the embodiment could include both components X and Y. Similarly, when used with respect to three or more components, such as “at least one of [X], [Y], and [Z],” the phrase means that the embodiment could include any one of the three or more components, any combination or sub-combination of any of the components, or all of the components.
[0048] In the foregoing description various embodiments of the present disclosure have been presented for the purpose of illustration and description. They are not intended to be exhaustive or to limit the disclosure to the precise form disclosed. Obvious modifications or variations are possible in light of the above teachings. The various embodiments were chosen and described to provide the best illustration of the principals of the disclosure and their practical application, and to enable one of ordinary skill in the art to utilize the various embodiments with various modifications as are suited to the particular use contemplated. All such modifications and variations are within the scope of the present disclosure as determined by the appended claims when interpreted in accordance with the breadth they are fairly, legally, and equitably entitled.