POROUS TITANIUM-BASED SINTERED BODY, METHOD FOR PRODUCING THE SAME, AND ELECTRODE

Abstract

A porous titanium-based sintered body, having a porosity of 50% to 75%, an average pore diameter of 23 μm to 45 μm, and a specific surface area of 0.020 m.sup.2/g to 0.065 m.sup.2/g, and having a bending strength of 22 MPa or more. According to the present invention, a porous titanium-based sintered body having a high porosity, a large specific surface area and a large average pore diameter and thereby having good gas permeability or liquid permeability, and further having a high strength can be provided.

Claims

1-3. (canceled)

4. A porous titanium-based sintered body, having a void ratio of 50 to 75%, an average pore diameter of 23 to 45 μm, and a specific surface area of 0.020 to 0.065 m.sup.2/g; and having a flexural strength of 22 MPa or more.

5. The porous titanium-based sintered body according to claim 4, wherein the void ratio is 55 to 75%.

6. The porous titanium-based sintered body according to claim 4, wherein the flexural strength is 22 to 45 MPa.

7. An electrode comprising the porous titanium-based sintered body according to claim 4.

8. A method for producing a porous titanium-based sintered body, comprising the step of placing a titanium-based powder having an average circularity of 0.85 or less and having D10 of 40 μm or more and D50 of 65 to 100 μm, the D10 and the D50 being obtained by particle size distribution measurement, in a mold by dry process without substantially applying pressure, and the step of sintering the powder at higher than 900° C. and 1000° C. or lower.

9. The method for producing a porous titanium-based sintered body according to claim 8, wherein as the titanium-based powder, a titanium-based powder having D50, as obtained by particle size distribution measurement, of 70 to 85 μm is used.

10. The method for producing a porous titanium-based sintered body according to claim 8, wherein the titanium-based powder is a titanium-based powder obtained by removing particles having particle diameters of more than 150 μm.

11. The method for producing a porous titanium-based sintered body according to claim 8, wherein the titanium-based powder is a titanium-based powder obtained by removing particles having particle diameters of less than 40 μm.

12. The method for producing a porous titanium-based sintered body according to claim 8, wherein the titanium-based powder is one or more selected from a titanium powder and a hydrogenated titanium powder.

13. The method for producing a porous titanium-based sintered body according to claim 8, wherein the step of sintering is a step of sintering at 920 to 1000° C.

14. The method for producing a porous titanium-based sintered body according to claim 8, wherein the step of sintering is carried out in a reduced-pressure atmosphere of 5.0×10.sup.−3 Pa or less.

Description

BRIEF DESCRIPTION OF DRAWINGS

[0030] FIG. 1 is an optical microscope observation image of a porous titanium-based sintered body of the invention Example 1.

[0031] FIG. 2 is a schematic view to describe a bending test for determining a bending strength.

DESCRIPTION OF EMBODIMENTS

[0032] The porous titanium-based sintered body of the present invention is a porous titanium-based sintered body, having a porosity of 50% to 75%, an average pore diameter of 23 μm to 45 μm, and a specific surface area of 0.020 m.sup.2/g to 0.065 m.sup.2/g, and having a bending strength of 22 MPa or more. In usual, the porous titanium-based sintered body is a sintered body of a particulate titanium-based powder and has many pores inside.

[0033] The titanium-based powder according to the present invention is a titanium powder, a hydrogenated titanium powder, a titanium powder coated with titanium nitride or titanium silicide, a titanium alloy powder, or a composite material of a combination thereof. Examples of the titanium-based powders in the present invention include a titanium powder formed of metallic titanium and inevitable impurities, and a titanium alloy powder formed of metallic titanium, an alloy metal and inevitable impurities. For example, the titanium alloy is an alloy of titanium and a metal (alloy metal) comprising one or more of Fe, Sn, Cr, Al, V, Mn, Zr or Mo, and specific examples thereof include Ti-6-4 (Ti-6A1-4V), Ti-5A1-2.5Sn, Ti-8-1-1 (Ti-8A1-1Mo-1V), Ti-6-2-4-2 (Ti-6A1-2Sn-4Zr-2Mo-0.1Si), Ti-6-6-2 (Ti-6A1-6V-2Sn-0.7Fe-0.7Cu), Ti-6-2-4-6 (Ti-6A1-2Sn-4Zr-6Mo), SP700 (Ti-4.5A1-3V-2Fe-2Mo), Ti-17 (Ti-5A1-2Sn-2Zr-4Mo-4Cr), β-CEZ (Ti-5A1-2Sn-4Zr-4Mo-2Cr-1Fe), TIMETAL555, Ti-5553 (Ti-5A1-5Mo-5V-3Cr-0.5Fe), TIMETAL21S (Ti-15Mo-2.7Nb-3A1-0.2Si), TIMETAL LCB (Ti-4.5Fe-6.8Mo-1.5A1), 10-2-3 (Ti-10V-2Fe-3A1), Beta C (Ti-3A1-8V-6Cr-4Mo-4Cr), Ti-8823 (Ti-8Mo-8V-2Fe-3A1), 15-3 (Ti-15V-3Cr-3A1-3Sn), BetaIII (Ti-11.5Mo-6Zr-4.5Sn), and Ti-13V-11Cr-3A1. In the above, the number attached before each alloy metal indicates a content (mass %). For example, “Ti-6A1-4V” indicates a titanium alloy containing 6 mass % of A1 and 4 mass % of V as an alloy metal.

[0034] The porous titanium-based sintered body of the present invention has a porosity of 50% to 75%, an average pore diameter of 23 μm to 45 μm, and a specific surface area of 0.020 m.sup.2/g to 0.065 m.sup.2/g.

[0035] In the present invention, by setting the porosity of the porous titanium-based sintered body to 50% to 75%, a large specific surface area can be ensured while ensuring good gas permeability or liquid permeability. The lower limit side of the porosity of the porous titanium-based sintered body of the present invention is preferably 55% or more. On the other hand, the upper limit side of the porosity of the porous titanium-based sintered body of the present invention is preferably 70% or less, more preferably 68% or less, still more preferably 65% or less, and even more preferably 63% or less. A porosity of less than 50% means that the porous titanium-based sintered body is too dense. That is to say, there is concern that the gas permeability or the liquid permeability becomes insufficient. On the other hand, a porosity of more than 75% means that the porous titanium-based sintered body is too coarse. That is to say, there is concern about insufficient specific surface area or insufficient strength.

[0036] The porosity is a proportion of voids per unit volume of the porous titanium-based sintered body and is expressed as percentage. In the present invention, the porosity is calculated from the following expression using a volume V (cm.sup.3) of the porous titanium-based sintered body, a mass M (g) of the porous titanium-based sintered body, and a true density D (g/cm.sup.3) of a metal part that forms the sintered body (e.g., true density of pure titanium: 4.51 g/cm.sup.3). The volume V indicates an apparent volume of the porous titanium-based sintered body.

Porosity (%)=100−((M/V)/D)×100)

[0037] The average pore diameter of the porous titanium sintered body of the present invention is 23 μm to 45 μm. By combining a high porosity with a large average pore diameter, good gas permeability or liquid permeability is ensured. The average pore diameter of the porous titanium sintered body of the present invention is preferably 23 μm to 40 μm, and more preferably 23 μm to 35 μm. If the average pore diameter is less than 23 μm, there is concern about an excessive increase in pressure loss. If the average pore diameter exceeds 45 μm, there is concern about a decrease in contact area (specific surface area).

[0038] In the present invention, the average pore diameter is determined by a mercury penetration method (Washburn model).

Average pore diameter (μm)=2×V.sub.p/S.sub.p

wherein V.sub.p is a pore volume (cc/g), and S.sub.p is a pore specific surface area (m.sup.2/g). [0039] Measurement conditions: JIS R 1655 (2003)—Pressure measuring method: strain-gauge method Temperature: room temperature [0040] Pretreatment: After pressure reduction to about 6 Pa at room temperature, mercury penetration is started.

[0041] In the present invention, it is possible to set the specific surface area of the porous titanium-based sintered body to 0.020 m.sup.2/g to 0.065 m.sup.2/g, and the specific surface area is made compatible with good gas permeability or liquid permeability. The lower limit side of the specific surface area of the porous titanium-based sintered body of the present invention is preferably 0.025 m.sup.2/g or more, and more preferably 0.030 m.sup.2/g or more. The upper limit side of the specific surface area of the porous titanium-based sintered body of the present invention is preferably 0.060 m.sup.2/g or less, and more preferably 0.055 m.sup.2/g or less. The specific surface area has great influence on the heat removal or the reaction efficiency. If the specific surface area is less than 0.020 m.sup.2/g, the amount of a catalyst supported becomes insufficient, so that there is concern about an excessive decrease in the reaction area, and because the sites that come into contact with a gas or a liquid excessively decrease, there is also concern about, for example, insufficient cooling during heat removal. On the other hand, if the specific surface area is more than 0.065 m.sup.2/g, the sites that come into contact with a gas or a liquid excessively increase, and therefore, there is concern about deterioration of gas permeability or liquid permeability. In the present invention, the specific surface area is determined based on JIS:Z8831:2013 “Determination of the specific surface area of powders (solids) by gas adsorption-BET method”.

[0042] The bending strength of the porous titanium-based sintered body of the present invention is 22 MPa or more. In the porous titanium-based sintered body of the present invention, the sintered area of the titanium-based powder that is a raw material is appropriately ensured, and therefore, a bending strength of 22 MPa or more can be attained. The bending strength of the porous titanium-based sintered body of the present invention is preferably 25 MPa or more. The upper limit side of the bending strength of the porous titanium-based sintered body of the present invention is not particularly limited, but it is preferably, for example, 65 MPa or less. The upper limit side of the bending strength of the porous titanium-based sintered body of the present invention may be 45 MPa or less, or may be 35 MPa or less.

[0043] The bending strength is a mechanical property having been reduced in influence of thickness or length of a specimen. In the present invention, the bending strength is determined in accordance with JIS Z2248 (2006) “Metallic materials-Bend test”. The conditions adopted in the example described later are as follows.

[0044] Specimen size: 15 mm×50 mm×0.5 mm

[0045] Test temperature: 23° C.

[0046] Indentation rate: 2.0 mm/min

[0047] Inter-fulcrum distance: 40 mm

[0048] Bending radius (indenter/lower fulcrum tip): R 5 mm

[0049] Specimen setting direction: A surface having high surface roughness is regarded as an indenter side, and a maximum load (N) is determined. Using the following expression, conversion into a bending strength is carried out.

[00001]$\begin{array}{cc}\sigma =\frac{M_{\max }}{Z}=\frac{F_{\max }.Math.L}{4}.Math.\text{/}.Math.\frac{{\mathrm{wt}}^2}{6}=\frac{3.Math.F_{\max }.Math.L}{2.Math.{\mathrm{wt}}^2}& \left[\mathrm{Expression}.Math..Math.1\right]\end{array}$

[0050] σ: bending strength (MPa), F: (bending) load (N), L: inter-fulcrum distance (mm), t: specimen thickness (mm), w: specimen width (mm), Z: section modulus*.sup.1 (mm.sup.3), M: bending moment*.sup.2 (N.Math.mm) [0051] *1: Section modulus Z=wt.sup.2/6 (value determined by only a shape of section) [0052] *2: Bending moment M=F.sub.max×L/4 (because pressure is applied to the center of the sample)

[0053] Next, the production method of the present invention will be described.

[0054] The method for producing a porous titanium-based sintered body of the present invention is a method for producing a porous titanium-based sintered body, comprising the step of placing a titanium-based powder having an average circularity of 0.85 or less and having D10 of 40 μm or more and D50 of 65 μm to 100 μm, the D10 and the D50 being obtained by particle size distribution measurement, in a mold by dry process without substantially applying pressure, and the step of sintering the powder at higher than 900° C. and 1000° C. or lower.

[0055] The average circularity of the titanium-based powder for use in the production method of the present invention is 0.85 or less. The average circularity of the titanium-based powder is preferably 0.83 or less. On the other hand, if the average circularity exceeds 0.85, the shape of the titanium-based powder comes too close to a sphere, and therefore, the bulk density becomes too high, and the porous titanium-based sintered body may become too dense.

[0056] In the present invention, the average circularity of the titanium-based powder is determined by the following method. Using an electron microscope, a perimeter (A) of a projected area of a particle is measured, and when a perimeter of a circle having the same area as the projected area is taken as (B), B/A is taken as a circularity. The average circularity is obtained by pouring particles together with a carrier liquid into a cell, photographing images of a large amount of particles by a CCD camera, measuring a perimeter (A) of a projected area of each particle and a perimeter (B) of a circle having the same area as the projected area from each particle image of 1000 to 1500 particles, calculating a circularity, and determining an average value of circularities of the particles.

[0057] As the shape of the particle comes close to a true sphere, the numerical value of the circularity increases, and the circularity of a particle having a shape of a perfect true sphere becomes 1. Contrary to this, as the shape of the particle becomes further away from a true sphere, the numerical value of the circularity decreases.

[0058] The titanium-based powder for use in the production method of the present invention is a titanium-based powder having D10 of 40 μm or more and D50 of 65 μm to 100 μm, the D10 and the D50 being obtained by particle size distribution measurement. The present inventors have acquired knowledge that when a titanium-based powder that is a crushed product is sintered at a high temperature, the sintered area of the titanium-based powder increases. That is to say, when a high strength is attempted to be attained while ensuring good porosity, average pore diameter and specific surface area, it is advantageous to utilize a titanium-based powder having a certain size. A fine powder is undesirable because the pores may be closed by the powder. In the present invention, therefore, D10 of the titanium-based powder is set to 40 μm or more. D10 of the titanium-based powder is preferably 42 μm or more, and more preferably 45 μm or more. In the present invention, D50 of the titanium-based powder is set to 65 μm to 100 μm. By using a titanium-based powder having this constitution, the porosity of the porous titanium-based sintered body can be increased, the average pore diameter thereof can be increased, and the specific surface area thereof can be increased. The lower limit side of D50 of the titanium-based powder is preferably 70 μm or more. The upper limit side of D50 of the titanium-based powder is preferably 90 μm or less, and more preferably 85 μm or less.

[0059] In the present invention, D10 and D50 indicate particle diameters by which volume-based cumulative distributions in the measurement of particle size distribution as determined by a laser diffraction/scattering method become 10% and 50%, respectively. In detail, the titanium-based powder particle size distribution is measured by the following method, and D10 and D50 are measured. That is to say, they are measured based on JIS Z8825:2013.

[0060] In the production method of the present invention, the titanium-based powder is placed in a mold by dry process without substantially applying pressure. By placing the titanium-based powder in a mold without substantially applying pressure, the titanium-based powder is bridged in a natural state, and a porous titanium-based sintered body having a high porosity can be obtained. The expression “bridged” referred to herein indicates that the powder forms an arch-shaped cavity. On the other hand, if the titanium-based powder is placed in a mold by wet process, the titanium-based powder accumulates while having anisotropy because of resistance of a fluid, and therefore, desired porosity and average pore diameter may not be obtained. Moreover, if the titanium-based powder is placed in a mold by wet process, the titanium-based powder may be filled densely up to a density equivalent to tap density. If the pressure applied to the upper surface of the titanium-based powder in a mold is too high when the titanium-based powder is placed in the mold, the porosity and the average pore diameter do not increase.

[0061] In the present invention, the expression “without substantially applying pressure” indicates that excepting a force applied to the titanium-based powder under the titanium-based powder's own weight when the titanium-based powder is filled in the mold or a force applied to the upper surface of the titanium-based powder in the mold when the titanium-based powder that has overflown and is present above the upper edge of the mold is levelled off after filling of the titanium-based powder in the mold, the pressure of a force intendedly applied to the upper surface of the titanium-based powder in the mold is 1×10.sup.−2 MPa/mm.sup.2 or less. The pressure applied to the upper surface of the titanium-based powder in the mold is a value obtained by dividing the force applied to the whole of the upper surface of the titanium-based powder-filled part of the mold by the area of the upper surface of the filled part. In the present invention, the expression “dry process” indicates that water or an organic solvent is not intendedly used.

[0062] A material of the mold for use in the present invention can be appropriately selected as long as the material does not react with the titanium-based powder, can withstand high temperatures and can be inhibited from thermal expansion. For example, quartz, alumina, graphite, carbon, cordient, indium oxide, calcia, silica, magnesia, zirconia, spinel, silicon carbide, aluminum nitride, boron nitride or mullite is preferable as the material of the mold. A more preferred material of the mold is quartz, alumina, carbon, calcia, magnesia, zirconia, boron nitride or the like by the reason of good workability.

[0063] In the production method of the present invention, the titanium-based powder is sintered at higher than 900° C. and 1000° C. or lower. By the sintering in this temperature range, an increase in strength of the porous titanium-based sintered body produced is achieved while ensuring a large average pour diameter of the porous titanium-based sintered body. The sintering temperature is the highest reaching temperature during sintering. If the sintering temperature is 900° C. or lower, the desired high strength cannot be attained even if the porosity, the average pour diameter and the specific surface area can be favorably ensured. The lower limit side of the sintering temperature is preferably 920° C. or higher, more preferably 930° C. or higher, and still more preferably 950° C. or higher. On the other hand, the upper limit side of the sintering temperature is 1000° C. or lower. Even if the sintering temperature is excessively raised, a special effect is hard to expect, and it is disadvantageous in terms of cost. Moreover, the shape of the titanium-based powder excessively collapses in some cases, and there is concern about lowering of a porosity, an average pore diameter and a specific surface area.

[0064] In the production method of the present invention, the sintering time for sintering the titanium-based powder is appropriately selected.

[0065] In the method for producing a porous titanium-based sintered body of the present invention, sintering of the titanium-based powder is usually carried out under reduced pressure. Examples of methods for sintering the titanium-based powder include:

[0066] (1) a method comprising placing the titanium-based powder in a mold, then installing pressure reducing means in the mold, tightly closing the mold, reducing the pressure inside the mold by the pressure reducing means, then removing the pressure reducing means while maintaining a state of reduced pressure, setting the mold in a sintering furnace, and heating the titanium-based powder to sinter the powder;

[0067] (2) a method comprising placing the titanium-based powder in a mold, then installing pressure reducing means in the mold, tightly closing the mold, setting the mold in a sintering furnace, reducing the pressure inside the mold by the pressure reducing means in the furnace, and heating the titanium-based powder to sinter the powder after terminating pressure reduction or while further continuing pressure reduction; and

[0068] (3) a method comprising placing the titanium-based powder in a mold, then setting the mold in a sintering furnace, reducing the pressure inside the furnace together with the mold, and heating the titanium-based powder to sinter the powder after terminating pressure reduction or while further continuing pressure reduction.

[0069] In the present invention, the pressure of an atmosphere in which the titanium-based powder is sintered is preferably 5.0×10.sup.−3 Pa or less. If the pressure of the atmosphere is too high, the titanium-based powder is oxidized by excess oxygen present in the atmosphere, and the sintering does not easily take place.

[0070] As the porous titanium-based sintered body of the present invention, one obtained by placing a titanium-based powder having an average circularity of 0.85 or less and having D10 of 40 μm or more and D50 of 65 μm to 100 μm, the D10 and the D50 being obtained by particle size distribution measurement, in a mold by dry process without substantially applying pressure, and sintering the powder at higher than 900° C. and 1000° C. or lower (hereinafter, also referred to as a porous titanium-based sintered body of a first embodiment of the present invention) can be mentioned.

[0071] The titanium-based power according to the porous titanium-based sintered body of the first embodiment of the present invention is the same as the titanium-based powder according to the porous titanium-based sintered body of the present invention. That is to say, the average circularity of the titanium-based powder according to the porous titanium-based sintered body of the first embodiment of the present invention is 0.85 or less. The average circularity of the titanium-based powder is preferably 0.83 or less. On the other hand, if the average circularity exceeds 0.85, the shape of the titanium-based powder comes too close to a sphere, and therefore, the bulk density becomes too high, and the porous titanium-based sintered body may become too dense.

[0072] The titanium-based powder according to the porous titanium-based sintered body of the first embodiment of the present invention is a titanium-based powder having D10 of 40 μm or more and D50 of 65 μm to 100 μm, the D10 and the D50 being obtained by particle size distribution measurement. The present inventors have acquired knowledge that when a titanium-based powder that is a crushed product is sintered at a high temperature, the sintered area of the titanium-based powder increases. That is to say, when a high strength is attempted to be attained while ensuring good porosity, average pore diameter and specific surface area, it is advantageous to utilize a titanium-based powder having a certain size. A fine powder is undesirable because the pores may be closed by the powder. In the present invention, therefore, D10 of the titanium-based powder is set to 40 μm or more. D10 of the titanium-based powder is preferably 42 μm or more, and more preferably 45 μm or more. In the present invention, D50 of the titanium-based powder is set to 65 μm to 100 μm. By using a titanium-based powder having this constitution, the porosity of the porous titanium-based sintered body can be increased, the average pore diameter thereof can be increased, and the specific surface area thereof can be increased. The lower limit side of D50 of the titanium-based powder is preferably 70 μm or more. The upper limit side of D50 of the titanium-based powder is preferably 90 μm or less, and more preferably 85 μm or less.

[0073] The porous titanium-based sintered body of the first embodiment of the present invention is one obtained by placing the titanium-based powder in a mold by dry process without substantially applying pressure, heating the powder under reduced pressure, preferably at 5.0×10.sup.−3 Pa or less, and thereby sintering the powder.

[0074] The sintering temperature of the titanium-based powder is higher than 900° C. and 1000° C. or lower. By the sintering in this temperature range, an increase in strength of the porous titanium-based sintered body is achieved. The sintering temperature is the highest reaching temperature during sintering. If the sintering temperature is 900° C. or lower, the desired high strength cannot be attained even if the porosity, the average pour diameter and the specific surface area can be favorably ensured. The lower limit side of the sintering temperature is preferably 920° C. or higher, more preferably 930° C. or higher, and still more preferably 950° C. or higher. On the other hand, the upper limit side of the sintering temperature is 1000° C. or lower. Even if the sintering temperature is excessively raised, a special effect is hard to expect, and it is disadvantageous in terms of cost. Moreover, the shape of the titanium-based powder excessively collapses in some cases, and there is concern about lowering of the porosity and the specific surface area.

[0075] The porous titanium-based sintered body of the first embodiment of the present invention is a porous titanium-based sintered body having a porosity of 50% to 75%, an average pore diameter of 23 μm to 45 μm, a specific surface area of 0.020 m.sup.2/g to 0.065 m.sup.2/g, and a bending strength of 22 MPa or more.

[0076] The porous titanium-based sintered body of the first embodiment of the present invention has a porosity of 50% to 75%, an average pore diameter of 23 μm to 45 μm, and a specific surface area of 0.020 m.sup.2/g to 0.065 m.sup.2/g.

[0077] In the present invention, by setting the porosity of the porous titanium-based sintered body of the first embodiment to 50% to 75%, a large specific surface area can be ensured while ensuring good gas permeability or liquid permeability. The lower limit side of the porosity of the porous titanium-based sintered body of the first embodiment of the present invention is preferably 55% or more. On the other hand, the upper limit side of the porosity of the porous titanium-based sintered body of the first embodiment of the present invention is preferably 70% or less, more preferably 68% or less, still more preferably 65% or less, and even more preferably 63% or less. A porosity of less than 50% means that the porous titanium-based sintered body is too dense. That is to say, there is concern that the gas permeability or the liquid permeability becomes insufficient. On the other hand, a porosity of more than 75% means that the porous titanium-based sintered body is too coarse. That is to say, there is concern about insufficient specific surface area or insufficient strength.

[0078] The average pore diameter of the porous titanium sintered body of the first embodiment of the present invention is 23 μm to 45 μm. By combining a high porosity with a large average pore diameter, good gas permeability or liquid permeability is ensured. The average pore diameter of the porous titanium sintered body of the first embodiment of the present invention is preferably 23 μm to 40 μm, and more preferably 23 μm to 35 μm. If the average pore diameter is less than 23 μm, there is concern about an excessive increase in pressure loss. If the average pore diameter exceeds 45 μm, there is concern about a decrease in contact area (specific surface area).

[0079] In the present invention, it is possible to set the specific surface area of the porous titanium-based sintered body of the first embodiment to 0.020 m.sup.2/g to 0.065 m.sup.2/g, and the specific surface area is made compatible with good gas permeability or liquid permeability. The lower limit side of the specific surface area of the porous titanium-based sintered body of the first embodiment of the present invention is preferably 0.025 m.sup.2/g or more, and more preferably 0.030 m.sup.2/g or more. The upper limit side of the specific surface area of the porous titanium-based sintered body of the first embodiment of the present invention is preferably 0.060 m.sup.2/g or less, and more preferably 0.055 m.sup.2/g or less. The specific surface area has great influence on the heat removal or the reaction efficiency. If the specific surface area is less than 0.020 m.sup.2/g, the amount of a catalyst supported becomes insufficient, so that there is concern about an excessive decrease in the reaction area, and because the sites that come into contact with a gas or a liquid excessively decrease, there is also concern about, for example, insufficient cooling during heat removal. On the other hand, if the specific surface area is more than 0.065 m.sup.2/g, the sites that come into contact with a gas or a liquid excessively increase, and therefore, there is concern about deterioration of gas permeability or liquid permeability.

[0080] The bending strength of the porous titanium-based sintered body of the first embodiment of the present invention is 22 MPa or more. In the porous titanium-based sintered body of the first embodiment of the present invention, the sintered area of the titanium-based powder that is a raw material is appropriately ensured, and therefore, a bending strength of 22 MPa or more can be attained. The bending strength of the porous titanium-based sintered body of the first embodiment of the present invention is preferably 25 MPa or more. The upper limit side of the bending strength of the porous titanium-based sintered body of the first embodiment of the present invention is not particularly limited, but it is preferably, for example, 65 MPa or less. The upper limit side of the bending strength of the porous titanium-based sintered body of the first embodiment of the present invention may be 45 MPa or less, or may be 35 MPa or less.

[0081] The porous titanium-based sintered body of the first embodiment of the present invention is one obtained by placing a titanium-based powder having an average circularity of 0.85 or less and having D10 of 40 μm or more and D50 of 65 μm to 100 μm, the D10 and the D50 being obtained by particle size distribution measurement, in a mold by dry process without substantially applying pressure, and sintering the powder at higher than 900° C. and 1000° C. or lower, preferably 920° C. or higher and 1000° C. or lower, more preferably 930° C. or higher and 1000° C. or lower, and therefore, it has a structure in which the area of a connection part of the titanium-based powder is large and the pore diameter is large, and has a high porosity, a large average pore diameter, a large specific surface area, a high strength, and good gas permeability or liquid permeability.

[0082] The electrode of the present invention is an electrode comprising the porous titanium-based sintered body of the present invention.

[0083] Since the porous titanium-based sintered body of the present invention is excellent in porosity, average pore diameter and specific surface area, it is useful as an electrode. Since the porous titanium-based sintered body of the present invention has attained a high strength, it does not easily undergo buckling or the like and is excellent in handling property in the fabrication of an electrode. The porous titanium-based sintered body of the present invention is preferable as an electrode of a fuel battery or an electrode of a large storage battery.

[0084] The present invention will be described in more detail with reference to an example, but this example is just an example and does not limit the present invention.

EXAMPLE

[0085] In the following example, a titanium powder produced by a hydrogenation/dehydrogenation method and having a shape of a crushed product was used as a titanium-based powder. An average circularity, D10 and D50 of the titanium-based powder used are set forth in Table 1.

[0086] In the measurement, the average circularity was determined using PITA-3 (manufactured by SEISHIN ENTERPRISE CO., LTD.). D10 and D50 were determined in accordance with JIS:Z8825:2013 using a measuring device: LMS-350 (manufactured by SEISHIN ENTERPRISE CO., LTD.).

[0087] A difference of titanium powders between No. 1 and No. 4 will be described. Regarding both the titanium powders of No. 1 and No. 4, particles having particle diameters of more than 150 μm were removed using a sieve. Regarding No. 1, particles having particle diameters of less than 40 μm were further removed using a sieve, but regarding No. 4, particles having particle diameters of less than 40 μm were not removed.

EXAMPLE AND COMPARATIVE EXAMPLES

[0088] Each titanium-based powder was filled in a quartz mold under the drying and no-pressure application conditions, and a titanium-based powder having overflown and present above the upper edge of the mold was leveled off. That is to say, any excess force other than a force of leveling operation was not applied to the titanium-based powder. Thereafter, in environment in which the degree of vacuum was set to at least 3.0×10.sup.−3 Pa, the mold filled with the titanium-based powder was placed, then the powder was sintered up to a sintering temperature shown in Table 1 at a temperature rise rate of 15° C/min, and sintering was carried out for 1 hour. After the sintering, the resulting sinter was cooled down to room temperature by furnace cooling, thereby obtaining a porous sintered body of the titanium-based powder.

[0089] The resulting porous titanium-based sintered body was subjected to analyses to determine a porosity, an average pore diameter, a specific surface area and a bending strength. The results are set forth in Table 1.

[0090] Regarding the measurement of the porosity, the aforesaid calculation method (calculation backward from relative density) was used to determine the porosity. The average pore diameter was measured by a strain-gauge type pressure measuring method using a mercury penetration measuring device manufactured by Micromeritics Instrument Corporation. The specific surface area was measured by a volumetric method using, as an adsorption gas Kr, BELSORP-Max manufactured by MicrotracBEL Corp. Regarding the bending strength, a maximum load was measured by a method whose outline is shown in FIG. 2, using a universal testing machine manufactured by SHIMADZU CORPORATION, and it was converted into a bending strength.

TABLE-US-00001 TABLE 1 Titanium-based powder properties Sintering Average pore Specific Bending Average D10 D50 temperature Porosity diameter surface area strength No. circularity (μm) (μm) (° C.) (%) (μm) (m.sup.2/g) (MPa) Note 1 0.82 45 76 950 60 27 0.034 28.8 invention example 2 0.82 45 76 900 59 29 0.038 18.9 comparative example 3 0.77 22 36 900 62 16 0.083 36.9 comparative example 4 0.79 34 62 950 64 17 0.049 19.0 comparative example

[0091] As shown in Table 1, No. 1 that was the invention example attained a high strength while ensuring a high porosity, an average pore diameter and a specific surface area. In FIG. 1, a result of optical microscope observation of the invention Example 1 is shown. In the invention Example 1, many portions in each of which the sintered area of the titanium-based powder was large (portions illustrated by white circles) were present, and therefore, it could be confirmed that the sintering proceeded more and the bending strength increased.

[0092] No. 2 that was a comparative example could not attain a high bending strength. In comparison between the result of No. 1 and that of No. 2, it is thought that control of the sintering temperature in the production of the porous titanium-based sintered body is important.

[0093] From the viewpoint of gas permeability or liquid permeability, there is room for improvement in No. 3 that was a comparative example because the specific surface area was too large. In comparison between No. 1 and No. 3, it is thought that control of the particle size distribution of the titanium-based powder that is a raw material is important.

[0094] No. 4 that was a comparative example was a sintered body obtained by sintering the titanium-based powder containing a fine powder of less than 40 μm. There is concern that desired gas permeability or liquid permeability cannot be ensured because of a small average pore diameter. In comparison with No. 1, there is room for increase in strength. In comparison between No. 1 and No. 4, the importance of controlling the quantity of fine powder was exhibited.