HYBRID FOSSIL FUEL AND SOLAR HEATED SUPERCRITICAL CARBON DIOXIDE POWER GENERATING SYSTEM AND METHOD

Abstract

The present disclosure provides an integrated power generating system and method that combines combustion power generation with solar heating. Specifically, a closed cycle combustion system utilizing a carbon dioxide working fluid can be increased in efficiency by passing at least a portion of a carbon dioxide working fluid through a solar heater prior to passage through a combustor.

Claims

1. A method of generating power, the method comprising: combusting a solid fuel in the presence of O.sub.2 and CO.sub.2 in a partial oxidation combustor, the solid fuel, O.sub.2, and CO.sub.2 being provided in ratios such that the solid fuel is only partially oxidized to produce a partially oxidized combustion product stream comprising an incombustible component, CO.sub.2, and one or more of H.sub.2, CO, CH.sub.4, H.sub.2S, and NH.sub.3; combusting a carbonaceous fuel comprising at least a portion of the partially oxidized combustion product stream in a primary combustor with oxygen in the presence of a pressurized CO.sub.2 containing stream to provide a heated CO.sub.2 containing stream, the heated CO.sub.2 containing stream being at a temperature of about 500 C. or greater and a pressure of about 150 bar (15 MPa) or greater, the heated CO.sub.2 containing stream comprising one or more combustion products; passing the heated CO.sub.2 containing stream through a turbine to expand the heated CO.sub.2 containing stream, generate power, and form a turbine exhaust stream comprising CO.sub.2; cooling the turbine exhaust stream comprising CO.sub.2 in a heat exchanger to form a cooled turbine exhaust stream; pressurizing CO.sub.2 from the cooled turbine exhaust stream to form the pressurized CO.sub.2 containing stream; heating the pressurized CO.sub.2 containing stream in the heat exchanger; further heating the pressurized CO.sub.2 containing stream with a solar heater; and passing the pressurized and solar heated CO.sub.2 containing stream to the primary combustor.

2-6. (canceled)

7. The method of claim 1, wherein a portion of the pressurized CO.sub.2 containing stream is heated with supplemental heat after the pressurizing step and prior to being heated by the solar heater.

8. (canceled)

9. The method of claim 1, further comprising passing the pressurized and solar heated CO.sub.2 containing stream from the solar heater through a combustion heater prior to passage into the primary combustor.

10. (canceled)

11. The method of claim 1, further comprising purifying the cooled turbine exhaust stream from the heat exchanger in a separator by separating one or more of the combustion products from the CO.sub.2.

12-14. (canceled)

15. The method of claim 1, wherein the solid fuel, O.sub.2, and CO.sub.2 are provided in ratios such that the temperature of the partially oxidized combustion product stream is sufficiently low that all of the incombustible component in the stream is in the form of solid particles.

16. The method of claim 1, further comprising passing the partially oxidized combustion product stream through one or more filters.

17. The method of claim 11, wherein the solid fuel comprises coal, lignite, biomass, or petroleum coke.

18. The method of claim 17, wherein the solid fuel is in a particulate form and is slurried with CO.sub.2.

19. The method of claim 1, wherein the amount of carbonaceous fuel and oxygen provided to the primary combustor is controlled such that the heat of combustion in the primary combustor is inversely related to heat available from the solar heater for heating the pressurized CO.sub.2 containing stream passing through the solar heater.

20. The method of claim 19, wherein the amount heat available from the solar heater varies by greater than 10% over a single solar cycle.

21. The method of claim 20, wherein the amount of carbonaceous fuel and oxygen provided to the combustor is controlled such that the temperature of the CO.sub.2 containing stream passed to the turbine varies by less than 10% over the single solar cycle.

22. The method of claim 1, further comprising splitting the pressurized CO.sub.2 containing stream exiting the heat exchanger prior to heating with the solar heater such that a first portion of the pressurized CO.sub.2 containing stream continues to the solar heating step and a second portion of the pressurized CO.sub.2 containing stream passes to the primary combustor without first being heated by the solar heater.

23-25. (canceled)

26. A power generating system comprising: a solar heater; a primary combustor in fluid communication with the solar heater; a partial oxidation combustor having an outlet in fluid communication with an inlet of the primary combustor; a power producing turbine in fluid communication with the primary combustor; a heat exchanger in fluid communication with the power producing turbine and the solar heater; and at least one compressor in fluid communication with the heat exchanger.

27. The power generating system of claim 26, further comprising a combustion heater positioned between and in fluid communication with the solar heater and the primary combustor.

28. The power generating system of claim 26, further comprising a separator positioned between and in fluid communication with the heat exchanger and the at least one compressor.

29. The system of claim 26, further comprising an air separation plant.

30. (canceled)

31. The system of claim 26, wherein the heat exchanger comprises a series of two or more heat exchange units.

32. (canceled)

33. The system of claim 26, further comprising a filter positioned between and in fluid communication with the outlet of the partial oxidation combustor and the inlet of the primary combustor.

34. The system of claim 26, further comprising a splitter positioned downstream from and in fluid communication with a hot end outlet of the heat exchanger, said splitter having a first outlet in fluid communication with the partial oxidation combustor and a second outlet in fluid communication with the solar heater.

35. The system of claim 26, further comprising a splitter positioned downstream from and in fluid communication with a hot end outlet of the heat exchanger, said splitter having a first outlet in fluid communication with the primary combustor and a second outlet in fluid communication with the solar heater.

36. The system of claim 26, further comprising a flow valve positioned downstream from and in fluid communication with a hot end outlet of the heat exchanger, said flow valve having a first outlet in fluid communication with the primary combustor and a second outlet in fluid communication with the solar heater, said flow valve being adapted to alternate flow between the solar heater and the primary combustor.

37-42. (canceled)

Description

BRIEF DESCRIPTION OF THE FIGURES

[0026] FIG. 1 is a flow diagram illustrating a power generating system and method according to one embodiment of the present disclosure wherein a solar heater is integrated with a combustor and a turbine;

[0027] FIG. 2 is a flow diagram illustrating a power generating system and method according to one embodiment of the present disclosure including a primary combustor and a solar heater;

[0028] FIG. 3 is a flow diagram illustrating a power generating system and method according to further embodiment of the present disclosure wherein a partial oxidation combustor is included in addition to a primary combustor;

[0029] FIG. 4 is a flow diagram illustrating a power generating system and method according to another embodiment of the present disclosure wherein a splitter is included to split a recycle CO.sub.2 stream between a solar heater and a primary combustor;

[0030] FIG. 5 is a flow diagram illustrating a power generating system and method according to still a further embodiment of the present disclosure wherein a splitter is included to split a recycle CO.sub.2 stream into three streams passing to a solar heater, a partial oxidation combustor, and a primary combustor;

[0031] FIG. 6 is a flow diagram illustrating a power generating system and method according to yet another embodiment of the present disclosure wherein a two position flow valve is included to alternate a recycle CO.sub.2 stream between a solar heater and a primary combustor;

[0032] FIG. 7 is a flow diagram illustrating a power generating system and method according to still a further embodiment of the present disclosure wherein a two position flow valve is included the alternate a recycle CO.sub.2 stream between a solar heater and a combustor flow, which in turn is split between a partial oxidation combustor and a primary combustor; and

[0033] FIG. 8 is a solar cycle heating chart showing the relative heating supplied by the various heating components of a system according to certain embodiments of the present disclosure during an exemplary, single solar cycle.

DETAILED DESCRIPTION OF THE DISCLOSURE

[0034] The invention now will be described more fully hereinafter through reference to various embodiments. These embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. Indeed, the invention may be embodied in many different forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided so that this disclosure will satisfy applicable legal requirements. As used in the specification, and in the appended claims, the singular forms a, an, the, include plural referents unless the context clearly dictates otherwise.

[0035] US Patent Publication No. 2011/0179799, as already noted above, describes power production systems and methods wherein a CO.sub.2 cycle is utilized. In some embodiments, a CO.sub.2 circulating fluid can be provided in a combustor suitable for high temperature and high pressure conditions along with a carbonaceous fuel (such as NG, coal, syngas, biomass, etc.) and an oxidant, such as air or O.sub.2. Such systems and methods can comprise a combustor that operates at high temperatures (e.g., about 500 C. or greater, about 750 C. or greater, about 1,000 C. or greater, or about 1,200 C. or greater), and the presence of the circulating fluid can function to moderate the temperature of a fluid stream exiting the combustor so that the fluid stream can be utilized in energy transfer for power production. The nature of the reaction process at high temperatures and pressures, and with high recycle CO.sub.2 concentrations, can provide for excellent process efficiency and reaction speeds. The combustion product stream can be expanded across at least one turbine to generate power. The expanded gas stream then can be cooled to remove combustion by-products and/or impurities from the stream, and heat withdrawn from the expanded gas stream can be used to heat the CO.sub.2 circulating fluid that is recycled back to the combustor.

[0036] In the cooled state, the combustion stream can be processed for removal of water and other contaminants to provide an essentially pure CO.sub.2 stream for recycle back through the combustor with the materials for combustion. The purified CO.sub.2 stream typically is in a gaseous state, and it is beneficial to subject the stream to the necessary conditions such that the CO.sub.2 is a supercritical state. For example, after the combustion stream has been expanded through a turbine for power generation, cooled, and purified to comprise essentially pure CO.sub.2 (e.g., at least 95% by mass, at least 97% by mass, or at least 99% by mass CO.sub.2), the resultant recycle CO.sub.2 stream can be compressed to increase the pressure thereof, such as to about 80 bar (8 MPa). A second compression step can be used to increase the pressure to approximately the pressure in the combustore.g., about 200 bar (20 MPa), about 250 bar (25 MPa), or about 300 bar (30 MPa). In between the compression steps, the CO.sub.2 stream can be cooled to increase the density of the stream so as to reduce the energy input required to pump the stream to the higher pressure. The finally pressurized recycle CO.sub.2 stream can then be further heated and input back into the combustor.

[0037] Although the above-described power generating system and method provides increased efficiency over conventional power generation systems and methods (and does so while simultaneously capturing the produced carbon), the systems and methods of the present disclosure can further increase cycle efficiency through combination with a concentrated solar power (CSP) system. The CSP system can provide heating of the recycle CO.sub.2 stream during times of sufficient available sunlight as an alternative to using the combustor in the combustion cycle or the CSP system can provide supplemental heating of the recycle CO.sub.2 stream to reduce the fuel requirements of the combustor in the combustion cycle.

[0038] A CSP system useful according to the present disclosure can include any solar thermal collector adapted to concentrate solar power sufficiently to produce the necessary heating for a working fluid in a power generating system, such as described herein. Preferably, a high temperature solar collector can be used. One non-limiting example of a solar collector system that can be utilized for concentrating solar power according to the present disclosure is a parabolic trough wherein a series of curved, mirrored troughs can be used to reflect the direct solar radiation onto a collector tube containing a fluid (also called a receiver, absorber, or collector) running the length of the trough and positioned at the focal point of the reflectors. The trough is parabolic along one axis and linear in the orthogonal axis. The trough can be positionally adjusted daily and/or seasonally to maximize solar radiation collection. The absorber fluid can flow to a central heater. Power towers (also known as central tower power plants or heliostat power plants) are another example and can utilize a heliostat field to focus concentrated sunlight on a receiver, which typically sits atop a tower in the center of the field. In such systems, the heliostats can be positioned in a vertical array (e.g., a dish or parabolic configuration) to focus the solar power to a heat collector on a tower. Fresnel reflectors are a further example of useful solar concentrating technology that can be used according to the present disclosure.

[0039] In certain embodiments of the present disclosure, a CSP system can comprise solar concentrator and a solar heater. Generally, the solar concentrator can comprise heliostats, mirrors, lenses, or the like as noted above for gathering and concentrating solar radiation. The solar heater can comprise one or more components adapted to transfer heat from the collected and concentrated solar radiation and/or to convert the heat to work. For example, the solar heater can comprise a heat sink wherein the heat is stored and wherefrom the heat can be transferred to another material or fluid, such as a CO.sub.2 containing stream that can be passed therethrough. In other embodiments, the solar heater can comprise a solar cycle working fluid (e.g., a CO.sub.2 containing stream, a molten salt fluid, or the like). Such working fluid can pass through a collector tube as noted above for heating or can be present only in the solar heater for heating by the collected and concentrated solar radiation (e.g., in a power tower). The solar heater thus can comprise heat transfer components useful to transfer heat from the solar cycle working fluid to another material or fluid, such as a CO.sub.2 containing stream. In such embodiments, the term solar heater can encompass a discrete unit having the solar cycle working fluid passing therethrough and being adapted for passage of the CO.sub.2 containing stream (as an example) therethrough in a heat exchange relationship. The term solar heater also can encompass a more expansive system whereby the solar cycle working fluid can be passed from a heat collection portion to a heat transfer portion where heat from the solar cycle working fluid can be passed to another material or fluid, as already described.

[0040] In various embodiments, methods of generating power according to the present disclosure can comprise passing a CO.sub.2 containing stream from a primary combustor through a turbine to expand the CO.sub.2 containing stream, generate power, and form a turbine exhaust stream comprising CO.sub.2. The turbine exhaust stream comprising CO.sub.2 can be cooled in a heat exchanger to form a cooled turbine exhaust stream. The method further can comprise pressurizing CO.sub.2 from the cooled turbine exhaust stream to form a pressurized CO.sub.2 containing stream, and this stream can be heated in the heat exchanger. The re-heated, pressurized CO.sub.2 containing stream can be further heated with a solar heater, which can include passing the pressurized CO.sub.2 containing stream itself through the solar heater or can include heat exchange between the pressurized CO.sub.2 containing stream and a solar heating cycle working fluid (e.g., a molten salt fluid or a separate CO.sub.2 stream). Further, the method can comprise passing the pressurized and solar heated CO.sub.2 containing stream to the primary combustor.

[0041] A power generating system according to the present disclosure is illustrated in the diagram of FIG. 1. As seen therein, the system generally comprises a solar heater 90 that is in fluid communication with a primary combustor 10 that in turn is in fluid communication with a turbine 20. In use, a gaseous fuel stream 7 (or other fuel type as further discussed herein) is introduced to the primary combustor along with an oxygen stream 5 and a CO.sub.2 containing stream 92. The fuel can be combusted with the oxygen in the primary combustor with the CO.sub.2 present as a working fluid that can be recycled through a closed system. A combustor exit stream 12 comprising CO.sub.2 and any products of combustion and being pressurized can be passed to the turbine wherein the combustor exit stream is expanded to generate power and form a turbine exhaust stream 22. Depending upon the nature of the turbine exhaust stream, it can be further processed, such as to remove combustion products that may be presente.g., water and/or excess CO.sub.2. Thus, a system according to the present disclosure can include a variety of further components as otherwise described herein. The CO.sub.2 from the further processed turbine exhaust stream can be input to the solar heater 90 as a CO.sub.2 recycle stream 34. The solar heater exit stream 92 thus can direct CO.sub.2 back to the combustor as the recycled working fluid.

[0042] In some embodiments, the combustor 10 can be completely shut down, such as during times of peak solar heat production. In such instances, the heat of the solar heater exit stream 92 can be sufficient to negate the need for heat of combustion from the combustor. As such, the circulating streams can be sufficiently free of impurities that a continuous cycle can be carried out without the need for cooling and removal of combustion products. Thus, the turbine exhaust stream 22 can be passed directly to the solar heater 90 and thus become the CO.sub.2 recycle stream. In other embodiments, the turbine exhaust stream can be passed through one or more pumps and/or compressors (see FIG. 2, for example) to pressurize the turbine exhaust stream prior to passage to the solar heater as the CO.sub.2 recycle stream.

[0043] Although the combustor 10 can be shut down if desired during peak solar heat production, it can be advantageous to operate the integrated system with all components in continuous operation. The heating provided by the solar concentrator system can vary across a single solar cycle. As used herein, a single solar cycle is intended to mean a single 24 hour day, which can be measured from any pointe.g., from midnight to midnight or noon to noon. During sunlight hours, solar heating will be available and typically will increase from sunrise to peak sunlight hours and then decrease as sunset approaches. Depending upon the nature of the solar heater and the availability of solar heat storage, the heat produced by the solar heater will increase and decrease over a single solar cycle. As such, the amount of heat available from the solar heater can vary over a single solar cycle, such as by 5% or more, 10% or more, 20% or more, 30% or more, or 50% or more. In some embodiments, the amount of heat available from the solar heater over a single solar cycle can vary by 5% to 75%, 10% to 70%, or 15% to 60%. Via continuous operation of the presently disclosed integrated system, however, a constant turbine inlet temperature can be maintained.

[0044] During periods of peak solar energy availability, solar radiation can be concentrated in the solar heater to provide up to 100% of the necessary heat for the CO.sub.2 circulated through the system to the turbine. As the available solar energy decreases, the amount of fuel and oxygen input to the combustor can be increased as needed to maintain the desired turbine inlet temperature. During periods when available solar energy is insufficient, if needed, the system can be operated on the combustion fuel alone. The systems and methods of the present disclosure further can allow for use of the combustion fuel during peak load periods and can return to a solar only or a mainly solar base load operation if the conditions warrant. Thus, the amount of combustion fuel and oxygen provided to the combustor can be controlled such that the heat of combustion in the primary combustor is inversely related to heat available from the solar heater for heating the CO.sub.2 containing stream passing therethrough. As discussed above, this can provide for maintaining an essentially constant temperature at the point of entry into the turbine. For example, the amount of carbonaceous fuel and oxygen provided to the combustor can be controlled such that the temperature of the CO.sub.2 containing stream passed to the turbine can vary by less than 2% over a single solar cycle. In other embodiments, the temperature of the CO.sub.2 containing stream passed to the turbine can vary over a single solar cycle by less than 5%, less than 10%, or less than 15%. In further embodiments, the temperature of the CO.sub.2 containing stream passed to the turbine can vary over a single solar cycle by about 2% to about 15%, about 3% to about 12%, or about 5% to about 10%.

[0045] Operation of a system according to the present disclosure as discussed above can be advantageous for several reasons. For example, this can impart simplicity to the operation method in that complicated switching cycles between the solar heater and the primary combustor can be avoided. Moreover, the efficiency of the combustion system and method can be significantly increased. For instance, in an integrated system wherein about 25% of the total energy output is derived from solar energy (e.g., 6 peak hours of sunlight per day) and wherein the combustion cycle has a stand-alone efficiency (on natural gas fuel) of about 50%, then the average efficiency for a given 24 hour period of the integrated system using a natural gas fuel can be about 66%.

[0046] Certain embodiments of the system and method of the present disclosure are illustrated in the flow diagram provided in FIG. 2. In relation to this figure, a gaseous fuel stream 3 is pumped in pump 6 to form a pressurized gaseous fuel stream 7 that is directed to the primary combustor 10. In one example, the gaseous fuel can be natural gas; however, other gaseous fuels can be used, such as syngas. Further, liquid fuels can be used. In the embodiments encompassed by FIG. 2, an oxygen stream 5 from an air separation plant 110 is also directed to the combustor. The air separation plant can be used for providing purified oxygen from an air source 1. For example, the oxygen stream can comprise oxygen in a purity of about 95% molar or greater, about 97% molar or greater, or about 99% molar or greater. In the combustor, the fuel is combusted with the oxygen in the presence of a CO.sub.2 recycle stream to form a combustor exit stream 12, which, in this embodiment, comprises the CO.sub.2 working fluid and any combustion products, such as water and/or CO.sub.2.

[0047] The primary combustor can be any combustor suitable for combustion at the required temperature and pressure including, but not limited to a transpiration cooled combustor. A CO.sub.2 recycle stream passed to the combustor can be provided at a pressure of about 150 bar (15 MPa) or greater, about 200 bar (20 MPa) or greater, about 250 bar (25 MPa) or greater, or about 300 bar (30 MPa) or greater. In other embodiments, the pressure can be about 150 bar (15 MPa) to about 400 bar (40 MPa), about 200 bar (20 MPa) to about 380 bar (38 MPa), or about 250 bar (25 MPa) to about 350 bar (35 MPa). Combustion in the primary combustor can be carried out at a temperature, for example, of about 500 C. or greater, about 600 C. or greater, or about 700 C. or greater. In other embodiments, combustion can be carried out at a temperature of about 500 C. to about 1800 C., about 550 C. to about 1600 C., or about 600 C. to about 1200 C. In other embodiments, even further temperature ranges can be used, as otherwise described herein. In various embodiments, the CO2 in the combustor exit stream 12 can be in a supercritical state.

[0048] The combustor exit stream comprising CO.sub.2 is passed into a power generating turbine 20 that produces electrical power via a generator 25. The power generation method can be characterized by the pressure ratio across the turbine. Specifically, the ratio of the pressure of the combustor exit stream (entering the turbine) to the pressure of the turbine exhaust stream comprising CO.sub.2 (exiting the turbine) can be about 12 or less, about 10 or less, or about 8 or less. In other embodiments, the pressure ratio can be about 4 to about 12, about 5 to about 10, or about 6 to about 10.

[0049] The turbine exhaust stream 22 exiting the turbine 20 can be cooled by passage through a heat exchanger 30 to reduce the temperature thereof. This can be particularly useful to allow for separation of any impurities (e.g., combustion products) from the turbine exhaust stream. The heat exchanger (which can be characterized as a combustion product heat exchanger in some embodiments) can, in some embodiments, be a multi-stage heat exchanger or a series to two or more, preferably three, serial heat exchange units. In such series, the first serial heat exchange unit (passing from hot end to cold end) can transfer heat over a high, broad temperature rangee.g., from the turbine outlet temperature to the range of about 150 C. to about 200 C. The second serial heat exchange unit can transfer heat over a middle, narrower temperature rangee.g., from the exit temperature of the first serial heat exchange unit to the range of about 80 C. to about 140 C. The third serial heat exchange unit can transfer heat over a low temperature rangee.g., the range of about 20 C. to about 75 C. Such ranges likewise can apply to fluids passed from the cold end to the hot end of each heat exchange units in the series. Such series can be beneficial in that added heating of the CO.sub.2 recycle stream passing from the cold end of the serial heat exchange units to the hot end of the heat exchange units can be input at a defined point. For example, the stream exiting the third serial heat exchange unit and entering the second serial heat exchange unit can be split, and one fraction can enter the second serial heat exchange unit while the other fraction is heated from an external source, such as the heat of compression captured from an air separation plant. The higher heated fraction can then be joined with the stream exiting the second serial heat exchange unit and entering the first serial heat exchange unit. Such added heat can be beneficial to bring the temperature of the CO.sub.2 recycle stream to within a preferable threshold relative to the temperature of the turbine exhaust stream. Specifically, the CO.sub.2 recycle stream can be heated to within 50 C. or less, 40 C. or less, or 30 C. or less of the temperature of the turbine exhaust stream.

[0050] The cooled turbine exhaust stream 32 exiting the heat exchanger 30 preferably comprises CO.sub.2 in a gaseous state and can be passed through a low temperature cooler 40 (e.g., a water cooler), which can be useful to cool the turbine exhaust stream to near ambient temperature. In particular embodiments, the low temperature cooler can cool the gaseous CO.sub.2 stream to a temperature of about 50 C. or less, about 40 C. or less, or about 30 C. or less. Such component of the system in particular can be optional. The low temperature output stream 42 can be passed into a separator 50, which, in the illustrated embodiment is particularly a water separator. Thus, water stream 54 is withdrawn therefrom, and a dried CO.sub.2 stream 52 exits the separator and can be passed through one or more pumps or compressors.

[0051] In the illustrated embodiments, the dried CO.sub.2 stream 52 is passed through a pump 60, which can be useful to increase the pressure of the dried CO.sub.2 stream to a pressure sufficient such that the CO.sub.2 is in a supercritical state. For example, the pressure can be increased to about 75 bar (7.5 MPa) or greater or about 80 bar (8 MPa) or greater. The resultant pump discharge CO.sub.2 stream 62 can be further cooled in a densifying cooler 70, which can be particularly useful to increase the density of the supercritical CO.sub.2 to reduce the energy requirement to compress the CO.sub.2 stream to a pressure useful for recycle to the combustor 10. The stream particularly can be densified to a density of about 200 kg/m.sup.3 or greater, about 400 kg/m.sup.3 or greater, about 600 kg/m.sup.3 or greater, or about 800 kg/m.sup.3 or greater. The densifier cooler discharge CO.sub.2 stream 72 then can be passed through a compressor 80 to increase the pressure thereof to a range that preferably is in the range described above in relation to the CO.sub.2 recycle stream for input to the combustor. The compressed CO.sub.2 discharge stream 82 can be split or can be returned in total to the combustion cycle. Beneficially, if desired, any excess CO.sub.2 (e.g., CO.sub.2 resulting from combustion) can be withdrawn as a high pressure CO.sub.2 pipeline stream 84i.e., under conditions suitable for input to a pipeline. Any desired use of the withdrawn CO.sub.2 (e.g., enhanced oil recovery, sequestration, etc.) is encompassed by the present disclosure.

[0052] The compressed CO.sub.2 discharge stream (recycle fraction) 86 can be passed back through the heat exchanger 30 to heat the CO.sub.2 containing stream to a temperature that is at or near the temperature of the turbine discharge stream. In particular embodiments, the temperature of the recycle CO.sub.2 stream exiting the heat exchanger can differ from the temperature of the turbine discharge stream by only about 50 C. or less. If desired, additional heating can be input to the CO.sub.2 containing stream before or during passage through the heat exchanger. For example, heat derived from the adiabatic compression in the air separating unit 110 can be added to the CO.sub.2 containing stream. As illustrated, a high temperature heat transfer stream 112 can pass from the air separation plant to the heat exchange unit (e.g., to a stream passing into the heat exchanger or into one or more heat exchange units in a multi-stage heat exchanger), and a low temperature heat transfer stream 114 can pass from the heat exchanger back to the air separation plant.

[0053] The stream exiting the heat exchanger 30 can be characterized as being a CO.sub.2 recycle stream. As such, the CO.sub.2 recycle stream 34 can be at a pressure and/or temperature suitable for input to the combustor 10. In the illustrated embodiment, the CO.sub.2 recycle stream is first passed to a solar heater 90 that can be a single unit or can be a component of a CSP system, as already described above. As illustrated, solar energy rays 222 reflect from a solar concentrator 220, and the concentrated solar radiation 224 is collected in the solar heater. The CO.sub.2 recycle stream passing through the solar heater can be changed or unchanged depending upon the state of the CSP system.

[0054] As illustrated, a fluid stream is passed directly through the solar heater to recover heat directly from the concentrating system. In other embodiments, the working fluid stream (i.e., the recycle CO.sub.2 stream) can interface with a secondary working fluid (e.g., a solar cycle working fluid) in a heat exchange relationship. Such secondary working fluid can cycle through the solar concentrator system for heating, such as described above in relation to known solar thermal collectors. For example, a molten salt working fluid can be incorporated in the solar concentrator system, and the recycle CO.sub.2 stream entering the solar heater can receive heat from the molten salt working fluid.

[0055] As discussed above, during periods of sufficient solar collection, the solar heater can be heated to a temperature wherein the CO.sub.2 recycle stream passing therethrough is increased in temperature. At times of lesser solar collection, the solar heater can be at essentially the same temperature as the CO.sub.2 recycle stream exiting the heat exchanger, and the CO.sub.2 recycle stream may be neither heated nor cooled. At times of little or no solar collection, the solar heater can be increased in temperature by the passage of the CO.sub.2 recycle stream therethrough. Such can be beneficial in that the solar heater can be maintained at an essentially constant temperaturee.g., within about 5%, within about 10%, within about 20%, or within about 30% of the peak heating temperature of the solar heater. In known solar concentrating systems, the receiver typically cycles from very hot to much cooler during every solar cycle. This thermal cycling presents a design challenge to the receiver and can cause the receiver (i.e., the solar heater) to fail due to build up of thermal stresses day by day or require its design to be limited in temperature, which limits performance. In the noted embodiments of the present disclosure wherein a CO.sub.2 stream at or near the system operating temperature constantly flows through the receiver, daily temperature cycling can be avoided. The solar heater can thus be more reliable and can be built for higher temperatures, enabling higher efficiencies.

[0056] The solar heater exit stream 92 comprising recycle CO.sub.2 can, at some times, be at a temperature that is below the required input temperature for the primary combustor 10. Thus, in some embodiments, a combustion heater 100 can be positioned between the output of the solar heater and the input of the primary combustor. The combustion heater can, for example, combust a fraction of the gaseous fuel stream 7 or a separate fuel stream to provide low level heating needed to step up the temperature of the CO.sub.2 recycle fluid. The combustion heater exit stream 102 thus can be at a temperature required for input to the primary combustor and can be passed directly into the primary combustor. As will be appreciated, the combustion heater can be optional and, when present, can be fired only during the off-peak solar power periods when the solar heater exit stream is below a required temperature threshold.

[0057] As illustrated in FIG. 2, the integrated system of the present disclosure can include a retractable heat shield 200. The heat shield can be deployed during off-peak solar power periods to resist heat loss from the solar heater 90 while the solar concentrator 220 is supplying insufficient heating to maintain the high temperature required for the solar heater. The heat shield can comprise any material that is beneficial for resisting radiative losses from the solar heater and/or providing reflective heatingi.e., reflecting radiative losses back to the solar heater. The heat shield can be retractable so that, during peak solar power periods, all available solar radiation can be directed to the solar heater to maximize heat capacity.

[0058] A system and method according to the present disclosure also can encompass heat storage to maximize heat input from the solar heater. In certain embodiments, the solar heater and associated concentrating system can provide only a portion of the total heat required for the power generating system and method. Thus, it can be useful to maintain a constant, minimum flow of the combustion fuel into the primary combustor for the necessary minimum heating required. In some embodiments, however, the solar heater and its associated concentrating system can provide excess heating beyond that needed for operating conditions of the overall power generating system and method. In such embodiments, the disclosed system and method can include one or more heat storage components, such as a heated CO.sub.2 store or a heated molten salt store. The stored heat (e.g., in a CO.sub.2 storage tank or molten salt storage tank) then can be drawn upon during non-peak solar heating periods to further supplement the heating from the primary combustor and to conserve the excess heat produced by the solar heater during peak solar heating periods. Calculations based on an irradiation rate in the southwest United States of about 2,063 kWh/m.sup.2, for example, have shown that a system according to certain embodiments of the present disclosure can operate at peak solar heating periods on 100% solar-derived heating, and the total solar heat input to the system can be approximately 32.9% of the system capacity.

[0059] Although the present disclosure is discussed in relation to FIG. 2 as utilizing a gaseous or liquid fuel, the integrated system and method can also utilize solid fuels, such as coal, lignite, biomass, waste, and petroleum coke. In such embodiments, it can be useful to include a pre-combustor for the solid fuel that provides an output stream of combustible products that can be combusted in the primary combustor. Exemplary embodiments are illustrated in FIG. 3. As seen therein, oxygen stream 5 can be split, and a POX oxygen stream 354 can be input to a partial oxidation (POX) combustor 360 along with a pressurized, particularized fuel slurry 332. To prepare the slurry, a solid fuel stream 305 (e.g., coal) is ground in a mill 310 to provide a particularized solid fuel stream 312, which is slurried in a mixer 320 powered by a generator 321. The particularized solid fuel is combined with a CO.sub.2 slurry fraction 74 withdrawn from the densifier cooler discharge CO.sub.2 stream 72 prior to pressurization through compressor 80. The CO.sub.2, which is preferably supercritical at this point, combines with the particularized solid fuel to form low pressure slurry 322, which is then passed through a slurry pump 330 to provide the pressurized, particularized fuel slurry 332 as in input to the POX combustor. Further input to the POX combustor is a CO.sub.2 recycle stream POX fraction 38, which can be taken from the CO.sub.2 recycle stream 34, such as via a splitter 35. Also exiting the splitter is the CO.sub.2 recycle stream solar heater fraction 36.

[0060] Combustion in the POX combustor provides a POX combustion stream 362, which can include a variety of components. In specific embodiments, the solid fuel, O.sub.2, and CO.sub.2 can be provided in ratios such that the partial oxidation of the solid fuel results in a combustion stream including an incombustible component, CO.sub.2, and one or more of H.sub.2, CO, CH.sub.4, H.sub.2S, and NH.sub.3. The POX combustion stream can be passed through a filter 370 to remove any incombustible components, such as ash. The resulting filtered POX combustion stream 374 can be directed to the primary combustor 10 as the combustion fuel and can include essentially only gaseous and/or liquid fuel materials. A filtered particulate stream 372 can be withdrawn from the filter for disposal.

[0061] In combination with the above disclosure, the embodiments encompassed by FIG. 3 essentially comprise the system components otherwise discussed in relation to FIG. 2 and the methods of use thereof can be carried out in a manner as discussed in relation to FIG. 2. In particular, the combustor exit stream 12 can be expanded across the turbine 20. The turbine exhaust stream 22 can be cooled through the heat exchanger 30. The cooled turbine exhaust stream can be further cooled, if desired, in a low temperature cooler 40, and the low temperature output stream 42 can have any water and other impurities separated therefrom in a separator 50 as impurity stream 54. The dried CO.sub.2 stream 52 can be pressurized in pump 60, and the pump discharge CO.sub.2 stream 62 can be cooled and densified in the densifying cooler 70. The densifier cooler discharge CO.sub.2 stream can be split, as discussed above, with a fraction 74 being directed to the mixer and the remaining fraction 72 being compressed in the compressor 80. The compressed CO.sub.2 discharge CO.sub.2 stream can be split. The compressed CO.sub.2 discharge stream (recycle fraction) 86 can be passed back to the heat exchanger, and a compressed CO.sub.2 discharge stream (filter fraction) 88 can be passed to the filter 370. Any remaining high pressure CO.sub.2 for pipeline can be withdrawn as discussed above. The CO.sub.2 recycle stream 34 exiting the hot end of the heat exchanger can be split at splitter 35 as noted above, with the respective fractions proceeding through the system as already discussed in relation to FIG. 3 above.

[0062] Returning to FIG. 2, the CO.sub.2 recycle stream 34 can be configured to pass through the solar heater 90 and the optional combustion heater 100 prior to passage into the primary combustor 10. In other embodiments, though, such as in FIG. 3, the CO.sub.2 recycle stream can be optionally split. Whereas the CO.sub.2 stream is split for input to the POX combustor in FIG. 3, such splitting can be used for directing CO.sub.2 flow to other components of the system. For example, as seen in FIG. 4, the CO.sub.2 recycle stream exiting the hot end of the heat exchanger 30 can pass through a combustion recycle CO.sub.2 splitter 135 to form two exit streams. A CO.sub.2 recycle solar heater split stream 136 can be directed through the solar heater 90, and a CO.sub.2 recycle primary combustor split stream 137 can pass directly to the primary combustor 10. The combustion recycle CO.sub.2 splitter can be, for example, a simple flow splitter that can have a fixed ratio division of the entering CO.sub.2 recycle stream or can have a variable division of the entering CO.sub.2 recycle stream. A fixed division can range from 10:90 solar heater flow to primary combustor flow to 90:10 solar heater flow to primary combustor flow on a mass flow basis. Other fixed ratio divisions (solar heater flow to primary combustor flow) can be 20:80 to 80:20, 30:70 to 70:30, or 40:60 to 60:40, on a mass flow basis. In embodiments where variable division is used, flow rates to the solar heater and the primary combustor can be varied based upon the heat producing status of the solar heater. For example, at peak solar heating periods, 50% or greater, 75% or greater, 80% or greater, or 90% or greater of the mass flow can be directed to the solar heater. During periods of lower solar heating, the majority of the mass flow (e.g., the same mass flow rates noted above) can be directed to the primary combustor. Automated control of the variable flow valve also can be encompassed. Specifically, heat output from the solar heater can be continuously or intermittently monitored and compared against a predetermined CO.sub.2 flow schedule. The mass flow of CO.sub.2 through the combustion recycle CO.sub.2 splitter can be automatically adjusted as the heat output from the solar heater increases and decreased through a solar cycle. For example, as available heat from the solar heater increases, the percentage of the CO.sub.2 mass flow can be automatically and proportionally increased to the CO.sub.2 recycle solar heater split and decreased to the CO.sub.2 recycle primary combustor split. As available heat from the solar heater increases, the percentage of the CO.sub.2 mass flow can be automatically and proportionally decreased to the CO.sub.2 recycle solar heater split and increased to the CO.sub.2 recycle primary combustor split. Thus, the systems of the present disclosure can include computerized control elements, including hardware and/or software adapted to measure available heat from the solar heater and adapted to open and close flow valves as necessary to adjust solar heater flow and primary combustor flow of the CO.sub.2 recycle stream.

[0063] Similar splitting of the CO.sub.2 recycle stream can be provided in embodiments wherein a solid fuel and a partial oxidation combustor are used. In FIG. 5, for example, a system substantially similar to that discussed above in relation to FIG. 3 is shown. The embodiment of FIG. 5 differs, however, in that the splitter 35 has been repositioned and is configured to split the CO.sub.2 recycle stream 34 into three separate streams. The CO.sub.2 recycle stream POX fraction 38 again passes directly to the POX combustor 360. A CO.sub.2 recycle stream solar heater fraction 36 likewise again passes directly to the solar heater 90. A dedicated CO.sub.2 recycle primary combustor fraction 37 now is provided directly to the primary combustor 10. As in relation to FIG. 5, the splitter in FIG. 5 can be configured for fixed ratio division or variable ratio division. In some embodiments, a majority of the CO.sub.2 recycle stream flow through the splitter (on a mass flow basis) can be directed to one of the three streams. In other words, a majority of the CO.sub.2 recycle stream flow through the splitter (on a mass flow basis) can be directed to the POX combustor, or majority of the CO.sub.2 recycle stream flow through the splitter (on a mass flow basis) can be directed to the solar heater, or majority of the CO.sub.2 recycle stream flow through the splitter (on a mass flow basis) can be directed to the primary combustor.

[0064] Returning to FIG. 2, if desired, the CO.sub.2 recycle stream 34 can be alternatively directed in total to either the solar heater 90 or the primary combustor 10. For example, as illustrated in FIG. 6, a two position flow valve 235 can be positioned in-line of the CO.sub.2 recycle stream. The flow valve can be placed in the solar heater position so that 100% of the CO.sub.2 recycle stream passes to the solar heater 90 in CO.sub.2 recycle solar heater loop 236. This configuration can be used during peak solar heating times so that all of the CO.sub.2 recycle stream is heated in the solar heater. In such embodiments, the combustion heater can particularly be absent as no additional heating of the solar heater exit stream 92 will be needed, and the solar heater exit stream then can proceed directly to the primary combustor. The flow valve alternatively can be placed in the primary combustor position so that 100% of the CO.sub.2 recycle stream passes to the primary combustor 10 in CO.sub.2 recycle primary combustor loop 237. This configuration can be used during off-peak solar heating times when insufficient heating can be provided in the solar heater to heat the CO.sub.2 recycle stream to the necessary temperature for entry to the primary combustor. The entirety of the CO.sub.2 recycle stream then can be heated in the primary combustor to the necessary temperature.

[0065] The use of a two position flow valve also can be used in embodiments wherein a solid fuel is combusted in a POX combustor prior to combustion of partial oxidation products in the primary combustor. For example, as seen in FIG. 7, a two position flow valve 235 is positioned in-line of the CO.sub.2 recycle stream 34. The flow valve can be placed in the solar heater position so that 100% of the CO.sub.2 recycle stream passes to the solar heater 90 in CO.sub.2 recycle solar heater loop 236. This configuration can be used during peak solar heating times so that all of the CO.sub.2 recycle stream is heated in the solar heater. In such embodiments, the combustion heater can particularly be absent as no additional heating of the solar heater exit stream 92 will be needed, and the solar heater exit stream then can proceed directly to the primary combustor. The flow valve alternatively can be placed in the combined combustors position so that 100% of the CO.sub.2 recycle stream passes to the two combustors in CO.sub.2 recycle combined combustors loop 239. This loop specifically can be split in a combustion recycle CO.sub.2 splitter 135 wherein a portion of the recycle CO.sub.2 can be passed to the POX combustor 360 in the CO.sub.2 recycle stream POX fraction 38, and a portion of the recycle CO.sub.2 can be passed to the primary combustor 10 in the CO.sub.2 recycle primary combustor fraction 37.

[0066] As can be seen from the foregoing, the integrated systems and methods of the present disclosure can be particularly beneficial for utilizing all available heating from a CSP system to improve the efficiency of a combustion power generating system and method. This is illustrated in FIG. 8, where the relative heating from the various sources in an integrated system and method utilizing natural gas as the fuel. Such heating sources are mapped across an exemplary solar cycle from midnight to midnight. As seen therein, during non-daylight times, the primary combustor is being fired such that a primary combustion period 401 accounts for most to all of the heating in the integrated system. As sunrise proceeds, the primary combustion period can cease (although a more gradual decrease can occur) while the solar heating period 403 increases. During the time that solar heating is increasing as peak solar output approaches, the combustion heater can be fired to supplement heating, and a combustor heating period 405 can begin and gradually decrease. As peak solar output begins to wane, the combustor heater period can again increase until the point that solar heating is sufficiently low such that the primary combustion period begins and dominates heat production. During the primary combustor period, heat shield deployment 407 can be implemented to reduce heat loss from the solar heater.

[0067] Many modifications and other embodiments of the inventions set forth herein will come to mind to one skilled in the art to which these inventions pertain having the benefit of the teachings presented in the foregoing descriptions. Therefore, it is to be understood that the inventions are not to be limited to the specific embodiments disclosed and that modifications and other embodiments are intended to be included within the scope of the appended claims. Although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.