Method and system for filtration and filtration cake layer formation
09868079 · 2018-01-16
Assignee
Inventors
Cpc classification
C02F2209/10
CHEMISTRY; METALLURGY
Y02W10/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B01D29/00
PERFORMING OPERATIONS; TRANSPORTING
C02F2209/08
CHEMISTRY; METALLURGY
B01D29/64
PERFORMING OPERATIONS; TRANSPORTING
B01D29/62
PERFORMING OPERATIONS; TRANSPORTING
International classification
B01D29/64
PERFORMING OPERATIONS; TRANSPORTING
C02F3/00
CHEMISTRY; METALLURGY
B01D29/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The present invention relates to filtration of liquids, such as water, containing substances that desirably should be removed from the liquids. The invention relates in particular to a filtration cake, being produced in situ of a cleaning system from substances that desirably should be filtered away. Particular preferred embodiments of the present invention relate to treatment of waste water, where an activated sludge is provided, which sludge contains activated sludge flocs. These flocs are accumulated on a fluid penetrable support structure to form a layer of flocs, which subsequently is compressed to form a filter of desired properties. The invention also relates to adapting waste wateror other liquids containing biodegradable substancesto optimized biodegradation and filtration by deflocculating flocs in an activated sludge during or before a biodegradation step and subsequently promoting re-flocculation prior to filtering or other means of biomass separation.
Claims
1. A method for providing a filtration cake of a filter element for filtering an activated sludge supernatant through the filtration cake comprising: an accumulation phase (A) comprising accumulating activated sludge flocs on a support structure by inducing a pressure difference to generate a flow of sludge, towards and through the support structure until a desired layer of flocs has been established on the support structure, wherein the pressure difference during the accumulation phase (A) is constant over time or increased over time and the fluid flowing through the support structure is recirculated during the accumulation phase (A), and a compression phase (B) comprising increasing the pressure difference to a level being sufficient to compress the layer of accumulated flocs on the support structure into a filtration cake of desired properties, wherein the compression phase is performed subsequent to the accumulation phase, wherein the filtration cake is provided solely by flocs present in the activated sludge, and the pressure increase initiating the compression phase (B) is a step-wise increase.
2. The method according to claim 1, further comprising determining, by measuring and/or calculating one or more parameters of turbidity, suspended solids concentration, total bacteria count, total organic carbon concentration, or chemical oxygen demand (COD) of the fluid after having passed through the support structure during the accumulation phase (A) and the compression phase (B) when a pre-defined criteria involving a measured and/or calculated parameters has been met.
3. The method according to claim 1, wherein the pressure difference during the accumulation phase (A) is below 1 bar and the pressure difference during the compression phase (B) is above the pressure difference of the accumulation phase (A) and below 2 bar.
4. The method according to claim 1, wherein the pressure difference during the accumulation phase (A) and/or the compression phase (B) is/are provided by a hydrostatic pressure difference by pressurizing the sludge and/or providing suction.
5. The method according to claim 1, wherein the pressure difference during the accumulation phase (A) and/or the pressure difference during the compression phase (B) is/are provided by a pump arranged in or downstream of an outlet of the filter element.
6. The method according to claim 1, wherein the support structure is cylindrically shaped, and the method comprises feeding sludge to the support structure and rotating the support structure to provide centrifugal forces, which move flocs in the sludge toward the support structure.
7. The method according to claim 6, wherein the accumulation phase (A) and the compression phase (B) comprise rotating the support structure at two different rotational speeds, wherein the rotational speed during the compression phase (B) is higher than the rotation speed during the accumulation phase (A).
8. The method according to claim 1, wherein the surface of the filtration cake is trimmed by a mechanical manipulation of the filtration cake.
9. The method according to claim 1, wherein the filtration cake is provided by flocs present in the activated sludge and coagulated substances provided by adding a coagulant to the sludge.
10. The method according to claim 1, further comprising arranging a backing layer on the support structure so that the filtration cake forms on the surface of the backing layer, wherein the backing layer is fixed or disposable.
11. The method according to claim 1, wherein the filter after having been in an operation mode (C) for a period, is renewed by removing the filtration cake by scraping or cleaning, and the accumulation phase (A) and compression phase (B) are carried out again.
Description
BRIEF DESCRIPTION OF THE FIGURES
(1) The invention and in particular preferred embodiments thereof will now be described in more detail with regard to the accompanying figures. The FIGS. show ways of implementing the present invention and are not to be construed as being limiting to other possible embodiments falling within the scope of the attached claim set.
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(9) and
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DETAILED DESCRIPTION OF EMBODIMENTS
(11) With reference to
(12)
(13) A number of filter elements 5 may be arranged submerged in the liquid inside the compartment 2 in zone I in the region of an outlet 11 for out letting liquid, such as surplus of activated sludge, from the compartment 9. The location of the outlet 11 can be different from what is disclosed in
(14) With reference to
(15) One aim of the invention is to remove biodegradable substances contained in waste water. In many of the preferred embodiments, this is implemented by waste water being put into a process tank of a waste water treatment facility. In this tank there are bacteria, which inhabit the process tank (compartment 9 of
(16) With reference to
(17) Assuming that a filtration cake 10 (which will be described in detail later), comprising accumulated and compressed activated sludge flocs present in the sludge 2, has already been formed on the net 14 on the support structure 5, filtering of the liquid may be provided when the pump 8 provides a flow of liquid through the filter element 5. The filtering is provided by the pores of the filtration cake 10 (formed on the support structure 14) having sufficient porosity to let liquid, in the preferred embodiment being water, pass through but preventing activated sludge flocs and other particles from the activated sludge supernatant to pass through the filtration cake 10.
(18) The filtering may generate a build-up of flocs of biological material on the filtration cake 10. To prevent such build-up, air bubbles may be introduced from a position below the support filter elements 5 by means of an aeration device (not shown) similar to the aeration device 3. Air typically being atmospheric air or in general gas is fed to the aeration device by means of the pump. The air bubbles introduced by the aeration device will rise up along the filtration cake 10 and during this rise, their interaction with the liquid and the activated sludge flocs tends to limit or even avoid build-up of the flocs of activated sludge on the filtration cake 10, made of accumulated and compressed flocs of activated sludge.
(19) As indicated in
(20) The system comprises a number of sensors used for monitoring and controlling the treatment process. The actual locations of these sensors are selected according to what is to be monitored in a manner being ordinary to a skilled person. In
(21) The system also comprises a control unit (not shown) comprising a processing unit and memory, typically embodied as a computer. The control unit has instructions being executed to control the system, e.g. the various pump and valves of the system inter alia in response to signals received from the sensors.
(22) The temperature of the sludge in the compartment 9 should in many cases be within certain ranges to obtain optimal conditions for the degradation. Accordingly, one or more temperature sensors are arranged inside the compartment 9. If a sensor detects that the temperature of the sludge is to low, heat may be added by suitable means either by heating waste water being added to the compartment 9 and/or by heating the liquid present in the compartment. Similar measures may be applied in case the temperature gets too high.
(23) The quality of the liquid leaving the filter elements 5 through outlet 7, the filtrate, can be determined in different manners. Typically, the turbidity is considered when the quality of the filtrate is to be monitored and a turbidity sensor is arranged in the outlet 7. Another parameter to monitor could be total organic carbon concentration (TOC), total bacteria count, suspended solids concentration (SS) or chemical oxygen demand (COD).
(24) An oxygen sensor is typically arranged inside the compartment to determine the oxygen content in the activated sludge. If the oxygen content is not within the ranges preferred, the aeration device introduces more or less oxygen in response to oxygen content being not with ranges preferred by suitable operation of the pump 12.
(25) One or more pressure sensors are applied to determine the pressure difference across the support structure 14 and the filtration cake 10. It has been found that the pressure difference across the support structure 14 and the filtration cake 10 should be below 1 bar and in the embodiments shown in
(26) The outputs from the various sensors are fed into a controlling device, typically being a computer having instructions for controlling the various pumps, valves, heating means, cooling means etc. arranged in the system 1. While many of the controlling instructions may be determined theoretically, it has been found more practical to base the controlling on experiments.
(27) As noted above, the support structure 14 is formed from a net having a mesh size being sufficient to prevent particles of a certain size to pass through. The mesh size is preferably in the order of 1-100 micron times 1-100 micron and the net is preferably made as a woven or non-woven fabric produced from paper, synthetic or natural fibers or metal, such as stainless steel mesh.
(28) A backing layer may be applied on support structure 14, and the filtration cake 10 will be formed on this backing layer. Such backing layer may be paper, fabric, net or similar and in such cases, the support structure 14 is typically adapted to support the backing layer and the filtration cake 10 and being provided with openings being insufficient to arrest flocs. The arrestment of activated sludge flocs is instead carried out by the backing layer. Combination of these different measures to arrest activated sludge flocs may be used.
(29) A filtration cake design phase (filter cake build up phase), for providing the filtration cake 10, is initiated upon start-up of the system or in general when no filtration cake 10 is present on the support structure 14. The filtration cake design phase comprising, with reference to
(30) During the accumulation phase A at least, activated sludge flocs having a size allowing them to pass through the mesh or the not yet fully designed filtration cake 10 go through the filter element 5 and in order to avoid discharging these flocs to the environment, the fluid going through the filter element 5 is typically recycled to the compartment 9.
(31) Once flocs have begun to be arrested on the support structure 14 or the backing layer and activated sludge flows towards the support structure 14 a further accumulation of flocs on the support structure occurs. This further accumulation is continued until a pre-determined thickness of accumulated activated sludge flocs has been reached (t=t.sub.2). The point in time at which this occurs may be determined in a number of ways. One possible way is to monitor the pressure drop over the filter element 5 and experimentally determine a correlation between the filtration cake of accumulated activated sludge flocs and the pressure drop, so that phase A is ended once a certain pressure drop occurs over the filter element 5. In
(32) At the end of phase A (t=t.sub.2), the filtration cake 10 has been formed, but is still mechanically quite unstable and the filtering characteristics of the filtration cake 10 may still not be as desired. During compression phase B (from t.sub.2 to t.sub.3), the pressure difference over the filter element is at an elevated level providing a compression of the filtration cake 10. The pressure difference needed for this compression may vary, but may typically be in the range of 0.01 to 1 bar measured across the support and the filtration cake 10. The compression is carried out for a certain time, preferably being determined experimentally, with the aim of compressing flocs in the entire filtration cake 10. At the end of phase B (t=t.sub.3), the filtration cake 10 comprising accumulated and compressed activated sludge flocs and the filter element 5 is ready for filtration and filtration phase C (t>t.sub.3) is initiated. Once phase B is ended, the pressure difference is lowered to a pressure difference typically being smaller than 1 bar, recirculation of filtrate, if implemented, is stopped, and the filtration as disclosed above is carried out, provided that the filtrate quality is sufficient.
(33) It should be noted, that design of the filtration cake 10 can be performed with other pressure profiles than what is disclosed in
(34) During filtration, that is in phase C with reference to
(35) Replacementor in general renewalof the filter or filter cake 10 is performed at t=t.sub.4 from which a new design phase is initiated after removal of the filtration cake 10. Thus, at t=t.sub.4 the cycle comprising phases A, B and C is repeated as indicated in the figure. Phase A and B are in the time range of seconds, preferably phase A being around 20 seconds and phase B being around 15 seconds, whereas phase C is in the range of 300 seconds.
(36) It is noted that
(37)
(38) Compared to conventional filtering using e.g. polymeric or ceramic filters, the present invention provides an advantage with respect to regeneration and adjustment of filter capabilities, such as improved rejection capabilities of the cake due to porosity adjusted by pressure treatment in stage B. In the present invention, the regeneration of the filter capabilities is provided by removing the filtration cake 10 and establishing a new filtration cake 10 by the methods disclosed above. As the filter material, that is the filtration cake 10, according to the present invention is made from the very same material as what is to be filtered away from the sludge the filter may be disposed in the same manner as the filtered away material. Furthermore, the cost for the filter material can be neglected.
(39) Removal of the filtration cake 10 may be provided e.g. by mechanical actions such as scraping or a chemical action. The mechanical action is preferred, although some material may be left on or in the support structure 14. However, the support structure 14 is preferably made from stainless steel or other heat or chemical-resistant material, and any leftovers may be burned away, removed by chemical cleaning and/or removed mechanically.
(40) In embodiments, where a backing layer is applied, the backing layer is typically removed together with the filtration cake 10 with the result that no material is left on or in the support structure 14.
(41) While the replacement of the filtration cake 10 is disclosed above to impose at least to some extend a replacement phase where no filtration occurs, the system may be adapted to provide a continuous filtering. This may be provided e.g. by having a number of filter elements 5 and replacing one or morebut not allfilter elements 5 in a sequence.
(42) With reference to
(43) The pre-filtering performed by 26 may advantageously be combined with the deflocculation disclosed with reference to
(44) Furthermore, the physical borders between three compartments disclosed in
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(49) An optimised biodegradation may be performed according to the method disclosed in
(50) As indicated in
(51) It is noted that in a broad context, performing a biodegradation means allowing bacteria to perform the degradation. In addition, the step of deflocculation and biodegradation may be performed simultaneously.
(52) With reference to
(53) After a certain residence time in the deflocculation compartment 20, the activated sludge is transferred into a re-flocculation compartment 21 where flocculation is promoted by seeking to avoid shear forces acting on the activated sludge flocs. The re-flocculation chamber 21 is a cavity in which the sludge is allowed a certain residence time sufficient for a flocculation to occur where the sludge is not acted upon in a manner that could result in a deflocculation. This flocculation may take place driven purely by the natural interactions between liquid and the substances present therein, although some mixing may be induced to the fluid to increase the flocculation speed. In general, the flocculation may be effected by promoting aerobic activity of bacteria, e.g. by aeration and addition of some waste water or other substrate or by chemical flocculation, e.g. by dosing a flocculant. In order to promote flocculation, an aeration device 3a is present in the compartment 21, to introduce air bubbles, or in general air or oxygen, into the activated sludge. In addition, addition of substrate, such as waste water or synthetic carbon source, would preferably also be applied to promote flocculation.
(54) Once the re-flocculation has been performed, the fluid is transferred to the filter compartment 22. This compartment comprises a filter element 5 (more than one filter element 5 can be applied), with outlet 7 as disclosed in relation to
(55)
Experimental Results
(56) In the following, results obtained by a device as shown in
(57) The process parameters where Pressure during accumulation phase A: 0.010.1 bar Pressure during compression phase B: above pressure during accumulation phase and below 1 bar Pressure during filtration phase C: lower than pressure during phase B, but typically up to 1 bar
(58) Filtration cake height was from 0 to 10 mm during accumulation phase A. After compression (phase B) the height was typically 1-4 (up to 10 mm).
(59) TABLE-US-00001 Suspended solids concentration Sample [mg/L] Raw sludge supernatant 34 Supernatant filtered through a coffee filter alone 15 Supernatant filtered through a cake built on a coffee 4 filter and compressed at 10 kPa Supernatant filtered through a cake built on a coffee 2 filter and compressed at 15 kPa Supernatant filtered through a cake built on a coffee 0 filter and compressed at 20 kPa Supernatant filtered through a membrane (pore size 1 0.45 micron, comparable example)
(60) The conclusions are that: the majority of rejection with respect to suspended solids comes from the filtration cake the quality of filtrate with respect to suspended solids, produced by the filtration cake, is comparable or exceeding that produced with a membrane the quality of filtrate increasing with pressure level during stage B indicates the adjustable selectivity of filtration cake, which is an advantage of this approach
(61) Although the present invention has been described in connection with the specified embodiments, it should not be construed as being in any way limited to the presented examples. The scope of the present invention is set out by the accompanying claim set. In the context of the claims, the terms comprising or comprises do not exclude other possible elements or steps. Also, the mentioning of references such as a or an etc. should not be construed as excluding a plurality. The use of reference signs in the claims with respect to elements indicated in the figures shall also not be construed as limiting the scope of the invention. Furthermore, individual features mentioned in different claims, may possibly be advantageously combined, and the mentioning of these features in different claims does not exclude that a combination of features is not possible and advantageous.