IRON-CATALYZED METATHESIS POLYMERIZATION OF OLEFINS

Abstract

This invention is directed to iron-based complexes, and uses thereof for catalytic olefin metathesis reaction, including ring opening metathesis polymerization of olefins.

Claims

1. An iron complex represented by the structures of formula A1, its dimer A2 or its isomers: ##STR00073## wherein R.sup.1 and R.sup.2 are each independently linear or branched alkyl, cycloalkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl, or alkylheterocyclyl; R.sup.3 is H, D, linear or branched alkyl; R.sup.4 is SiH.sub.x(alkyl).sub.y(aryl).sub.z or CH.sub.x(alkyl).sub.y(aryl).sub.z; wherein x is an integer between 0-3; y is an integer between 0-3; z is an integer between 0-3; wherein x+y+z is 3; Q.sup.1, Q.sup.2, Q.sup.3, Q.sup.4 Q.sup.5 or Q.sup.6 are each independently H, linear or branched alkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl, alkylheterocyclyl, halide, nitro, amide, ester, cyano, alkoxy, NH.sub.2, aminoalkyl or arylamino; wherein at least one of Q.sup.1-Q.sup.5 is an alkyl; and n is an integer between 1 and 3.

2. The iron complex of claim 1, wherein the iron is iron (III).

3. The iron complex of claim 1, wherein the R.sup.1 and R.sup.2 are the same; or wherein R.sup.1 and R.sup.2 are each independently isopropyl, ethyl, phenyl or tertbutyl; or wherein R.sup.3 is H; or wherein R.sup.4 is Si(CH.sub.3).sub.3 or C(CH.sub.3).sub.3; or wherein Q2 and Q4 are H; or wherein Q1, Q3 and Q5 are each independently isopropyl or tertbutyl; or wherein Q.sup.1, Q.sup.5 are each independently isopropyl or tertbutyl and Q.sup.3 is H.

4-9. (canceled)

10. The iron complex of claim 1, wherein the structure of formula A1 and A2 are in equilibrium in solution.

11. (canceled)

12. The iron complex of claim 1, wherein the complex is represented by the following structures: ##STR00074## ##STR00075##

13. A method for metathesis polymerization of cyclic olefins comprising reacting a substituted or unsubstituted cyclic olefin with the iron complex of claim 1, thereby obtaining a polymer by ring opening metathesis polymerization.

14. The method of claim 13, wherein the cyclic olefin has a strain in the ring; or wherein the cyclic olefin comprises norbornene, bicycles, 3, 4 or 5 membered ring; or wherein the cyclic olefin is a carbocycle or heterocycle; or wherein the cyclic olefin is a diene.

15-22. (canceled)

23. The method of claim 13, wherein the cyclic olefin is substituted or unsubstituted norbornene obtaining a substituted or unsubstituted polynorbornene of formula I: ##STR00076## wherein Q.sup.7 is H, linear or branched alkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl, Si(alkyl).sub.3, alkylheterocyclyl, halide, nitro, amide, ester, cyano, alkoxy, NH.sub.2, aminoalkyl or arylamino; o is an integer between 1-3; m is an integer larger than 2.

24. (canceled)

25. An iron complex represented by the structures of formula A3 or its isomer: ##STR00077## wherein: R.sup.1 and R.sup.2 are each independently linear or branched alkyl, cycloalkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl, or alkylheterocyclyl; R.sup.3 is H, D, linear or branched alkyl; X.sup.1 and X.sup.2 are each independently Cl, Br, I or F; Q.sup.1, Q.sup.2, Q.sup.3, Q.sup.4, Q.sup.5 or Q.sup.6 are each independently H, linear or branched alkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl, alkylheterocyclyl, halide, nitro, amide, ester, cyano, alkoxy, NH.sub.2, aminoalkyl or arylamino; wherein at least one of Q.sup.1-Q.sup.5 is alkyl; and n is an integer between 1 and 3.

26. The iron complex of claim 25, wherein the iron is iron (II).

27. The iron complex of claim 25, wherein the R.sup.1 and R.sup.2 are the same; or wherein R.sup.1 and R.sup.2 are each independently isopropyl, ethyl, phenyl or tertbutyl; or wherein R.sup.3 is H; or wherein X.sup.1 and X.sup.2 are independently Br or Cl; or wherein Q.sup.2 and Q.sup.4 are H; or wherein Q.sup.1, Q.sup.3 and Q.sup.5 are each independently isopropyl or tertbutyl; or wherein Q.sup.1, Q.sup.5 are each independently isopropyl or tertbutyl and Q.sup.3 is H.

28-33. (canceled)

34. The iron complex of claim 25, wherein the complex is represented by the following structures: ##STR00078## ##STR00079##

35. A compound represented by the structure of formula B1 or its isomers: ##STR00080## R.sup.1 and R.sup.2 are each independently linear or branched alkyl, cycloalkyl, heterocyclyl, alkylcycloalkyl, alkylaryl, or alkylheterocyclyl; R.sup.3 is H, D, linear or branched alkyl; Q.sup.1, Q.sup.2, Q.sup.3, Q.sup.4 Q.sup.5 or Q.sup.6 are each independently H, linear or branched alkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl, alkylheterocyclyl, halide, nitro, amide, ester, cyano, alkoxy, NH.sub.2, aminoalkyl or arylamino; wherein at least one of Q.sup.1-Q.sup.5 is alkyl; and n is an integer between 1 and 3.

36. The compound of claim 35, wherein the compound is represented by the following structures: ##STR00081##

37. The method of claim 13, wherein said polymerization is conducted in the presence of an olefin (RCHCH.sub.2, wherein R is substituted or unsubstituted-aryl, phenyl, heteroaryl, alkyl, cycloalkyl or heterocycloalkyl).

38. The method of claim 37, wherein the olefin is styrene, wherein said styrene is optionally in an equimolar amount of the cyclic olefin.

39. (canceled)

40. The method of claim 38, wherein said styrene itself does not undergo polymerization.

41. The method of claim 37, wherein said polymerization produces a polymer that is soluble in an organic solvent.

42. (canceled)

43. The method of claim 38, wherein said method produces a polymer capped by CH-Ph (of styrene).

44. The method of claim 38, wherein said polymer comprises a mixture of compounds I, Va, Vb, Vc and Vd: ##STR00082## wherein m.sub.1, m.sub.2, m.sub.3, m.sub.4 and m.sub.5 are each an integer of 2-1,000,000; Q.sup.7 is independently H, linear or branched alkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl, alkylheterocyclyl, Si(alkyl).sub.3, halide, nitro, amide, ester, cyano, alkoxy, NH.sub.2, aminoalkyl or arylamino; and o is an integer between 1-3.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0034] The subject matter regarded as the invention is particularly pointed out and distinctly claimed in the concluding portion of the specification. The invention, however, both as to organization and method of operation, together with objects, features, and advantages thereof, may best be understood by reference to the following detailed description when read with the accompanying drawings in which:

[0035] FIG. 1A-1B present synthetic schemes for the preparation of iron complexes of this invention. FIG. 1A presents preparation of complex A1 from complex A3. Specifically, preparation of complexes 9, 10, 11 and 12 from complexes 1, 2, 3 and 8 respectively. FIG. 1B presents a reaction between A1 and 4-dimethylaminopyridine where 4 coordinated iron complex is obtained following a reaction with BPh.sub.3 to obtain again complex A1. Specifically, preparation of complex 14 from complex 9. Complex 9 can be further obtained by addition of BPh.sub.3.

[0036] FIG. 2A-2C present X-ray structures of complexes of this invention with 50% probability ellipsoids. H atoms, except H(1), and solvent molecules are omitted for clarity FIG. 2A: X-ray structure of 11: selected bond lengths (): Fe(1)-C(27) 2.0176(18); selected bond angles (0): Fe(1)-C(27)-Si(1) 122.10(10). FIG. 2B: X-ray structure of 13 (dimer of 12): selected bond lengths (): Fe(1)-C(28) 2.0683(15); selected bond angles (): Fe(1)-C(28)-Si(1) 124.56(8). FIG. 2C: X-ray structure of 14. H atoms, except CHPiPr.sub.2, and solvent molecules are omitted for clarity. Selected bond lengths (): Fe(1)-C(25) 2.045(4), Fe(1)-N(2) 2.106(3), Fe(1)-P(1) 2.4448(11), Fe(1)-N(1) 2.057(3), C(1)-C(2) 1.371(5). Selected bond angles: N(1)-Fe(1)-P(1) 84.02(9), N(2)-Fe(1)-C(25) 106.73(14), P(1)-C(1)-C(2) 121.9(3), Fe(1)-C(25)-Si(1) 119.0(2).

[0037] FIG. 3A-3C present iron catalyzed ROMP (ring-opening metathesis polymerization) of norbornene and characterization of the product. FIG. 3A presents a synthetic scheme of ROMP of norbornene catalyzed by 9. FIG. 3B presents TEM image of air dried 0.058 mg/mL solution of I (polynorbornene); FIG. 3C presents partial epoxidation of I (polynorbornene) by meta-chloroperbenzoic acid (m-CPBA), and .sup.1H-.sup.1H gCOSY NMR spectra of partially epoxidized I showing correlation between H.sub.a and H.sub.b.

[0038] FIG. 4 presents X-ray structure of 1 with 50% probability ellipsoids. H atoms and solvent molecules are omitted for clarity. Selected bond lengths (): FeCl(1) 2.2247(6), Fe(1)-Cl(2) 2.2570(6), Fe(1)-P(1) 2.4357(6), Fe(1)-N(1) 2.1692(14), C(1)-C(2) 1.505(3). Selected bond angles (): N(1)-Fe(1)-P(1) 79.45(4), Cl(1)-Fe(1)-Cl(2) 119.87(2), P(1)-C(1)-C(2) 109.05(13).

[0039] FIG. 5 presents X-ray structure of 2 with 50% probability ellipsoids. H atoms and solvent molecules are omitted for clarity. Selected bond lengths (): FeBr(1) 2.4036(6), Fe(1)-Br(2) 2.3687(5), Fe(1)-P(1) 2.4225(9), F(1)-N(1) 2.157(2), C(1)-C(2) 1.505(4). Selected bond angles: N(1)-Fe(1)-P(1) 80.00(7), Br(1)-Fe(1)-Br(2) 116.61(2), P(1)-C(1)-C(2) 108.9(2).

[0040] FIG. 6 presents X-ray structure of 3 with 50% probability ellipsoids. H atoms and solvent molecules are omitted for clarity. Selected bond lengths (): Fe(1)-Cl(1) 2.2392(13), Fe(1)-Cl(2) 2.2452(14), Fe(1)-P(1) 2.4397(14), Fe(1)-N(1) 2.157(4), C(1)-C(2) 1.500(6). Selected bond angles: N(1)-Fe(1)-P(1) 81.42(10), Cl(1)-Fe(1)-Cl(2) 120.15(5), P(1)-C(1)-C(2) 112.8(3).

[0041] FIG. 7 presents X-ray structure of 4 with 50% probability ellipsoids. H atoms and solvent molecules are omitted for clarity. Selected bond lengths (): Fe(1)-Cl(1) 2.2484(6), Fe(1)-Cl(2) 2.2313(6), Fe(1)-P(1) 2.4058(6), Fe(1)-N(1) 2.1638(19), C(1)-C(2) 1.532(3). Selected bond angles: N(1)-Fe(1)-P(1) 80.77(5), Cl(1)-Fe(1)-Cl(2) 116.98(3), P(1)-C(1)-C(2) 107.74(15).

[0042] FIG. 8 presents X-ray structure of 9 with 50% probability ellipsoids. H atoms and solvent molecules are omitted for clarity. Only the major conformation is presented. Selected bond lengths (): Fe(1)-C(25) 2.043(4), Fe(1)-N(1) 2.182(3), Fe(1)-P(1) 2.4413(15), Fe(1)-Cl(1) 2.3110(10), C(1)-C(2) 1.513(5). Selected bond angles: N(1)-Fe(1)-P(1) 80.71(9), Cl(1)-Fe(1)-C(25) 126.05(13), P(1)-C(1)-C(2) 114.2(3), Fe(1)-C(25)-Si(1) 117.3(2).

[0043] FIGS. 9A-9E present the spectra of compounds I, Va-Vd. FIG. 9A: .sup.1H NMR spectra of I, Va-Vd prepared in the presence of styrene (inset: expansion of 6.5 to 4.8 ppm region showing signals from end groups); FIG. 9B: .sup.1H-.sup.1H-gCOSY NMR; FIG. 9C: .sup.13C{.sup.1H}NMR spectra of I, Va-Vd prepared in the presence of styrene (inset: expansion of 134 to 135 ppm region); FIG. 9D: .sup.1H-.sup.1H-gCOSY NMR spectrum of partially epoxidized I, Va-Vd; and FIG. 9E: IR spectra of I, Va-Vd prepared in the presence of styrene.

[0044] It will be appreciated that for simplicity and clarity of illustration, elements shown in the figures have not necessarily been drawn to scale. For example, the dimensions of some of the elements may be exaggerated relative to other elements for clarity. Further, where considered appropriate, reference numerals may be repeated among the figures to indicate corresponding or analogous elements.

DETAILED DESCRIPTION OF THE PRESENT INVENTION

[0045] In the following detailed description, numerous specific details are set forth in order to provide a thorough understanding of the invention. However, it will be understood by those skilled in the art that the present invention may be practiced without these specific details. In other instances, well-known methods, procedures, and components have not been described in detail so as not to obscure the present invention.

[0046] This invention is directed to iron-catalyzed metathesis polymerization of cyclic olefins. In some embodiments, this invention is directed to iron-catalyzed ring opening metathesis polymerization of olefins. This reaction enables the formation of polynorbornene with unprecedented stereoregularity and high molecular weight (>10.sup.7 g/mol). The iron-based catalyst of this invention involves a metal-ligand cooperation, involving dearomatization-aromatization of pyridine-based pincer ligands, which has led to the design of several new catalytic reactions.

[0047] A unique feature of these iron catalysts is that an open coordination site is formed upon dearomatization of the pyridine-based ligand, making possible the activation of incoming substrates such as H.sub.2, CO.sub.2, amines, and alcohols via metal-ligand cooperation.

Iron Complexes

[0048] In some embodiments, this invention is directed to an iron complex and to methods of use thereof represented by the structure of formula A1, its dimer A2 or its isomers:

##STR00005## [0049] wherein [0050] R.sup.1 and R.sup.2 are each independently linear or branched alkyl, cycloalkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl, or alkylheterocyclyl; [0051] R.sup.3 is H, D, linear or branched alkyl; [0052] R.sup.4 is SiH.sub.x(alkyl).sub.y(aryl).sub.z or CH.sub.x(alkyl).sub.y(aryl).sub.z; wherein x is an integer between 0-3; y is an integer between 0-3; z is an integer between 0-3; wherein x+y+z is 3. [0053] Q.sup.1, Q.sup.2, Q.sup.3, Q.sup.4 Q.sup.5 or Q.sup.6 are each independently H, linear or branched alkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl, alkylheterocyclyl, halide, nitro, amide, ester, cyano, alkoxy, NH.sub.2, aminoalkyl or arylamino; and [0054] n is an integer between 1 and 3.

[0055] In some embodiments, this invention is directed to an iron complex and methods of use thereof represented by the structure of formula A3 or its isomers:

##STR00006## [0056] wherein: [0057] R.sup.1 and R.sup.2 are each independently linear or branched alkyl, cycloalkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl or alkylheterocyclyl; [0058] R.sup.3 is H, D, linear or branched alkyl; [0059] X.sup.1 and X.sup.2 are each independently Cl, Br, I or F; [0060] Q.sup.1, Q.sup.2, Q.sup.3, Q.sup.4, Q.sup.5 or Q.sup.6 are each independently H, linear or branched alkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl, alkylheterocyclyl, halide, nitro, amide, ester, cyano, alkoxy, NH.sub.2, aminoalkyl or arylamino; and [0061] n is an integer between 1 and 3.

[0062] In various embodiments, the iron complexes of structures A1 and A2 are presented below:

##STR00007## ##STR00008##

[0063] In various embodiments, the iron complexes of structures A3 are presented below:

##STR00009##

Ligands

[0064] In some embodiments, this invention is directed to a compound by the structure of formula B1 or its isomers:

##STR00010## [0065] R.sup.1 and R.sup.2 are each independently linear or branched alkyl, cycloalkyl, heterocyclyl, alkylcycloalkyl, alkylaryl, or alkylheterocyclyl; [0066] R.sup.3 is H, D, linear or branched alkyl; [0067] Q.sup.1, Q.sup.2, Q.sup.3, Q.sup.4 Q.sup.5 or Q.sup.6 are each independently H, linear or branched alkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl, alkylheterocyclyl, halide, nitro, amide, ester, cyano, alkoxy, NH.sub.2, aminoalkyl or arylamino; and [0068] n is an integer between 1 and 3.

[0069] In various embodiments, the compounds of B1 are presented below:

##STR00011##

[0070] In some embodiments, the compound of formula B1 is used as a ligand for the preparation of an iron complex of this invention.

[0071] In some embodiments R.sup.1 of the structures of formula A1, A2 A3 or B1 is a linear alkyl. In other embodiments, R.sup.1 of the structures of formula A1, A2 A3 or B1 is a branched alkyl. In other embodiments, R.sup.1 of the structures of formula A1, A2 A3 or B1 is cycloalkyl. In other embodiments, R.sup.1 of the structures of formula A1, A2 A3 or B1 is aryl. In other embodiments, R.sup.1 of the structures of formula A1, A2 A3 or B1 is heterocyclyl. In other embodiments, R.sup.1 of the structures of formula A1, A2 A3 or B1 is alkylcycloalkyl. In other embodiments, R.sup.1 of the structures of formula A1, A2 A3 or B1 is alkylaryl. In other embodiments, R.sup.1 of the structures of formula A1, A2 A3 or B1 is alkylheterocyclyl.

[0072] In some embodiment R.sup.2 of the structures of formula A1, A2 A3 or B1 is a linear alkyl. In other embodiments, R.sup.2 of the structures of formula A1, A2 A3 or B1 is a branched alkyl. In other embodiments, R.sup.2 of the structures of formula A1, A2 A3 or B1 is cycloalkyl. In other embodiments, R.sup.2 of the structures of formula A1, A2 A3 or B1 is aryl. In other embodiments, R.sup.2 of the structures of formula A1, A2 A3 or B1 is heterocyclyl. In other embodiments, R.sup.2 of the structures of formula A1, A2 A3 or B1 is alkylcycloalkyl. In other embodiments, R.sup.2 of the structures of formula A1, A2 A3 or B1 is alkylaryl. In other embodiments, R.sup.2 of the structures of formula A1, A2 A3 or B1 is alkylheterocyclyl.

[0073] In some embodiments R.sup.3 of the structures of formula A1, A2 A3 or B1 is H. In other embodiments, R.sup.3 of the structures of formula A1, A2 A3 or B1. In other embodiments, R.sup.3 of the structures of formula A1, A2 A3 or B1 a linear alkyl. In other embodiments, R.sup.3 of the structures of formula A1, A2 A3 or B1 is a or branched alkyl.

[0074] In some embodiments R.sup.4 of the structures of formula A1, A2 or A3 is Si(alkyl).sub.3. In other embodiments, R.sup.4 of the structures of formula A1, A2 or A3 C(alkyl).sub.3. In other embodiment, R.sup.4 of the structures of formula A1, A2 or A3 is SiH.sub.x(alkyl).sub.y(aryl).sub.z. In other embodiment, R.sup.4 of the structures of formula A1, A2 or A3 is CH.sub.x(alkyl).sub.y(aryl).sub.z; wherein x is an integer between 0-3; y is an integer between 0-3; z is an integer between 0-3; wherein x+y+z is 3.

[0075] In some embodiments Q.sup.1, of the structures of formula A1, A2 A3 or B1 is H. In other embodiments, Q.sup.1 of the structures of formula A1, A2 A3 or B1 is linear or branched alkyl. In other embodiments, Q.sup.1 of the structures of formula A1, A2 A3 or B1 is aryl. In other embodiments, Q.sup.1 of the structures of formula A1, A2 A3 or B1 is heterocyclyl. In other embodiments, Q.sup.1 of the structures of formula A1, A2 A3 or B1 is alkylcycloalkyl. In other embodiments, Q.sup.1 of the structures of formula A1, A2 A3 or B1 is alkylaryl. In other embodiments, Q.sup.1 of the structures of formula A1, A2 A3 or B1 is alkylheterocyclyl. In other embodiments, Q.sup.1 of the structures of formula A1, A2 A3 or B1 is halide. In other embodiments, Q.sup.1 of the structures of formula A1, A2 A3 or B1 is nitro. In other embodiments, Q.sup.1 of the structures of formula A1, A2 A3 or B1 is amide. In other embodiments, Q.sup.1 of the structures of formula A1, A2 A3 or B1 is ester. In other embodiments, Q.sup.1 of the structures of formula A1, A2 A3 or B1 is cyano. In other embodiments, Q.sup.1 of the structures of formula A1, A2 A3 or B1 is alkoxy. In other embodiments, Q.sup.1 of the structures of formula A1, A2 A3 or B1 is NH.sub.2. In other embodiments, Q.sup.1 of the structures of formula A1, A2 or A3 is aminoalkyl. In other embodiments, Q.sup.1 of the structures of formula A1, A2 A3 or B1 is arylamino.

[0076] In some embodiments Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 A3 or B1 are each independently H. In other embodiments, Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 or A3 are each independently a linear or branched alkyl. In other embodiments, Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 A3 or B1 are each independently an aryl. In other embodiments, Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 or A3 are each independently a heterocyclyl. In other embodiments, Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 A3 or B1 are each independently an alkylcycloalkyl. In other embodiments, Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 A3 or B1 are each independently an alkylaryl. In other embodiments, Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 A3 or B1 are each independently an alkylheterocyclyl. In other embodiments, Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 A3 or B1 are each independently a halide. In other embodiments, Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 A3 or B1 are each independently a nitro. In other embodiments, Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 A3 or B1 are each independently an amide. In other embodiments, Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 A3 or B1 are each independently an ester. In other embodiments, Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 A3 or B1 are each independently a cyano. In other embodiments, Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 A3 or B1 are each independently an alkoxy. In other embodiments, Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 A3 or B1 are each independently a NH.sub.2. In other embodiments, Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 A3 or B1 are each independently an aminoalkyl. In other embodiments, Q.sup.2 and Q.sup.4 of the structures of formula A1, A2 A3 or B1 are each independently an arylamino.

[0077] In some embodiments Q.sup.3, of the structures of formula A1, A2 A3 or B1 is H. In other embodiments, Q.sup.3 of the structures of formula A1, A2 A3 or B1 is linear or branched alkyl. In other embodiments, Q.sup.3 of the structures of formula A1, A2 A3 or B1 is aryl. In other embodiments, Q.sup.3 of the structures of formula A1, A2 A3 or B1 is heterocyclyl. In other embodiments, Q.sup.3 of the structures of formula A1, A2 A3 or B1 is alkylcycloalkyl. In other embodiments, Q.sup.3 of the structures of formula A1, A2 A3 or B1 is alkylaryl. In other embodiments, Q.sup.3 of the structures of formula A1, A2 A3 or B1 is alkylheterocyclyl. In other embodiments, Q.sup.3 of the structures of formula A1, A2 A3 or B1 is halide. In other embodiments, Q.sup.3 of the structures of formula A1, A2 A3 or B1 is nitro. In other embodiments, Q.sup.3 of the structures of formula A1, A2 A3 or B1 is amide. In other embodiments, Q.sup.3 of the structures of formula A1, A2 A3 or B1 is ester. In other embodiments, Q.sup.3 of the structures of formula A1, A2 A3 or B1 is cyano. In other embodiments, Q.sup.3 of the structures of formula A1, A2 A3 or B1 is alkoxy. In other embodiments, Q.sup.3 of the structures of formula A1, A2 A3 or B1 is NH.sub.2. In other embodiments, Q.sup.3 of the structures of formula A1, A2 A3 or B1 is aminoalkyl. In other embodiments, Q.sup.3 of the structures of formula A1, A2 A3 or B1 is arylamino.

[0078] In some embodiments Q.sup.5, of the structures of formula A1, A2 A3 or B1 is H. In other embodiments, Q.sup.5 of the structures of formula A1, A2 A3 or B1 is linear or branched alkyl. In other embodiments, Q.sup.5 of the structures of formula A1, A2 A3 or B1 is aryl. In other embodiments, Q.sup.5 of the structures of formula A1, A2 A3 or B1 is heterocyclyl. In other embodiments, Q.sup.5 of the structures of formula A1, A2 A3 or B1 is alkylcycloalkyl. In other embodiments, Q.sup.5 of the structures of formula A1, A2 A3 or B1 is alkylaryl. In other embodiments, Q.sup.5 of the structures of formula A1, A2 A3 or B1 is alkylheterocyclyl. In other embodiments, Q.sup.5 of the structures of formula A1, A2 A3 or B1 is halide. In other embodiments, Q.sup.5 of the structures of formula A1, A2 A3 or B1 is nitro. In other embodiments, Q.sup.5 of the structures of formula A1, A2 A3 or B1 is amide. In other embodiments, Q.sup.5 of the structures of formula A1, A2 A3 or B1 is ester. In other embodiments, Q.sup.5 of the structures of formula A1, A2 A3 or B1 is cyano. In other embodiments, Q.sup.5 of the structures of formula A1, A2 A3 or B1 is alkoxy. In other embodiments, Q.sup.5 of the structures of formula A1, A2 A3 or B1 is NH.sub.2. In other embodiments, Q.sup.5 of the structures of formula A1, A2 A3 or B1 is aminoalkyl. In other embodiments, Q.sup.5 of the structures of formula A1, A2 A3 or B1 is arylamino.

[0079] In some embodiments Q.sup.6, of the structures of formula A1, A2 A3 or B1 is H. In other embodiments, Q.sup.6 of the structures of formula A1, A2 A3 or B1 is linear or branched alkyl. In other embodiments, Q.sup.6 of the structures of formula A1, A2 A3 or B1 is aryl. In other embodiments, Q.sup.6 of the structures of formula A1, A2 A3 or B1 is heterocyclyl. In other embodiments, Q.sup.6 of the structures of formula A1, A2 A3 or B1 is alkylcycloalkyl. In other embodiments, Q.sup.6 of the structures of formula A1, A2 A3 or B1 is alkylaryl. In other embodiments, Q.sup.6 of the structures of formula A1, A2 A3 or B1 is alkylheterocyclyl. In other embodiments, Q.sup.6 of the structures of formula A1, A2 A3 or B1 is halide. In other embodiments, Q.sup.6 of the structures of formula A1, A2 A3 or B1 is nitro. In other embodiments, Q.sup.6 of the structures of formula A1, A2 A3 or B1 is amide. In other embodiments, Q.sup.6 of the structures of formula A1, A2 A3 or B1 is ester. In other embodiments, Q.sup.6 of the structures of formula A1, A2 A3 or B1 is cyano. In other embodiments, Q.sup.6 of the structures of formula A1, A2 A3 or B1 is alkoxy. In other embodiments, Q.sup.6 of the structures of formula A1, A2 A3 or B1 is NH.sub.2. In other embodiments, Q.sup.6 of the structures of formula A1, A2 or A3 is aminoalkyl. In other embodiments, Q.sup.6 of the structures of formula A1, A2 A3 or B1 is arylamino. In other embodiments the pyridine ring of the structure of formula A1, A2 A3 or B1 is substituted with 1 to 3 groups of Q.sup.6 wherein each are independently H, linear or branched alkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl, alkylheterocyclyl, halide, nitro, amide, ester, cyano, alkoxy, NH.sub.2, aminoalkyl or arylamino.

[0080] In some embodiments n, of the structures of formula A1, A2 A3 or B1 is an integer between 1 and 3. In other embodiments n is 1. In other embodiments n is 2. In other embodiments n is 3.

[0081] In some embodiments, Q.sup.1 and Q.sup.5 of the structures of A1, A2 A3 or B1 is the same. In some embodiments Q.sup.1 and Q.sup.5 of the structures of A1, A2 A3 or B1 is isopropyl. In some embodiments Q.sup.3 of the structures of A1, A2 A3 or B1 is isopropyl. In some embodiments Q.sup.3 of the structures of A1, A2 A3 or B1 is H. In some embodiments, R.sup.1 and R.sup.2 of the structures of A1, A2 A3 or B1 is the same. In some embodiments, R.sup.1 and R.sup.2 of the structures of A1, A2 A3 or B1 is isopropyl. In some embodiments, R.sup.1 and R.sup.2 of the structures of A1, A2 A3 or B1 is tertbutyl. In some embodiments, R.sup.1 and R.sup.2 of the structures of A1, A2 A3 or B1 is ethyl. In some embodiments, R.sup.1 and R.sup.2 of the structures of A1, A2 A3 or B1 is phenyl.

[0082] In some embodiments, X.sup.1 and X.sup.2 of the structure of A3 is the same. In some embodiments, X.sup.1 and X.sup.2 of the structure of A3 is different. In some embodiments, X.sup.1 and X.sup.2 of the structure of A3 is Cl. In some embodiments, X.sup.1 and X.sup.2 of the structure of A3 is Br.

[0083] As used herein, the term alkyl can be any linear- or branched-chain alkyl group containing up to about 15 carbons unless otherwise specified. In various embodiments, an alkyl includes C.sub.1-C.sub.5 carbons. In some embodiments, an alkyl includes C.sub.1-C.sub.6 carbons. In some embodiments, an alkyl includes C.sub.1-C.sub.8 carbons. In some embodiments, an alkyl includes C.sub.1-C.sub.10 carbons. In some embodiments, an alkyl includes C.sub.1-C.sub.15 carbons. In some embodiments, branched alkyl is an alkyl substituted by alkyl side chains of 1 to 5 carbons. In various embodiments, the alkyl group may be unsubstituted. In some embodiments, the alkyl group may be substituted by a halide, haloalkyl, hydroxyl, alkoxy, carbonyl, amido, alkylamido, dialkylamido, cyano, nitro, CO.sub.2H, amino, aminoalkyl, diaminoalkyl, carboxyl, thio and/or thioalkyl.

[0084] The alkyl group can be a sole substituent or it can be a component of a larger substituent, such as in an alkylcycloalyl, alkylaryl, alkylheterocyclyl, aminoalkyl, alkoxy, etc. Preferred alkyl groups are methyl, ethyl, propyl, isopropyl, tertbutyl and thus methoxy, ethoxy, propoxy, methylamino, ethylamino, propylamino, dimethylamino, diethylamino, isopropylamino, tertbutylamino, methylaryl, ethylaryl, propylaryl, isopropylaryl, tertbutylaryl etc.

[0085] A cycloalkyl or carbocyclic group refers, in various embodiments, to a ring structure comprising carbon atoms as ring atoms, which may be either saturated or unsaturated, substituted or unsubstituted, single or fused. In some embodiments the cycloalkyl is a 3-10 membered ring. In some embodiments the cycloalkyl is a 3-12 membered ring. In some embodiments the cycloalkyl is a 6 membered ring. In some embodiments the cycloalkyl is a 5-7 membered ring. In some embodiments the cycloalkyl is a 3-8 membered ring. In some embodiments the cycloalkyl is a 3-5 membered ring. In some embodiments, the cycloalkyl group may be unsubstituted or substituted by a halogen, alkyl, haloalkyl, hydroxyl, alkoxy, carbonyl, amido, alkylamido, dialkylamido, cyano, nitro, CO.sub.2H, amino, aminoalkyl, diaminoalkyl, carboxyl, thio and/or thioalkyl. In some embodiments, the cycloalkyl ring may be fused to another saturated or unsaturated cycloalkyl or heterocyclic 3-8 membered ring. In some embodiments, the cycloalkyl ring is a saturated ring. In some embodiments, the cycloalkyl ring is an unsaturated ring. Non limiting examples of a cycloalkyl group comprise cyclohexyl, cyclohexenyl, cyclopropyl, cyclopropenyl, cyclopentyl, cyclopentenyl, norbornene, cyclobutyl, cyclobutenyl, cycloctyl, cycloctadienyl (COD), cycloctaene (COE) etc.

[0086] A heterocycle or heterocyclyl group refers, in various embodiments, to a ring structure comprising in addition to carbon atoms, sulfur, oxygen, nitrogen or any combination thereof, as part of the ring. In some embodiments the heterocycle is a 3-10 membered ring. In some embodiments the heterocycle is a 3-12 membered ring. In some embodiments the heterocycle is a 6 membered ring. In some embodiments the heterocycle is a 5-7 membered ring. In some embodiments the heterocycle is a 3-8 membered ring. In some embodiments the heterocycle is a 3-5 membered ring. In some embodiments, the heterocycle group may be unsubstituted or substituted by a halogen, alkyl, haloalkyl, hydroxyl, alkoxy, carbonyl, amido, alkylamido, dialkylamido, cyano, nitro, CO.sub.2H, amino, aminoalkyl, diaminoalkyl, carboxyl, thio and/or thioalkyl. In some embodiments, the heterocycle ring may be fused to another saturated or unsaturated cycloalkyl or heterocyclic 3-8 membered ring. In some embodiments, the heterocyclic ring is a saturated ring. In some embodiments, the heterocyclic ring is an unsaturated ring. Non limiting examples of a heterocyclic rings comprise pyridine, piperidine, morpholine, piperazine, thiophene, pyrrole, benzodioxole, or indole.

[0087] As used herein, the term aryl refers to any aromatic ring and can be either substituted or unsubstituted. Exemplary aryl groups include, without limitation, phenyl, tolyl, xylyl, furanyl, naphthyl, pyridinyl, pyrimidinyl, pyridazinyl, pyrazinyl, triazinyl, thiazolyl, oxazolyl, isooxazolyl, pyrazolyl, imidazolyl, thiophene-yl, pyrrolyl, phenylmethyl, phenylethyl, phenylamino, phenylamido, etc. Substitutions include but are not limited to: F, Cl, Br, I, C.sub.1-C.sub.5 linear or branched alkyl, C.sub.1-C.sub.5 linear or branched haloalkyl, C.sub.1-C.sub.5 linear or branched alkoxy, C.sub.1-C.sub.5 linear or branched haloalkoxy, CF.sub.3, CN, NO.sub.2, CH.sub.2CN, NH.sub.2, NH-alkyl, N(alkyl).sub.2, hydroxyl, OC(O)CF.sub.3, OCH.sub.2Ph, NHCO-alkyl, COOH, C(O)Ph, C(O)O-alkyl, C(O)H, or C(O)NH.sub.2.

[0088] As used herein, the term alkylcycloalkyl refers to an alkyl group as defined above substituted by a cycloalkyl group as defined above. Non limiting examples include: CH.sub.2-cyclohexyl, CH.sub.2-cyclohexenyl, CH.sub.2CH.sub.2-cyclopropyl, CH.sub.2CH.sub.2cyclopropenyl, etc.

[0089] As used herein, the term alkylaryl refers to an alkyl group as defined above substituted by an aryl group as defined above. Non limiting examples include: -benzyl (CH.sub.2Ph), CH.sub.2-tolyl, CH.sub.2 pyridinyl CH.sub.2CH.sub.2phenyl, etc.

[0090] As used herein, the term alkylheterocyclyl refers to an alkyl group as defined above substituted by a heterocyclyl group as defined above. Non limiting examples include: CH.sub.2 piperidinyl, CH.sub.2 thiophenyl, CH.sub.2 pyridinyl, CH.sub.2CH.sub.2indolyl, etc.

[0091] As used herein, the term alkoxy refers to an ether group substituted by an alkyl group as defined above. Alkoxy refers both to linear and to branched alkoxy groups. Nonlimiting examples of alkoxy groups are methoxy, ethoxy, propoxy, iso-propoxy, tert-butoxy.

[0092] As used herein, the term aminoalkyl refers to an amine group substituted by an alkyl group as defined above. Aminoalkyl refers to monoalkylamine, dialkylamine or trialkylamine. Nonlimiting examples of aminoalkyl groups are N(Me).sub.2, NHMe.

[0093] As used herein the term amide refers to both C(O)NH groups and to NHC(O) groups.

[0094] As used herein the term ester refers to both C(O)O groups and to OC(O) groups.

[0095] As used herein the term haloalkyl group refers, In some embodiments, to an alkyl group as defined above, which is substituted by one or more halogen atoms, e.g. by F, Cl, Br or I. Nonlimiting examples of haloalkyl groups are CF.sub.3, CF.sub.2CF.sub.3, CH.sub.2CF.sub.3.

[0096] In various embodiments, this invention provides a compound of this invention or its isomer of the complex of this invention. In various embodiments, the term isomer includes, but is not limited to, optical isomers and analogs, structural isomers and analogs, conformational isomers and analogs, and the like. In some embodiments, the isomer is an optical isomer. In some embodiment, the isomer is an isotopomer, where deuterium atoms can be used instead of hydrogen atoms. In various embodiments, this invention encompasses the use of various optical isomers of the compounds of the invention.

[0097] In some embodiments the iron complexes of the structures of formula A1 are catalysts used for metathesis polymerization of cyclic olefins. In some embodiments the iron complexes of the structures of 9, 10, 11 and 12 are catalysts used for metathesis polymerization of cyclic olefins. In some embodiments the iron complexes of the structures of formula A2 are catalysts used for metathesis polymerization of cyclic olefins.

[0098] In some embodiments the iron complex 13 is a catalyst used for metathesis polymerization of cyclic olefins.

[0099] In some embodiments, the iron complex of formula A1 in the solid state is in a dimer form represented by the structure of A2.

[0100] In some embodiments, the iron complex of formula A3 is a precursor for the preparation of the iron complex of A1.

Preparation of the Iron Complexes of this Invention

[0101] In some embodiments the iron complex of A1 is prepared by reacting the corresponding iron complex of A3 with alklyllithium reagents to obtain the corresponding iron complex A1 having SiH.sub.x(alkyl).sub.y(aryl).sub.z or CH.sub.x(alkyl).sub.y(aryl).sub.z groups respectively. In other embodiments, the reaction is conducted under inert atmosphere. In other embodiment the solvent is benzene, toluene, xylene, mesitylene, pentane, hexanes, 1,2-difluorobenzene. In other embodiments, the solvent is non-coordinating, and non-chlorinated solvent. In other aprotic.

[0102] In some embodiments the iron complex of A1 is prepared according to the process presented in FIG. 1A. In other embodiments, the iron complex of A1 is prepared according to the process disclosed in Example 3.

[0103] In some embodiment, the dimeric complex of A2 is prepared by precipitation of the iron complex of A1. In some embodiments, the dimeric complex of A2 is prepared by precipitating the iron complex of A1 in pentane or any other aprotic solvent at 30 deg. In some embodiments the iron complexe of A2 is prepared according to the process disclosed in Example 3.

[0104] In some embodiments the iron complex of A3 is prepared by reacting the corresponding free ligand with FeX.sub.2 (wherein X is halide) under inert atmosphere. In some embodiments the iron complex of A3 is prepared by reacting the free ligand with FeCl.sub.2 or FeBr.sub.2 under inert atmosphere. In some embodiments the iron complex of A3 is prepared according to the process disclosed in Example 4.

Metathesis Polymerization of Cyclic Olefins

[0105] In some embodiments, this invention is directed to a method for metathesis polymerization of cyclic olefins comprising reacting a substituted or unsubstituted cyclic olefin with the iron complex of formula A1 or A2, thereby obtaining a polymer by ring opening metathesis polymerization. In another embodiment, the polymer is polycyclic. In other embodiment, complexes A1 and A2 are used as isolated complexes or prepared in solution without isolation. In other embodiments, the iron complex of formula A1 or A2 is a complex of structure 9, 10, 11, 12 or 13. Each represents a separate embodiment of this invention.

[0106] In one embodiment, this invention provides iron-catalyzed ROMP (=ring-opening metathesis polymerization) of norbornene and its derivatives utilizing the pyridine-based ligand of structures A1 or A2.

[0107] In one embodiment, this invention provides iron-catalyzed ROMP (=ring-opening metathesis polymerization) of cyclic olefins and its derivatives utilizing the pyridine-based ligand of structures A1 or A2.

[0108] ROMP is one of the largest scale applications of the olefin metathesis reaction in the chemical industry.

[0109] Not being bound to any mechanism, in one embodiment, the metathesis polymerization of this invention includes -hydrogen elimination from a coordinated unsaturated iron(II)-alkyl complex leading to an iron-carbene complex, which may coordinate olefins and catalyzes metathesis reactions.

[0110] As used herein the term cyclic olefin refers, in various embodiments, to a ring structure comprising carbon atoms as ring atoms (carbocycle), or a ring structure comprising in addition to carbon atoms, sulfur, oxygen, nitrogen or any combination thereof, as part of the ring carbon atoms (heterocycle); having at least one double bond; which may be substituted or unsubstituted, single or fused. In other embodiments the cyclic olefin includes one double bone. In other embodiments the cyclic olefin includes a diene. In other embodiments, the cyclic olefin of this invention is a strained ring. In other embodiments the cyclic olefin is a norbornene, bicycle ring or a 3, 4 or 5 membered ring. Non limiting examples of cyclic olefins include: cyclopropene, cyclobutene, cyclopentene, cyclohexene, norbornene. In other embodiments, the cyclic olefin is unsubstituted. In other embodiments, the cyclic olefin is substituted by a halogen, alkyl, Si(alkyl).sub.3, haloalkyl, hydroxyl, alkoxy, carbonyl, amido, alkylamido, dialkylamido, cyano, nitro, CO.sub.2H, amino, aminoalkyl, diaminoalkyl, carboxyl, thio and/or thioalkyl.

[0111] In some embodiments, this invention is directed to a method for metathesis polymerization of cyclic olefins comprising reacting a substituted or unsubstituted cyclic olefin with the iron complex of formula A1 or A2 as a catalyst. In other embodiments, the iron catalyst being used is between 0.02 mol % to 2 mol % per cyclic olefin. In other embodiments, the iron catalyst being used is between 0.2 mol % to 1 mol % per cyclic olefin. In other embodiments, the iron catalyst being used is between 0.5 mol % to 1.5 mol % per cyclic olefin.

[0112] In some embodiment, the metathesis polymerization reaction of this invention is conducted under inert atmosphere. In other embodiment, the metathesis polymerization of this invention is conducted under nitrogen (N.sub.2). In other embodiment, the metathesis polymerization of this invention is conducted under Argon (Ar).

[0113] In some embodiment, the method of the metathesis polymerization of this invention further includes addition of less than 1 equivalent of water per iron. In other embodiment, 0.01 to 0.99 equivalents of water (per iron) are added to the reaction mixture. In other embodiment, 0.1 to 0.9 equivalents of water (per iron) are added to the reaction mixture. In other embodiment, 0.2 to 0.9 equivalents of water (per iron) are added to the reaction mixture. In other embodiment, 0.3 to 0.9 equivalents of water (per iron) are added to the reaction mixture. In other embodiment, 0.4 to 0.9 equivalents of water (per iron) are added to the reaction mixture. In other embodiment, 0.5 to 0.9 equivalents of water (per iron) are added to the reaction mixture.

[0114] In some embodiment, the method of the metathesis polymerization of this invention is conducted in an aprotic solvent. In other embodiments, the solvent is benzene, toluene, xylene, mesitylene, pentane, hexanes, 1,2-difluorobenzene. In other embodiments, the solvent is non-coordinating, and non chlorinated solvent.

[0115] In some embodiments, the method of this invention includes a method for the preparation of a polymer by ring opening metathesis polymerization by metathesis polymerization using iron complexes A1 or A2 of this invention. In another embodiment, the polymer product is polycyclic.

[0116] As used herein the term polycyclic polymer refers, in various embodiments, to a polymer comprising a cyclic ring (substituted or unsubstituted) as the monomeric unit. In other embodiment, the polycyclic polymer comprises a monomeric unit comprising a ring opening of the corresponding cyclic olefin used as the starting material.

[0117] In some embodiments, the method of metathesis polymerization using substituted or unsubstituted norbornene as a starting material is presented by the following scheme:

##STR00012## [0118] wherein Q.sup.7 is independently H, linear or branched alkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl, alkylheterocyclyl, Si(alkyl)3, halide, nitro, amide, ester, cyano, alkoxy, NH.sub.2, aminoalkyl or arylamino; [0119] o is an integer between 1-3; [0120] m is an integer larger than 2.

[0121] In some embodiments Q.sup.7 of formula I, Va-Vd or of the norbornene ring is H. In other embodiments Q.sup.7 of formula I, Va-Vd or of the norbornene ring is linear or branched alkyl. In other embodiments Q.sup.7 of formula I, Va-Vd or of the norbornene ring is aryl. In other embodiments Q.sup.7 of formula I, Va-Vd or of the norbornene ring is heterocyclyl. In other embodiments Q.sup.7 of formula I, Va-Vd or of the norbornene ring is alkylcycloalkyl. In other embodiments Q.sup.7 of formula I or of the norbornene ring is alkylaryl. In other embodiments Q.sup.7 of formula I, Va-Vd or of the norbornene ring is alkylheterocyclyl. In other embodiments Q.sup.7 of formula I, Va-Vd or of the norbornene ring is Si(alkyl).sub.3. In other embodiments Q.sup.7 of formula I, Va-Vd or of the norbornene ring is halide. In other embodiments Q.sup.7 of formula I, Va-Vd or of the norbornene ring is nitro. In other embodiments Q.sup.7 of formula I, Va-Vd or of the norbornene ring is amide. In other embodiments Q.sup.7 of formula I, Va-Vd is ester. In other embodiments Q.sup.7 of formula I, Va-Vd or of the norbornene ring is cyano. In other embodiments Q.sup.7 of formula I, Va-Vd or of the norbornene ring is alkoxy. In other embodiments Q.sup.7 of formula I, Va-Vd or of the norbornene ring is NH.sub.2. In other embodiments Q.sup.7 of formula I, Va-Vd or of the norbornene ring is aminoalkyl. In other embodiments Q.sup.7 of formula I, Va-Vd or of the norbornene ring is arylamino. In other embodiments the norborene ring and the cyclopentane ring of the structure of I, Va-Vd is substituted with 1 to 3 groups of Q.sup.7 wherein each are independently H, linear or branched alkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl, alkylheterocyclyl, Si(alkyl)3, halide, nitro, amide, ester, cyano, alkoxy, NH.sub.2, aminoalkyl or arylamino.

[0122] In some embodiments, o of formula I, Va-Vd is an integer 1. In other embodiments o is an integer 2. In other embodiments o is an integer 3.

[0123] In some embodiments m refers to the number of monomeric units in the polymers obtained according to this invention. In some embodiments m is an integer larger than 2. In some embodiments m is an integer between 2 to 1,000,000. In other embodiments m is an integer between 50-1000. In other embodiments m is an integer between 1,000 to 200,000. In other embodiments m is an integer between 1,000 to 500,00000. In other embodiments m is an integer between 1,000 to 700,000. In other embodiments m is an integer between 100 to 1,000,000. In other embodiments m is an integer between 10,000 to 1,000,000. In other embodiments m is an integer between 100,000 to 1,000,000.

[0124] In other embodiments, the polynorbornene of formula I has a molecular weight larger than 10.sup.7 g/mol. In some embodiments, the polynorbornene of formula I has a molecular weight of about 4,000,000 g/mol. In some embodiments, the polynorbornene of formula I has a molecular weight larger than 4,000,000 g/mol.

[0125] In some embodiments, the polycyclic polymer of formula I is a highly stereoregular ROMP polymer. In other embodiments, the polycyclic polymer of formula I is a trans-isotactic polynorbornene (substituted or unsubstituted).

[0126] In some embodiments substituted or unsubstituted polynorbornene prepared by the method of this invention (without addition of another olefin to the reaction mixture) is represented by the structure of formula I has hydrogen (H) as terminal end group.

[0127] In some embodiments, the metathesis polymerization of this invention comprises reacting a cyclic olefin and an olefin (RCHCH.sub.2 wherein R is substituted or unsubstituted-aryl, phenyl, herteroaryl, alkyl, cycloalkyl or heterocycloalkyl) in the presence of the iron complex of this invention to obtain a polymer (by ring opening metathesis polymerization) having inter alia a terminal R group. In some embodiments, the olefin (RCHCH.sub.2) is added in an equimolar amount of the cyclic olefin. In some embodiments, the olefin (RCHCH.sub.2) itself does not undergo polymerization.

[0128] In some embodiments, the method of metathesis polymerization of the invention is conducted in the presence of styrene. In some embodiments, the styrene is in an equimolar amount of the cyclic olefin. In some embodiments, the styrene itself does not undergo polymerization.

[0129] In some embodiments, in the presence of styrene, the method of the invention produces a ring opening metathesis polymerization that is soluble in an organic solvent (having inter alia a terminal CH-Ph group). In some embodiments, the organic solvent is chloroform. In other embodiments, the organic solvent is benzene.

[0130] In some embodiments, in the presence of styrene, the method of the invention produces a ring opening metathesis polymerization capped by PhCH. In some embodiments, the ring opening metathesis polymerization has the end (terminal) groups of PhCH.

[0131] In some embodiments, a reaction between norbornene and styrene, produces a polycyclic polymer comprising at least one of I, Va, Vb, Vc, Vd or combination thereof:

##STR00013## [0132] wherein m.sub.1, m.sub.2, m.sub.3, and m.sub.4 are each an integer of 2-1,000,000; Q.sup.7 is independently H, linear or branched alkyl, aryl, heterocyclyl, alkylcycloalkyl, alkylaryl, alkylheterocyclyl, Si(alkyl)3, halide, nitro, amide, ester, cyano, alkoxy, NH.sub.2, aminoalkyl or arylamino; and [0133] is an integer between 1-3.

[0134] In some embodiments, the molecular weight of compound Va-Vd is between 15,000 g/mol and 50,000 g/mol. In some embodiments, the molecular weight of compound Va-Vd is greater than 23,000 g/mol. In some embodiments, the molecular weight of compound Va-Vd is between 23,000 g/mol and 32,000 g/mol. In some embodiments, the molecular weight of compound Va-Vd is about 16,000 g/mol. In some embodiments, the molecular weight of compound Va-Vd is greater than 16,000 g/mol. In some embodiments, the molecular weight of compound of Va-Vd is about 46,000 g/mol. In some embodiments, the molecular weight of compound of Va-Vd is larger than 46,000 g/mol. In some embodiments, the molecular weight of compound Va-Vd is about 32,000 g/mol. In some embodiments, the molecular weight of compound Va-Vd is greater than 32,000 g/mol.

[0135] In some embodiments, m.sub.1 is an integer of 2-1,000,000. In other embodiments, m.sub.1 is an integer of 50-1000. In some embodiments, m.sub.1 is an integer of 1,000-200,000. In some embodiments, m.sub.1 is an integer of 1,000-500,00000. In some embodiments, m.sub.1 is an integer of 1,000-700,000. In some embodiments, m.sub.1 is an integer of 100-1,000,000. In some embodiments, m.sub.1 is an integer of 10,000-1,000,000. In some embodiments, m.sub.1 is an integer of 100,000-1,000,000.

[0136] In some embodiments, m.sub.2 is an integer of 2-1,000,000. In other embodiments, m.sub.2 is an integer of 50-1000. In some embodiments, m.sub.2 is an integer of 1,000-200,000. In some embodiments, m.sub.2 is an integer of 1,000-500,00000. In other embodiments, m.sub.2 is an integer of 1,000-700,000. In some embodiments, m.sub.2 is an integer of 100-1,000,000. In some embodiments, m.sub.2 is an integer of 10,000-1,000,000. In some embodiments, m.sub.2 is an integer of 100,000-1,000,000.

[0137] In some embodiments, m.sub.3 is an integer of 2-1,000,000. In other embodiments, m.sub.3 is an integer of 50-1000. In some embodiments, m.sub.3 is an integer of 1,000-200,000. In some embodiments, m.sub.3 is an integer of 1,000-500,00000. In some embodiments, m.sub.3 is an integer of 1,000-700,000. In some embodiments, m.sub.3 is an integer of 100-1,000,000. In some embodiments, m.sub.3 is an integer of 10,000-1,000,000. In other embodiments, m.sub.3 is an integer of 100,000-1,000,000.

[0138] In some embodiments, m.sub.4 is an integer of 2-1,000,000. In other embodiments, m.sub.4 is an integer of 50-1000. In some embodiments, m.sub.4 is an integer of 1,000-200,000. In some embodiments, m.sub.4 is an integer of 1,000-500,00000. In other embodiments, m.sub.4 is an integer of 1,000-700,000. In some embodiments, p is an integer of 100-1,000,000. In some embodiments, m.sub.4 is an integer of 10,000-1,000,000. In some embodiments, m.sub.4 is an integer of 100,000-1,000,000.

[0139] In one embodiment, the terms about, approximately or the symbol may comprise a deviance from the indicated term of +1%, or in some embodiments, 1%, or in some embodiments, 2.5%, or in some embodiments, 5%, or in some embodiments, 7.5% or in some embodiments, 10%, or in some embodiments.

[0140] The following examples are presented in order to more fully illustrate the preferred embodiments of the invention. They should in no way, however, be construed as limiting the broad scope of the invention.

EXAMPLES

Example 1

Preparation of PN Ligands

[0141] PN ligands in this invention refers to ligands comprising phosphorus and nitrogen atoms that bind the iron.

[0142] 2-(2,6-diisopropylphenyl)-6-methylpyridine. [F. Speiser, P. Braunstein, L. Saussine, Organometallics 23, 2633 (2004)]

##STR00014##

[0143] The titled compound was prepared using a modified literature procedure [R. R. Schrock, J. D. Fellmann, J. Am. Chem. Soc. 100, 3359 (1978)]. In a nitrogen glove box, a 100 mL Schlenk flask equipped with a Teflon coated stirring bar was charged with Ni(acac).sub.2 (256.6 mg, 1.0 mmol), 2-bromo-6-methylpyridine (3.4511 g, 20.0 mmol), 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolinium chloride (346.4 mg, 1.0 mmol), and 20 mL THF. Using Schlenk technique outside the box, to the green solution was then added 2,6-diisopropylphenylmagnesium bromide (prepared using 1-bromo-2,6-diisopropylbenzene (7.2721 g, 30.0 mmol) and magnesium (1.4553 g, 59.9 mmol) in 20 mL THF) using extra 10 mL THF to transfer the solution quantitatively. The reaction mixture was then stirred for 16 h at r.t., quenched using 10 mL methanol, and concentrated. The organic compounds were then extracted from the resulting solid using ether. The collected ether solution was concentrated, and purified by column chromatography (SiO.sub.2, hexanes: ethyl acetate=20:1). The product was obtained as a yellow crystalline solid, 3.5822 g, 70% yield.

2-(2,4,6-trimethylphenyl)-6-methylpyridine

##STR00015##

[0144] In a nitrogen glove box, a 100 mL Schlenk flask equipped with a Teflon coated stirring bar was charged with Ni(acac).sub.2 (127.2 mg, 0.5 mmol), 2-bromo-6-methylpyridine (3.466 g, 20.1 mmol), 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolinium chloride (170.1 mg, 0.5 mmol), and 10 mL THF. Using Schlenk technique outside the box, to the green solution was then added 2,4,6-trimethylphenylmagnesium bromide (prepared using 1-bromo-2,4,6-trimethylbenzene (5.903 g, 29.6 mmol) and magnesium (1.4872 g, 61.1 mmol) in 20 mL THF) using extra 10 mL THF to transfer the solution quantitatively. The reaction mixture was then stirred for 4 h at r.t., quenched using 10 mL methanol, and concentrated. The organic compounds were then extracted from the resulting solid using ether. The collected ether solution was concentrated. The product was obtained as a yellow oil, 4.52 g, quantitative yield. Known compound. Reference: H.-P. Chen, Y.-H. Liu, S.-M. Peng, and S.-T. Liu, Organometallics 22, 4893 (2003).

2-(2,4,6-triisopropylphenyl)-6-methylpyridine

##STR00016##

[0145] In a nitrogen glove box, a 250 mL Schlenk flask equipped with a Teflon coated stirring bar was charged with Ni(acac).sub.2 (128 mg, 0.5 mmol), 2-bromo-6-methylpyridine (1.72 g, 10.0 mmol), 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolinium chloride (171 mg, 0.5 mmol), and 5 mL THF. Using Schlenk technique outside the box, to the green solution was then added 2,4,6-triisopropylphenylmagnesium bromide (prepared using 1-bromo-2,4,6-triisopropylbenzene (4.25 g, 15.0 mmol) and magnesium (0.725 g, 30.0 mmol) in 7 mL THF) using extra 8 mL THF to transfer the solution quantitatively. The reaction mixture was then stirred for 16 h at r.t., quenched using 5 mL methanol, and concentrated. The organic compounds were then extracted from the resulting solid using ether. The collected ether solution was concentrated, and purified by column chromatography (SiO.sub.2, eluted first using hexanes to remove 2,4,6-triisopropylbenzene, then using dichloromethane to elute the product crystallized on the column). The product was obtained as a off-white crystalline solid, 1.3569 g, 46% yield.

[0146] .sup.1H NMR (500.08 MHz, CDCl.sub.3, 298 K): 1.08 (6H, d, .sup.3J.sub.HH=7.0 Hz, 2,6-CH(CH.sub.3).sub.2), 1.12 (6H, d, .sup.3J.sub.HH=6.5 Hz, 2,6-CH(CH.sub.3).sub.2), 1.26 (6H, d, .sup.3J.sub.HH=7.0 Hz, 4-CH(CH.sub.3).sub.2), 2.50 (2H, septet, .sup.3J.sub.HH=7.1 Hz, 2,6-CH(CH.sub.3).sub.2), 2.59 (3H, s, CH.sub.3), 2.91 (1H, septet, .sup.3J.sub.HH=6.8 Hz, 4-CH(CH.sub.3).sub.2), 7.05 (2H, s, aromatic 2CH), 7.08 (1H, overlapping d, .sup.3J.sub.HH=7.5 Hz, aromatic CH), 7.10 (1H, overlapping d, .sup.3J.sub.HH=8.0 Hz, aromatic CH), 7.60 (1H, t, .sup.3J.sub.HH=7.5 Hz, aromatic CH).

[0147] .sup.13C{.sup.1H}NMR (125.75 MHz, CDCl.sub.3, 298 K): 23.8 (s, 2,6-CH(CH.sub.3).sub.2), 24.1 (s, 2,6-CH(CH.sub.3).sub.2), 24.4 (s, 4-CH(CH.sub.3).sub.2), 24.6 (s, CH.sub.3), 30.3 (s, 2,6-CH(CH.sub.3).sub.2), 34.5 (s, 4-CH(CH.sub.3).sub.2), 120.7 (s, 2 aromatic CH), 120.8 (s, aromatic), 121.9 (s, aromatic), 135.8 (s, aromatic), 136.6 (s, aromatic, ipso), 146.1 (s, 2 aromatic ipso CH), 148.6 (s, aromatic ipso), 157.8 (s, aromatic, ipso), 159.4 (s, aromatic, ipso).

[0148] HRMS (ESI.sup.+) m/z caled for C.sub.24H.sub.37NP.sup.+ ([M+H].sup.+): 296.2378. Found: 296.2391.

2-(2,6-diisopropylphenyl)-6-(diisopropylphophinomethyl)pyridine (20, PNdipp-.SUP.i.Pr)

##STR00017##

[0149] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with 2-(2,6-diisopropylphenyl)-6-methylpyridine (synthesis described above; 503.9 mg, 1.99 mmol) and 6 mL THF. The clear faint yellow solution was cooled to 35 C. To the cold solution was added 1.6 M .sup.nBuLi in hexanes (1.3 mL, 2.08 mmol) dropwise. The dark red solution was stirred at r.t. for 5.5 h, and cooled to 35 C. To the solution was then added chlorodiisopropylphosphine (306.8 mg, 2.01 mmol) in 3 mL THF. The solution was stirred for 16 h at r.t., quenched by 1 mL methanol, and concentrated. The product was extracted from the resulting solid using n-pentane. Concentration of the pentane extract gave PNdipp-.sup.iPr as an off-white solid. Yield: 717.1 mg, 98%.

[0150] .sup.1H NMR (400.36 MHz, CDCl.sub.3, 291 K): 1.06 (18H, overlapping d, 2PCH(CH.sub.3).sub.2 and CH(CH.sub.3).sub.2), 1.12 (6H, d, .sup.3J.sub.HH=6.9 Hz, CH(CH.sub.3).sub.2), 1.83 (2H, septet, .sup.3J.sub.HH=7.1 Hz, .sup.2J.sub.HP=1.6 Hz, 2PCH(CH.sub.3).sub.2), 2.52 (2H, septet, .sup.3J.sub.HH=6.9 Hz, 2CH(CH.sub.3).sub.2), 3.07 (2H, d, .sup.2J.sub.HP=2.2 Hz, CH.sub.2), 7.02 (1H, d, .sup.3J.sub.HH=7.5 Hz, aromatic CH), 7.19 (2H, d, .sup.3J.sub.HH=7.7 Hz, aromatic 2CH), 7.32 (1H, d, .sup.3J.sub.HH=7.7 Hz, aromatic CH), 7.37 (1H, d, .sup.3J.sub.HH=7.9 Hz, aromatic CH), 7.62 (1H, t, .sup.3J.sub.HH=7.8 Hz aromatic CH).

[0151] .sup.13C{.sup.1H}NMR (100.67 MHz, CDCl.sub.3, 291 K): 19.0 (d, .sup.2J.sub.CP=9.8 Hz, PCH(CH.sub.3).sub.2), 19.8 (d, .sup.2J.sub.CP=15.1 Hz, PCH(CH.sub.3).sub.2), 23.7 (d, J.sub.CP=13.8 Hz, 2PCH(CH.sub.3).sub.2), 23.8 (s, CH(CH.sub.3).sub.2), 24.3 (s, CH(CH.sub.3).sub.2), 30.2 (s, 2CH(CH.sub.3).sub.2), 32.5 (d, .sup.1J.sub.CP=21.0 Hz, CH.sub.2), 121.6 (d, .sup.3J.sub.CP=8.9 Hz, aromatic), 121.8 (s, aromatic), 122.6 (s, 2 aromatic CH), 128.3 (s, aromatic), 135.6 (s, aromatic), 139.0 (s, aromatic, ipso), 146.4 (s, 2 aromatic ipso C), 159.0 (s, aromatic, ipso), 160.4 (d, .sup.2J.sub.CP=9.8 Hz, aromatic, ipso).

[0152] .sup.31P{.sup.1H}NMR (121.50 MHz, CDCl.sub.3, 291 K): 13.5.

[0153] HRMS (ESI.sup.+) m/z caled for C.sub.24H.sub.37NP.sup.+ ([M+H].sup.+): 370.2664. Found: 370.2663.

2-(2,6-diisopropylphenyl)-6-(di-tert-butylphophinomethyl)pyridine (21, PNdipp-.SUP.t.Bu)

##STR00018##

[0154] In a nitrogen glove box, a 20 mL vi equipped with a Teflon coated stirring bar was charged with 2-(2,6-diisopropylphenyl)-6-methylpyridine (synthesis described above; 506.5 mg, 2.00 mmol) and 4 mL THF. The clear faint yellow solution was cooled to 35 C. To the cold solution was added 1.6 M .sup.nBuLi in hexanes (1.3 mL, 2.08 mmol) dropwise. The dark red solution was stirred at r.t. for 4 h, and cooled to 35 C. To the solution was then added di-tert-butylchlorophosphine (378.5 mg, 2.10 mmol) in 3 mL THF. The solution was stirred for 10 h at r.t., quenched by 1 mL methanol, and concentrated. The product was extracted from the resulting solid using n-pentane. Concentration of the pentane extract gave PNdipp-.sup.tBu as an off-white solid. Yield: 735.7 mg, 93%.

[0155] .sup.1H NMR (300.13 MHz, CDCl.sub.3, 291 K): 1.05 (6H, d, .sup.3J.sub.HH=6.9 Hz, CH(CH.sub.3).sub.2), 1.11 (6H, d, .sup.3J.sub.HH=6.8 Hz, CH(CH.sub.3).sub.2), 1.16 (18H, d, .sup.3J.sub.HP=14.0 Hz, 2PC(CH.sub.3).sub.3), 2.51 (2H, septet, .sup.3J.sub.HH=6.9 Hz, 2CH(CH.sub.3).sub.2), 3.13 (2H, d, .sup.2J.sub.HP=3.6 Hz, CH.sub.2), 7.01 (1H, d, .sup.3J.sub.HH=7.5 Hz, aromatic CH), 7.19 (2H, m, aromatic 2CH), 7.33 (2H, dd, J=8.4, 7.1 Hz, aromatic CH), 7.52 (1H, br d, .sup.3J.sub.HH=7.7 Hz, aromatic CH), 7.62 (1H, pseudo t, aromatic CH).

[0156] .sup.13C{.sup.1H}NMR (100.67 MHz, CDCl.sub.3, 291 K): 23.7 (s, CH(CH.sub.3).sub.2), 24.4 (s, CH(CH.sub.3).sub.2), 29.6 (d, .sup.2J.sub.CP=13.1, 2PC(CH.sub.3).sub.3), 30.1 (s, 2CH(CH.sub.3).sub.2), 31.9 (d, .sup.1J.sub.CP=21.0 Hz, 2PC(CH.sub.3).sub.3), 31.9 (d, J.sub.CP=23.4 Hz, CH.sub.2), 121.7 (s, aromatic), 121.9 (d, .sup.3J.sub.CP=11.6 Hz, aromatic), 122.6 (s, 2 aromatic CH), 128.3 (s, aromatic), 135.6 (s, aromatic), 139.0 (s, aromatic, ipso), 146.4 (s, 2 aromatic ipso C), 158.7 (s, aromatic, ipso), 161.7 (d, .sup.2J.sub.CP=15.1 Hz, aromatic, ipso).

[0157] .sup.31P{.sup.1H}NMR (121.50 MHz, CDCl.sub.3, 291 K): 37.2.

[0158] HRMS (ESI.sup.+) m/z calcd for C.sub.26H.sub.41NP.sup.+ ([M+H].sup.+): 398.2977. Found: 398.2980.

2-(2,6-diisopropylphenyl)-6-(diethylphophinomethyl)pyridine (22, PNdipp-Et)

##STR00019##

[0159] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with 2-(2,6-Diisopropylphenyl)-6-methylpyridine (synthesis described above; 255.1 mg, 1.01 mmol) and 2 mL THF. The clear faint yellow solution was cooled to 35 C. To the cold solution was added 1.6 M .sup.nBuLi in hexanes (0.65 mL, 2.04 mmol) dropwise. The dark red solution was stirred at r.t. for 5 h, and cooled to 35 C. To the solution was then added chlorodiethylphosphine (126.0 mg, 1.01 mmol) in 3 mL THF. The solution was stirred for 16 h at r.t., quenched by 1 mL methanol, and concentrated. The product was extracted from the resulting solid using n-pentane. Concentration of the pentane extract gave PNdipp-Et as an off-white solid. Yield: 353.6 mg, quantitative yield.

[0160] .sup.1H NMR (400.36 MHz, C.sub.6D.sub.6, 299 K): 0.99 (6H, dt, .sup.3J.sub.HH=7.6 Hz, .sup.2J.sub.HP=7.7 Hz, P(CH.sub.2CH.sub.3).sub.2), 1.12 (6H, d, .sup.3J.sub.HH=6.8 Hz, CH(CH.sub.3).sub.2), 1.21 (6H, d, .sup.3J.sub.HH=6.8 Hz, CH(CH.sub.3).sub.2), 1.30 (4H, q, .sup.3J.sub.HH=7.6 Hz, P(CH.sub.2CH.sub.3).sub.2), 1.35 (4H, q, .sup.3J.sub.HH=7.6 Hz, P(CH.sub.2CH.sub.3).sub.2), 2.74 (2H, septet, .sup.3J.sub.HH=6.8 Hz, 2CH(CH.sub.3).sub.2), 3.00 (2H, s, CH.sub.2), 6.86 (2H, overlapping two d, .sup.3J.sub.HH=7.7 Hz and .sup.3J.sub.HH=7.6 Hz, aromatic 2CH), 7.12 (1H, t, .sup.3J.sub.HH=7.7 Hz, aromatic CH), 7.21 (2H, d, .sup.3J.sub.HH=7.8 Hz, aromatic 2CH), 7.34 (1H, pseudo t, aromatic CH).

[0161] .sup.13C{.sup.1H}NMR (100.67 MHz, C.sub.6D.sub.6, 299 K): 10.0 (d, .sup.2J.sub.CP=14.5 Hz, P(CH.sub.2CH.sub.3).sub.2), 19.3 (d, .sup.1J.sub.CP=14.7 Hz, P(CH.sub.2CH.sub.3).sub.2), 24.2 (s, CH(CH.sub.3).sub.2), 24.5 (s, CH(CH.sub.3).sub.2), 30.8 (s, 2CH(CH.sub.3).sub.2), 36.7 (d, .sup.1J.sub.CP=20.4 Hz, CH.sub.2), 121.7 (d, .sup.3J.sub.CP=4.7 Hz, aromatic), 121.8 (s, aromatic), 122.9 (s, 2 aromatic CH), 128.8 (s, aromatic), 135.7 (s, aromatic), 139.8 (s, aromatic, ipso), 146.8 (s, 2 aromatic ipso C), 159.4 (d, .sup.2J.sub.CP=3.9 Hz, aromatic), 160.0 (s, aromatic, ipso).

[0162] .sup.31P{.sup.1H}NMR (162.07 MHz, C.sub.6D.sub.6, 299 K): 14.3.

[0163] HRMS (ESI.sup.+) m/z calcd for C.sub.22H.sub.32NPNa.sup.+ ([M+Na].sup.+): 364.2170. Found: 364.2170.

2-(2,6-diisopropylphenyl)-6-(diethylphophinomethyl)pyridine (PNdipp-Ph)

##STR00020##

[0164] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with 2-(2,6-Diisopropylphenyl)-6-methylpyridine (synthesis described above; 127.0 mg, 0.50 mmol) and 5 mL ether. The clear faint yellow solution was cooled to 35 C. To the cold solution was added 1.6 M .sup.nBuLi in hexanes (0.32 mL, 0.51 mmol) dropwise. The dark red solution was stirred at r.t. for 1 h, and cooled to 35 C. To the solution was then added diphenylchlorophosphine (111.3 mg, 0.50 mmol) in 2 mL ether. The solution was stirred for 30 min at r.t., quenched by 0.5 mL methanol, and concentrated. The product was extracted using n-pentane. Concentration of the pentane extract gave PNdipp-Ph as a colorless oil. Yield: 224.0 mg, quantitative yield. Known compound. Reference: F. Speiser, P. Braunstein, L. Saussine, Organometallics 23, 2633 (2004).

2-(2,6-diisopropylphenyl)-6-[1-(diisopropylphophino)-1,1-dimethylethyl]pyridine (23, PNdipp-.SUP.i.Pr-Me.SUB.2.)

##STR00021##

[0165] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with PNdipp-.sup.iPr (synthesis described above; 184.1 mg, 0.498 mmol) trimethylsilylmethyllithium (48.1 mg, 0.511 mmol), and 7 mL ether. The dark red solution was stirred at r.t. for 15 min. To the solution was added MeI (31 L, 0.498 mmol), and the solution was stirred at r.t. for 15 min. Trimethylsilylmethyllithium (47.3 mg, 0.502 mmol) was then added again. The dark red solution was stirred at r.t. for 15 min. To the solution was then added MeI (31 L, 0.498 mmol). The solution was stirred at r.t. for 15 min, quenched by 0.5 mL methanol, and concentrated. The product was extracted from the resulting solid using n-pentane. Concentration of the pentane extract gave PNdipp-.sup.iPr-Me.sub.2 as a faint yellow solid. Yield: 186.0 mg, 94%.

[0166] .sup.1H NMR (400.36 MHz, CDCl.sub.3, 291 K): 0.95 (6H, dd, .sup.3J.sub.HH=7.0 Hz, .sup.3J.sub.HP=10.3 Hz, PCH(CH.sub.3).sub.2), 1.11 (6H, dd, .sup.3J.sub.HH=7.2 Hz, .sup.3J.sub.HP=14.2 Hz, PCH(CH.sub.3).sub.2), 1.14 (6H, d, .sup.3J.sub.HH=6.9 Hz, CH(CH.sub.3).sub.2), 1.23 (6H, d, .sup.3J.sub.HH=6.9 Hz, CH(CH.sub.3).sub.2), 1.63 (6H, d, .sup.3J.sub.HP=9.6 Hz, 2CH.sub.3), 1.81(2H, d septet, .sup.3J.sub.HH=7.0 Hz, .sup.2J.sub.HP=4.2 Hz, 2PCH(CH.sub.3).sub.2), 2.73 (2H, septet, .sup.3J.sub.HH=6.8 Hz, 2CH(CH.sub.3).sub.2), 6.82 (1H, d, .sup.3J.sub.HH=7.6 Hz, aromatic CH), 7.16 (1H, overlapping with a residual C.sub.6D.sub.6 peak, aromatic CH), 7.21 (2H, d, .sup.3J.sub.HH=7.6 Hz, aromatic 2CH), 7.34 (2H, m, aromatic 2CH).

[0167] .sup.13C{.sup.1H}NMR (100.67 MHz, C.sub.6D.sub.6, 298 K): 20.4 (d, .sup.2J.sub.CP=10.0 Hz, PCH(CH.sub.3).sub.2), 22.7 (d, .sup.1J.sub.CP=23.3 Hz, 2PCH(CH.sub.3).sub.2), 23.4 (d, .sup.2J.sub.CP=22.0 Hz, PCH(CH.sub.3).sub.2), 24.2 (s, CH(CH.sub.3).sub.2), 24.8 (s, CH(CH.sub.3).sub.2), 27.5 (d, .sup.2J.sub.CP=12.7 Hz, 2CH.sub.3), 30.8 (s, 2CH(CH.sub.3).sub.2), 41.3 (d, .sup.1J.sub.CP=24.5 Hz, C(CH.sub.3).sub.2), 120.2 (d, .sup.3J.sub.CP=9.5 Hz, aromatic), 121.6 (s, aromatic), 123.0 (s, 2 aromatic CH), 128.8 (s, aromatic), 135.4 (s, aromatic), 139.9 (s, aromatic, ipso), 146.8 (s, 2 aromatic ipso C), 158.7 (s, aromatic, ipso), 167.5 (d, .sup.2J.sub.CP=6.0 Hz, aromatic).

[0168] .sup.31P{.sup.1H}NMR (162.07 MHz, C.sub.6D.sub.6, 298 K): 43.7.

[0169] HRMS (ESI.sup.+) m/z calcd for C.sub.26H.sub.41NP.sup.+ ([M+H].sup.+): 398.2977. Found: 398.2970.

2-(2,4,6-trimethylphenyl)-6-(diisopropylphophinomethyl)pyridine (24, PNmes-.SUP.i.Pr)

##STR00022##

[0170] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with 2-(2,4,6-trimethylphenyl)-6-methylpyridine (synthesis described above; 216.8 mg, 1.0 mmol) and 5 mL THF. The clear faint yellow solution was cooled to 35 C. To the cold solution was added 1.6 M .sup.nBuLi in hexanes (0.67 mL, 1.07 mmol) dropwise. The dark red solution was stirred at r.t. for 4 h. To the solution was then added chlorodiisopropylphosphine (154.2 mg, 1.0 mmol) in 3 mL THF. The solution was stirred for 16 h at r.t., quenched by 1 mL methanol, and concentrated. The product was extracted from the resulting solid using CH.sub.2Cl.sub.2. Concentration of the extract gave PNmes-.sup.iPr as a yellow oil. Yield: 204.0 mg, 61%.

[0171] .sup.1H NMR (400.36 MHz, C.sub.6D.sub.6, 298 K): 1.00 (6H, dd, .sup.3J.sub.HH=7.0 Hz, .sup.3J.sub.HP=12.1 Hz PCH(CH.sub.3).sub.2), 1.03 (6H, dd, .sup.3J.sub.HH=7.1 Hz, .sup.3J.sub.HP=9.7 Hz PCH(CH.sub.3).sub.2), 2.14 (6H, s, 2CH.sub.3), 2.19 (3H, s, CH.sub.3), 3.02 (2H, d, .sup.2J.sub.HP=1.7 Hz, CH.sub.2), 6.73 (H, pseudo d, aromatic CH), 6.86 (2H, s, aromatic 2CH), 7.14 (2H, m, overlapping with a residual C.sub.6D.sub.6 peak, aromatic 2CH).

[0172] .sup.13C{.sup.1H}NMR (100.67 MHz, C.sub.6D.sub.6, 298 K): 19.1 (d, .sup.2J.sub.CP=10.6 Hz, PCH(CH.sub.3).sub.2), 20.0 (d, .sup.2J.sub.CP=15.6 Hz, PCH(CH.sub.3).sub.2), 20.6 (s, 2CH.sub.3), 21.2 (s, CH.sub.3) 24.0 (d, J.sub.CP=15.7 Hz, 2PCH(CH.sub.3).sub.2), 33.2 (d, J.sub.CP=23.1 Hz, CH.sub.2), 121.4 (d, .sup.3J.sub.CP=7.1 Hz, aromatic), 121.6 (s, aromatic), 128.6 (s, aromatic), 135.8 (s, aromatic, ipso), 136.1 (s, aromatic), 137.0 (s, aromatic, ipso), 139.2 (s, aromatic, ipso), 160.0 (s, aromatic, ipso), 161.3 (d, .sup.2J.sub.CP=9.3 Hz, aromatic).

[0173] .sup.31P{.sup.1H}NMR (121.50 MHz, CDCl.sub.3, 297 K): 13.7.

[0174] HRMS (ESI.sup.+) m/z calcd for C.sub.21H.sub.31NP.sup.+ ([M+H].sup.+): 328.2194. Found: 328.2196.

2-(2,6-diisopropylphenyl)-6-(diisopropylphophinomethyl)pyridine-d.SUB.2.(25, PNdipp-.SUP.i.Pr-d.SUB.2.)

##STR00023##

[0175] In a nitrogen glove box, PNdipp-.sup.iPr was prepared using 2-(2,6-diisopropylphenyl)-6-methylpyridine (synthesis described above; 128.3 mg, 0.5 mmol), 1.6 M .sup.nBuLi in hexanes (0.32 mL, 0.51 mmol), and chlorodiisopropylphosphine (78.4 mg, 0.51 mmol). To a 20 mL vial containing PNdipp-.sup.iPr was then added KO.sup.tBu (59 mg, 0.53 mmol). The content of vial was then quantitatively transferred into a J. Young NMR tube using THF (0.7 mL) and CD.sub.3OD (0.5 mL). The solution was heated for 16 h at 80 C. and monitored by .sup.1H NMR. .sup.1H NMR spectra after 16 h of heating showed 91% deuteration of the benzylic CH.sub.2. The concentrated solution was extracted using pentane, and concentrated to dryness. PNdipp-.sup.iPr-d.sub.2 was obtained as a off-white solid. Yield: 170.1 mg, 90%.

[0176] .sup.1H NMR (400.36 MHz, CDCl.sub.3, 298 K): 1.06 (18H, overlapping d, 2PCH(CH.sub.3).sub.2 and CH(CH.sub.3).sub.2), 1.12 (6H, d, .sup.3J.sub.HH=6.8 Hz, CH(CH.sub.3).sub.2), 1.84 (2H, br 2PCH(CH.sub.3).sub.2), 2.50 (2H, br, 2CH(CH.sub.3).sub.2), 3.05 (0.19H, br, residual CH.sub.2), 7.02 (1H, d, .sup.3J.sub.HH=6.8 Hz, aromatic CH), 7.19 (2H, d, .sup.3J.sub.HH=7.6 Hz, aromatic 2CH), 7.32 (1H, d, .sup.3J.sub.HH=8.0 Hz, aromatic CH), 7.37 (1H, d, .sup.3J.sub.HH=9.2 Hz, aromatic CH), 7.62 (1H, br t, .sup.3J.sub.HH=7.1 Hz aromatic CH).

[0177] .sup.13C{.sup.1H}NMR (100.67 MHz, CDCl.sub.3, 291 K): 19.0 (d, .sup.2J.sub.CP=9.2 Hz, PCH(CH.sub.3).sub.2), 19.8 (d, .sup.2J.sub.CP=14.9 Hz, PCH(CH.sub.3).sub.2), 23.6 (d, .sup.1J.sub.CP=15.0 Hz, 2PCH(CH.sub.3).sub.2), 23.8 (s, CH(CH.sub.3).sub.2), 24.3 (s, CH(CH.sub.3).sub.2), 30.2 (s, 2CH(CH.sub.3).sub.2), 32.1 (detected by .sup.1H-.sup.13C HSQC, CH.sub.2), 121.6 (d, .sup.3J.sub.CP=7.3 Hz, aromatic), 121.8 (s, aromatic), 122.6 (s, 2 aromatic CH), 128.3 (s, aromatic), 135.6 (s, aromatic), 139.0 (s, aromatic, ipso), 146.4 (s, 2 aromatic ipso C), 159.0 (s, aromatic, ipso), 160.3 (br, aromatic, ipso). .sup.2H NMR (61.46 MHz, CDCl.sub.3, 298 K) 3.08.

[0178] .sup.31P{.sup.1H}NMR (121.50 MHz, CDCl.sub.3, 291 K): 13.0 (PNdipp-.sup.iPr-d.sub.2, 86%), 13.2 (PNdipp-.sup.iPr-d.sub.1, 14%).

[0179] HRMS (ESI.sup.+) m/z calcd for C.sub.24H.sub.35D.sub.2NP.sup.+ ([M+H].sup.+): 372.2789. Found: 372.2791.

2-(2,4,6-triisopropylphenyl)-6-(diisopropylphophinomethyl)pyridine (26, PNtipp-.SUP.i.Pr)

##STR00024##

[0180] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with 2-(2,4,6-triisopropylphenyl)-6-methylpyridine (297.0 mg, 1.00 mmol) and 10 mL ether. The clear faint yellow solution was cooled to 35 C. To the cold solution was added 1.6 M .sup.nBuLi in hexanes (0.65 mL, 1.04 mmol) dropwise. The orange suspension was stirred at r.t. for 1 h, and cooled to 35 C. To the solution was then added chlorodiisopropylphosphine (155.0 mg, 1.02 mmol) in 3 mL ether. The solution was stirred for 17 h at r.t., quenched by 0.5 mL methanol, and concentrated. The product was extracted from the resulting solid using n-pentane. Concentration of the pentane extract gave PNdipp-.sup.iPr as an off-white solid. Yield: 394.5 mg, 95%.

[0181] .sup.1H NMR (500.08 MHz, C.sub.6D.sub.6, 298 K): 1.02 (6H, overlapping dd, .sup.3J.sub.HH=7.1 Hz, .sup.2J.sub.HP=13.5 Hz, PCH(CH.sub.3).sub.2), 1.05 (6H, overlapping dd, .sup.3J.sub.HH=7.0 Hz, .sup.2J.sub.HP=11.2 Hz, PCH(CH.sub.3).sub.2), 1.22 (6H, d, .sup.3J.sub.HH=6.5 Hz, 2,6-CH(CH.sub.3).sub.2), 1.29 (6H, d, .sup.3J.sub.HH=7.0 Hz, 2,6-CH(CH.sub.3).sub.2), 1.31 (6H, d, .sup.3J.sub.HH=7.0 Hz, 4-CH(CH.sub.3).sub.2), 1.70 (1H, d septet, .sup.3J.sub.HH=7.0 Hz, .sup.2J.sub.HP=1.6 Hz, 2PCH(CH.sub.3).sub.2), 2.85 (2H, septet, .sup.3J.sub.HH=6.9 Hz, 2,6-CH(CH.sub.3).sub.2), 2.90 (2H, septet, .sup.3J.sub.HH=7.0 Hz, 4-CH(CH.sub.3).sub.2), 3.04 (2H, d, .sup.2J.sub.HP=1.8 Hz, CH.sub.2), 6.91 (1H, dd, .sup.3J.sub.HH=6.8 Hz, .sup.4J.sub.HH=1.9 Hz, aromatic CH), 7.16 (2H, overlapping m, aromatic 2CH), 7.25 (2H, s, aromatic 2CH).

[0182] .sup.13C{.sup.1H}NMR (125.75 MHz, C.sub.6D.sub.6, 298 K): 19.1 (d, .sup.2J.sub.CP=10.8 Hz, PCH(CH.sub.3).sub.2), 19.9 (d, .sup.2J.sub.CP=15.5 Hz, PCH(CH.sub.3).sub.2), 23.9 (d, J.sub.CP=15.5 Hz, 2PCH(CH.sub.3).sub.2), 24.3 (s, 2,6-CH(CH.sub.3).sub.2), 24.4 (s, 2,6-CH(CH.sub.3).sub.2), 24.6 (s, 4-CH(CH.sub.3).sub.2), 30.8 (s, 2,6-CH(CH.sub.3).sub.2), 33.2 (d, J.sub.CP=23.5 Hz, CH.sub.2), 34.9 (s, 4-CH(CH.sub.3).sub.2), 120.8 (s, 2 aromatic CH), 121.5 (d, .sup.3J.sub.CP=7.5 Hz, aromatic), 122.0 (s, aromatic), 135.6 (s, aromatic), 137.7 (s, aromatic, ipso), 146.8 (s, 2 aromatic, ipso CH), 148.8 (s, aromatic, ipso), 160.0 (s, aromatic, ipso), 160.9 (d, .sup.2J.sub.CP=9.2 Hz, aromatic, ipso).

[0183] .sup.31P{.sup.1H}NMR (121.50 MHz, CDCl.sub.3, 291 K): 12.5.

[0184] HRMS (ESI.sup.+) m/z calcd for C.sub.24H.sub.37NP.sup.+ ([M+H].sup.+): 412.3133. Found: 412.3129.

Example 2

Preparation of PN Iron Complexes of Structure A3

FeCl.SUB.2.(PNdipp-.SUP.i.Pr) (1)

##STR00025##

[0185] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with FeCl.sub.2 (13.4 mg, 0.106 mmol), PNdipp-.sup.iPr (synthesis described in Example 1; 37.5 mg, 0.101 mmol) and 2 mL THF. The off-white suspension was stirred at r.t. for 6 h, filtered through Celite, and the Celite was washed with THF. The THF solution was concentrated, and n-pentane was added for crystallization. The off-white micro-crystalline solid was washed by pentane, and vacuum dried. Yield: 41.2 mg, 82%.

[0186] .sup.1H NMR (300.13 MHz, C.sub.6D.sub.6, 291 K) 9.8 (2H), 8.4 (1H), 3.7 (6H), 2.7 (12H), 5.8, 5.9 (overlapping 3H), 8.7 (6H), 43.8 (1H), 46.4 (1H), 102.5 (2H) 130.7 (2H).

[0187] Elemental analysis: Calcd: H:7.31, C:58.08, N:2.82. Found: H:7.44, C:57.31, N:2.72.

[0188] .sub.eff (Evans' method, CDCl.sub.3, 292.6 K)=5.1 .sub.B.

[0189] Diffusion coefficient (0.02 M in C.sub.6D.sub.6, 298 K): 0.87710.sup.9(0.008) m.sup.2/s.

[0190] The X-ray structure of 1 is presented in FIG. 4 and its experimental details is presented in Table 1. The XRD analysis showed that 1 exhibits a tetrahedral geometry.

FeCl.SUB.2.(PNdipp-.SUP.i.Pr-d.SUB.2.) (1-d.SUB.2.)

##STR00026##

[0191] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with FeCl.sub.2 (62.3 mg, 0.49 mmol), PNdipp-.sup.iPr-d.sub.2 (37.5 mg, 0.46 mmol) and 6 mL THF. The off-white suspension was stirred at r.t. for 3 h, filtered through Celite, and the Celite was washed by THF. The THF solution was concentrated to ca.1 mL, and submitted to crystallization from THF/n-pentane. The off-white micro-crystalline solid was washed by pentane, and vacuum dried. Yield: 119.7 mg, 52%.

[0192] .sup.1H NMR (300.13 MHz, C.sub.6D.sub.6, 294 K) 9.8 (2H), 8.2 (1H), 3.7 (6H), 2.7 (12H), 5.8, 5.9 (overlapping 3H), 8.9 (6H), 43.5 (1H), 46.2 (1H), 129.4 (2H).

[0193] .sup.2H NMR (61.46 MHz, C.sub.6H.sub.6, 298 K) 101.5.

[0194] Elemental analysis: Calcd: H:7.69, C:57.85, N:2.81. Found: H:7.33, C:57.75, N:2.76.

[0195] .sub.eff (Evans' method, CDCl.sub.3, 292.6 K)=5.4 .sub.B. This is consistent with formation of high spin, S=2, Fe(II) complexes.

FeBr.SUB.2.(PNdipp-.SUP.i.Pr) (2)

##STR00027##

[0196] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with FeBr.sub.2 (106.6 mg, 0.494 mmol), PNdipp-.sup.iPr (synthesis described in Example 1; 184.2 mg, 0.498 mmol) and 8 mL THF. The brown suspension was stirred at r.t. for 6 h, filtered through Celite, and the Celite was washed with THF. The THF solution was concentrated to dryness, and submitted to recrystallization from benzene/n-pentane. The off-white micro-crystalline solid was washed by pentane, and vacuum dried. Yield: 267.1 mg, 92%.

[0197] .sup.1H NMR (300.13 MHz, CD.sub.6, 291 K) 13.0 (2H), 8.5 (1H), 4.2 (6H), 1.5 (6H), 6.1, 6,9, 7.6 (overlapping 3 peaks, 15H), 45.7 (1H), 48.6 (1H), 119.0 (2H) 130.5 (2H).

[0198] Elemental analysis: Calcd: H:6.20, C:49.26, N:2.39. Found: H:6.22, C:49.77, N:1.99.

[0199] .sub.eff (Evans' method, CDCl.sub.3, 292.6 K)=5.2 .sub.B. This is consistent with formation of high spin, S=2, Fe(II) complexes.

[0200] X-ray structure of 2 is presented in FIG. 5 and its experimental details is presented in Table 1. The XRD analysis showed that 2 exhibits a tetrahedral geometry.

TABLE-US-00001 TABLE 1 XRD experimental detail for 1 and 2. 1 2 Empirical formula C24 H36 Cl2 Fe N P C24 H36 Br2 Fe N P Formula weight (g/mol) 496.26 585.18 Temperature (K) 120(2) 100(2) Wavelength () 0.71073 0.71073 Crystal system Tetragonal Tetragonal Space group P4.sub.2/n P4.sub.2/n a() 24.9310(5) 25.090(3) b () 24.9310(5) 25.090(3) c () 8.43400(10) 8.5077(10) () 90.0000(11) 90 () 90.0000(11) 90 () 90.0000(9) 90 Volume (.sup.3) 5242.2(2) 5355.5(15) Z 8 8 Density (calculated) (Mg/m.sup.3) 1.258 1.452 Absorption coefficient (mm.sup.1) 0.851 3.618 F(000) 2096 2384 Crystal size (mm.sup.3) 0.50 0.05 0.05 0.943 0.164 0.124 Theta range for data collection () 1.634 to 27.498 2.296 to 26.344 Reflections collected 76928 40789 Independent reflections 6016 [R(int) = 0.1434] 5461 [R(int) = 0.0671] Completeness (to theta = ) 99.9% (25.242) 100% (25.242) Absorption correction Cylinder Semi-empirical from equivalents Max. and min. transmission 0.811 and 0.804 0.7782 and 0.2388 Refinement method Full-matrix least-squares on F.sup.2 Full-matrix least-squares on F.sup.2 Data/restraints/parameters 6016/0/270 5461/0/270 Goodness-of-fit on F.sup.2 0.916 1 Final R indices [I > 2sigma(I)] R1 = 0.0356, wR2 = 0.0775 R1 = 0.0345, wR2 = 0.0622 R indices (all data) R1 = 0.0721, wR2 = 0.0855 R1 = 0.0687, wR2 = 0.0722 Extinction coefficient n/a n/a Largest diff. peak and hole (e .Math. .sup.3) 0.317 and 0.538 0.591 and 0.330

FeCl.SUB.2.(PNdipp-.SUP.t.Bu) (3)

##STR00028##

[0201] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with FeCl.sub.2 (25.1 mg, 0.198 mmol), PNdipp-Bu (synthesis described in Example 1; 82.0 mg, 0.206 mmol) and 2 mL THF. The off-white suspension was stirred at r.t. for 8 h, filtered through Celite, and the Celite was washed with THF. The THF solution was concentrated, washed by pentane, and vacuum dried to obtain off-white powder. Yield: 71.7 mg, 69%.

[0202] .sup.1H NMR (300.13 MHz, C.sub.6D.sub.6, 291 K): 12.9 (1H), 9.1 (2H), 3.8 (6H), 3.38 (6H), 5.1, 5.2 (overlapping 3H), 10.0 (18H), 43.3 (1H), 45.1 (1H), 101.3 (2H).

[0203] Elemental analysis: Calcd: H:7.69, C:59.56, N:2.67. Found: H:7.91, C:59.69, N:2.34.

[0204] .sub.eff (Evans' method, CDCl.sub.3, 292.6 K)=4.7 .sub.B. This is consistent with formation of high spin (4.6-5.1), S=2, Fe(II) complexes.

[0205] X-ray structure of 3 is presented in FIG. 6, and its experimental details is presented in Table 2. The XRD analysis showed that 3 exhibits a tetrahedral geometry.

FeCl.SUB.2.(PNdipp-.SUP.i.Pr-Me.SUB.2.) (4)

##STR00029##

[0206] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with FeCl.sub.2 (26.0 mg, 0.205 mmol), PNdipp-.sup.iPr-Me.sub.2 (synthesis described in Example 1; 80.8 mg, 0.203 mmol) and 4 mL THF. The off-white suspension was stirred at r.t. for 17 h, filtered through Celite, and the Celite was washed with THF. The THF solution was concentrated, and submitted to crystallization from THF/n-pentane. The off-white solid was washed by pentane, and vacuum dried. Yield: 92.5 mg, 87%.

[0207] .sup.1H NMR (300.13 MHz, CD.sub.6, 291 K): 15.8 (overlapping 2H), 6.6 (2H), 5.3 (6H), 2.5 (6H), 6.8 (2H) 7.9 (2H), 25.3 (6H) 39.9 (1H), 54.7 (1H), missing 12H for PiPr.sub.2 group.

[0208] Elemental analysis: Calcd: H:7.69, C:59.56, N:2.67. Found: H:7.79, C:60.46, N:2.52.

[0209] .sub.eff (Evans' method, CDCl.sub.3, 293.2 K)=4.7 .sub.B.

[0210] X-ray structure of 4 is presented in FIG. 7, and its experimental details is presented in Table 2.

TABLE-US-00002 TABLE 2 XRD experimental detail for (3) and (4). FeCl.sub.2(PNdipp-.sup.tBu) (3) FeCl.sub.2(PNdipp-.sup.iPr-Me.sub.2)(4) Empirical formula C56 H90 Cl4 Fe2 N2 O P2 C26 H40 Cl2 Fe N P Formula weight (g/mol) 1122.73 524.31 Temperature (K) 100(2) 100(2) Wavelength () 0.71073 1.54184 Crystal system Orthorhombic Triclinic Space group Fdd2 P-1 a() 27.288(2) 8.65510(10) b () 27.6504(16) 11.64840(10) c () 15.7169(8) 17.0741(2) () 90 71.5970(10) () 90 78.7340(10) () 90 83.7520(10) Volume (.sup.3) 11858.6(13) 1599.81(3) Z 8 2 Density (calculated) (Mg/m.sup.3) 1.258 1.088 Absorption coefficient (mm.sup.1) 0.761 5.863 F(000) 4784 556 Crystal size (mm.sup.3) 0.246 0.097 0.090 0.273 0.106 0.016 Theta range for data collection () 2.690 to 26.450 4.005 to 80.034 Reflections collected 20181 56574 Independent reflections 5873 [R(int) = 0.0506] 6894 [R(int) = 0.0754] Completeness (to theta = ) 99.7% (25.242) 99.7% (67.684) Absorption correction Semi-empirical from equivalents Analytical Max. and min. transmission 0.9347 and 0.8351 0.980 and 0.827 Refinement method Full-matrix least-squares on F.sup.2 Full-matrix least-squares on F.sup.2 Data/restraints/parameters 5873/2/326 6894/0/290 Goodness-of-fit on F.sup.2 1.157 1.11 Final R indices [I > 2sigma(I)] R1 = 0.0424, wR2 = 0.0684 R1 = 0.0455, wR2 = 0.1257 R indices (all data) R1 = 0.0500, wR2 = 0.0731 R1 = 0.0488, wR2 = 0.1282 Extinction coefficient n/a n/a Largest diff. peak and hole (e .Math. .sup.3) 0.291 and 0.295 0.704 and 0.483

FeCl.SUB.2.(PNdipp-Et). (5)

##STR00030##

[0211] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with FeCl.sub.2 (25.3 mg, 0.2 mmol), PNdipp-Et (synthesis described in Example 1; 69.3 mg, 0.2 mmol) and 2 mL THF. The off-white suspension was stirred at r.t. for 5 h, filtered through Celite, and the Celite was washed with THF. The THF solution was concentrated to ca. 1 mL, and crystallized with pentane. The crystals were washed with pentane, and vacuum dried. Yield: 76.7 mg, 82%.

[0212] .sup.1H NMR (300.13 MHz, C.sub.6D.sub.6, 291 K): 12.7 (2H), 5.1 (1H), 4.0 (6H), 1.6 (6H), 2.7 (6H), 6.1 (1H), 6.5 (2H) 44.5 (1H), 49.5 (1H), 112.3 (4H), 116.2 (2H).

[0213] Elemental analysis: Calcd: H:6.89, C:56.43, N:2.99. Found: H:6.79, C:55.11, N:2.76.

[0214] .sub.eff (Evans' method, CDCl.sub.3, 293.2 K)=5.1 .sub.B.

FeCl.SUB.2.(PNdipp-Ph) (6)

##STR00031##

[0215] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with FeCl.sub.2 (35 mg, 0.276 mmol), PNdipp-Ph (synthesis described in Example 1; 83 mg, 0.190 mmol) and 6 mL THF. The brown suspension was stired at r.t. for 15 h, filtered through Celite, and the Celite was washed with THF. The THF solution was concentrated to ca. 1 mL. The product was precipitated by the addition of ether to the THF solution. The off-white precipitate was washed with ether, and vacuum dried. Yield: 76.5 mg, 71%.

[0216] .sup.1H NMR (300.13 MHz, C.sub.6D.sub.6, 292 K): 12.7 (2H), 5.2 (2H), 5.0 (1H), 4.2 (6H), 1.8 (4H), 1.8 (6H), 5.6 (1H), 6.2 (2H), 16.9 (4H), 43.7 (1H), 51.1 (1H), 127.9 (2H).

[0217] Elemental analysis: Calcd: H:5.72, C:63.85, N:2.48. Found: H:5.70, C:63.72, N:2.32.

[0218] .sub.eff (Evans' method, CDCl.sub.3, 293.2 K)=4.8 .sub.B.

FeCl.SUB.2.(PNmes-.SUP.i.Pr). (7)

##STR00032##

[0219] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with FeCl.sub.2 (26.6 mg, 0.21 mmol), PNmes-.sup.iPr (Synthesis described in Example 1; 74.1 mg, 0.23 mmol) and 4 mL THF. The yellow suspension was stirred at r.t. for 17 h, concentrated, and extracted with CH.sub.2Cl.sub.2. Concentration of the solution gave faint yellow crystals. The crystals were washed by ether, and vacuum dried. Yield: 90.9 mg, 95%.

[0220] .sup.1H NMR (300.13 MHz, C.sub.6D.sub.6, 291 K): 15.6 (1H), 4.2 (6H), 0.9 (3H), 1.3 (3H), 3.9 (3H), 6.2 (2H) 11.9 (6H), 43.4 (1H), 47.3 (1H), 100.0 (2H), 137.5 (2H).

[0221] Elemental analysis: Calcd: H:6.66, C:55.53, N:3.08. Found: H:6.59, C:53.48, N:2.77.

[0222] .sub.eff (Evans' method, CDCl.sub.3, 293.6 K)=5.3 .sub.B.

Complex 8

##STR00033##

[0223] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with FeCl.sub.2 (63.8 mg, 0.503 mmol), PNtipp-.sup.iPr (204.1 mg, 0.496 mmol) and 5 mL THF. The off-white suspension was stirred at r.t. for 16 h, filtered through Celite, and the Celite was washed with THF. The THF solution was concentrated, and n-pentane was added for crystallization. The off-white micro-crystalline solid was washed with pentane, and vacuum dried. Yield: 193.7 mg, 73%.

[0224] .sup.1H NMR (300.13 MHz, C.sub.6D.sub.6, 293 K) 10.3 (2H), 8.1 (1H), 3.8 (6H), 2.7 (18H), 4.5 (1H), 6.0 (2H), 8.3 (6H), 43.6 (1H), 46.5 (1H), 102.7 (2H) 128.2 (2H).

[0225] Elemental analysis: Calcd: H:7.86, C:60.24, N:2.60. Found: H:7.69, C:57.53, N:2.49.

[0226] .sub.eff (Evans' method, CDCl.sub.3, 292.6 K)=4.6 .sub.B.

Example 3

Preparation of PN Iron Complexes of Structures A1 and A2

Complex 9

##STR00034##

[0227] In a nitrogen glove box, to a NMR tube equipped with a septa were added complex 1 (7.4 mg, 0.015 mmol), trimethylsilylmethyllithium (2.9 mg, 0.031 mmol), and 0.5 mL C.sub.6D.sub.6. The solution was mixed by shaking the tube, and monitored by .sup.1H NMR at r.t. .sup.1H NMR spectra after 4 h showed full conversion of 1 and formation of 9 and SiMe.sub.4.

[0228] .sup.1H NMR (300.13 MHz, C.sub.6D.sub.6, 291 K) 134.1 (6H), 83.7 (6H), 50.5 (6H), 48.9 (1H), 45.2 (2H), 13.3 (6H), 68.4 (2H), 76.7 (1H), 84.1 (9H), 110.7 (1H), 178.1 (1H).

[0229] .sub.eff (Evans' method, C.sub.6H.sub.6, 292.5 K)=5.3 .sub.B (per Fe atom).

[0230] Diffusion coefficient (0.02 M in C.sub.6D.sub.6, 298 K): 0.63310.sup.9(0.019) m.sup.2/s.

[0231] Elemental analysis: Calcd: H:9.06, C:65.74, N:2.74. Found: H:9.10, C:65.25, N:2.41.

Complex 10

##STR00035##

[0232] In a nitrogen glove box, a 4 mL vial was charged with 1 (5.2 mg, 0.011 mmol), neopentyllithium (1.8 mg, 0.023 mmol), and 0.5 mL C.sub.6D.sub.6. The solution was mixed by swirling the vial at r.t., and transferred into a J. Young NMR tube. .sup.1H NMR spectra after 30 min showed full conversion of 1 and formation of 10 and CMe.sub.4.

[0233] .sup.1H NMR (300.13 MHz, C.sub.6D.sub.6, 292 K, 20 mM) 132.5 (6H, 2,6-CH(CH.sub.3).sub.2), 89.0 (6H, PCH(CH.sub.3).sub.2), 50.5 (1H, para-CH of 2,6-Pr.sub.2C.sub.6H.sub.3), 49.6 (6H, PCH(CH.sub.3).sub.2), 43.9 (2H, two ortho-CH of 2,6-.sup.iPr.sub.2C.sub.6H.sub.3), 13.1 (6H, 2,6-CH(CH.sub.3).sub.2), 70.0 (2H, P{CH(CH.sub.3).sub.2}), 75.6 (1H, CH from pyridine ring), 106.7 (1H, CH from pyridine ring), 158.2 (9H, CMe.sub.3), 182.1 (1H, CH from pyridine ring), 300.0 (1H, CHP.sup.iPr.sub.2). .sup.1H NMR signals from 2,6-CH(CH.sub.3).sub.2 and CH.sub.2CMe.sub.3 were not detectable due to proximity to the iron center.

[0234] Elemental analysis: Calcd: H:9.36, C:70.29, N:2.83. Found: H:9.32, C:69.25, N:2.58.

[0235] .sub.eff (Evans' method, C.sub.6D.sub.6, 292.0 K)=5.8 .sub.B.

[0236] Diffusion coefficient (20 mM in C.sub.6D.sub.6, 298 K): 0.80410.sup.9(0.018) m.sup.2/s.

NMR Diffusion Measurements:

[0237] NMR diffusion measurements were performed using an Avance III HD Bruker 500 MHz spectrometer equipped with a gradient system capable of producing magnetic field pulse gradients in the z-direction of about 50 G cm.sup.1. The diffusion experiments were performed using the LED (longitudinal eddy current delay) diffusion sequence. Sine shape pulsed-gradients of 6 ms duration were incremented from 0.7 to 32.2 G cm.sup.1 in 10 linear steps and the pulse gradient separation was 7 ms. All experiments were performed three times using residual C.sub.6D.sub.6 signal as a secondary reference, and the reported values are means with standard deviation in a bracket. All measurements were performed at 298 K using 0.02 M solutions, and analyzed using TopSpin 3.5.

Stock Solution of Complex 9, or 10.

[0238] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with 1 (25 mg, 0.05 mmol), and trimethylsilylmethyllithium or neopentyllithiu.sup.m(0.10 mmol). 5.00 mL C.sub.6H.sub.6 was then added to the vial to form a clear red solution. The solution was stirred at r.t. for 5 h or 30 min for 9 or 10, respectively, to form dark red solution. The solution was then filtered through Celite to remove LiCl. An aliquot of this solution was analyzed by .sup.1H NMR to confirm the cle.sub.an formation of 9 or 10. The resulting dark red solution was used as an 0.0050 M stock solution of 9 or 10.

Complex 11

##STR00036##

[0239] In a nitrogen glove box, to a 20 mL vial equipped with a Teflon coated stirring bar were added complex 3 (26.2 mg, 0.050 mmol), trimethylsilylmethyllithium (10.2 mg, 0.108 mmol), and 3 mL C.sub.6H.sub.6. The solution was stirred for 4 h at r.t. The solution was concentrated to dryness. The resulting black oil was extracted using pentane, and the pentane solution was concentrated to ca. 0.1 mL. Black crystals of 11 were obtained from the solution upon storing the solution at 25 C. for overnight. The supernatant solution was removed, and the crystal was dried under high vacuum. Yield: 23.4 mg, 87%.

[0240] .sup.1H NMR (500.08 MHz, C.sub.6D.sub.6, 298 K, 40 mM) 127.2 (6H, 2,6-CH(CH.sub.3).sub.2), 79.7 (6H, PCH(CH.sub.3).sub.2), 47.5 (6H, PCH(CH.sub.3).sub.2), 46.3 (1H, para-H of 2,6-.sup.iPr.sub.2C.sub.6H.sub.3), 42.4 (2H, ortho-H of 2,6-.sup.iPr.sub.2C.sub.6H.sub.3), 12.6 (6H, 2,6-CH(CH.sub.3).sub.2), 69.0 (2H, P{CH(CH.sub.3).sub.2}), 73.2 (1H, CH from pyridine ring), 80.6 (9H, SiMe.sub.3), 106.6 (1H, CH from pyridine ring), 171.7 (1H, CH from pyridine ring), 286.3 (1H, CHP.sup.iPr.sub.2). .sup.1H NMR signals from 2,6-CH(CH.sub.3).sub.2 and CH.sub.2SiMe.sub.3 were not detectable due to proximity to the iron center.

[0241] Elemental analysis: Calcd: H:9.34, C:66.77, N:2.60. Found: H:9.42, C:66.77, N:2.48.

[0242] .sub.eff (Evans' method, C.sub.6D.sub.6, 292.5 K)=6.1 .sub.B

[0243] Effective g value (9.381 GHz, C.sub.6H.sub.6, 5 K)=8.0.

[0244] Diffusion coefficient (17 mM in C.sub.6D.sub.6, 298 K): 0.83510.sup.9(0.007) m.sup.2/s.

[0245] Solid state structure of 11 was obtained using XRD. The XRD analysis of 11 showed a 3-coordinate, trigonal planar iron-alkyl complex with a dearomatized pyridine ligand, and a short iron-carbon bond (2.0176 ).

[0246] Broad X-band EPR signals with effective g-value of 8.0 for 11 is consistent with S=2, Fe(II) complexes. The solution magnetic moment of is consistent with high-spin, S=2, trigonal planar Fe(II) complexes with a large spin-orbit coupling due to the small bite angle of the PN ligands. Despite the dimeric solid state structure of 12, the similarity of the .sup.1H NMR spectra of 9, 10, and 12 supports formation of monomeric, trigonal planer Fe(II)-alkyl complex in solution. The observation of CHPR.sup.1.sub.2 signals supports formation of monomeric species, since a CH peak adjacent to paramagnetic iron is known to be .sup.1H NMR silent. .sup.1H NMR signals along the FeC axis are shifted downfield, and signals perpendicular to the FeC axis are shifted upfield due to the large spin-orbit coupling. The concentration dependent change of the .sup.1H NMR chemical shift of 9, 10, and 12 suggests the presence of dimer-monomer equilibrium in solution.

Complex 12

##STR00037##

[0247] In a nitrogen glove box, to a 20 mL vial equipped with a Teflon coated stirring bar were added complex 8 (53.8 mg, 0.100 mmol), trimethylsilylmethyllithium (19.9 mg, 0.211 mmol), and 4 mL C.sub.6H.sub.6. The solution was stirred for 5 h at r.t. The solution was concentrated to dryness. The resulting oil was extracted using pentane, and the pentane solution was concentrated to ca. 0.1 mL. Black crystals of 12 were obtained from the solution upon storing the solution at 25 C. for overnight. The supernatant solution was removed, and the crystal was dried under high vacuum. Yield: 29.5 mg, 53%. .sup.1H NMR signals from 2,6-CH(CH.sub.3).sub.2 and CH.sub.2SiMe.sub.3 were not detectable due to proximity to the iron center.

[0248] .sup.1H NMR (300.13 MHz, C.sub.6D.sub.6, 293.7 K, 18 mM) 135.8 (6H, 2,6-CH(CH.sub.3).sub.2), 85.7 (6H, PCH(CH.sub.3).sub.2), 50.0 (6H, PCH(CH.sub.3).sub.2), 46.1 (2H, ortho-H of 2,4,6-.sup.iPr.sub.2C.sub.6H.sub.3), 14.2 (6H, 2,6-CH(CH.sub.3).sub.2), 10.3 (1H, 4-CH(CH.sub.3).sub.2), 8.7 (6H, 4-CH(CH.sub.3).sub.2), 67.8 (2H, P{CH(CH.sub.3).sub.2}), 76.3 (1H, CH from pyridine ring), 85.4 (9H, SiMe.sub.3), 112.4 (1H, CH from pyridine ring), 178.6 (1H, CH from pyridine ring), 294.8 (1H, CHP.sup.iPr.sub.2).

[0249] Elemental analysis: Calcd: H:9.47, C:67.25, N:2.53. Found: H:9.97, C:69.48, N:2.36.

[0250] .sub.eff (Evans' method, C.sub.6D.sub.6, 293.7 K)=5.6 .sub.B.

[0251] .sub.eff (SQUID, 300.0 K)=5.2 .sub.B.

[0252] Diffusion coefficient (17 mM in C.sub.6D.sub.6, 298 K): 0.77210.sup.9 (0.016) m.sup.2/s.

[0253] Complex 12 crystalized as a dimer (13). The XRD structure of 13 (the dimer of 12) exhibited dimerization of 3-coordinate iron centers via the deprotonated PN ligands to form 4-coordinate tetrahedral iron centers. The increased FeCSi angle of 124.56 in 13 indicates the presence of steric congestion around the iron center which may promote -hydrogen elimination or abstruction.

Complex 14

##STR00038##

[0254] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with 1 (49.4 mg, 0.10 mmol), trimethylsilylmethyllithium (1.98 mg, 0.21 mmol), and 3.00 mL C.sub.6H.sub.6. The solution was stirred for 7 h at r.t. To the dark red solution was added 4-dimethylaminopyridine (12.5 mg, 0.10 mmol) as a solid. The solution was stirred for 10 min to form a dark brown solution, and concentrated to dryness. The brown solid was extracted with pentane. Dark brown crystalline plates of 14 were obtained from a concentrated (ca. 1 ml) pentane solution at 35 C. The crystals were washed three times with cold pentane, and vacuum dried. Yield: 55.4 mg, 88%.

[0255] .sup.1H NMR (300.13 MHz, toluene-d.sub.8, 293 K) 36.0 (1H), 23.6 (3H), 12.7 (3H), 9.2 (3H), 6.3 (3H), 4.6 (3H), 1.1 (3H), 0.9 (3H), 4.1 (6H), 5.6 (3H), 9.2 (overlapping 4H), 19.3 (9H), 33.0 (2H), 39.3 (1H), 61.1 (1H), 69.0 (1H), 139.2 (br, 2H), 171.2 (1H), 179.8 (1H), a peak with 1H integration was not detected.

[0256] Elemental analysis: Calcd: H:6.63, C:66.33, N:8.91. Found: H:6.48, C:66.39, N:8.42.

[0257] .sub.eff (Evans' method, C.sub.6H.sub.6, 293.5 K)=4.9 .sub.B.

[0258] X-ray structure of 14 is presented in FIG. 1C, and its experimental details is presented in Table 3. XRD analysis of 14 showed a tetrahedral geometry with a dearomatized pyridine ligand. The solution magnetic moment of 4.9 s and a broad X-band EPR signals with effective g-value of 6.9 support the formation of a S=2, Fe(II) complex. Addition of 1.4 equiv of BPh.sub.3 to the DMAP complex 14 in C.sub.6D.sub.6 quantitatively regenerated 9 along with the formation of DMAP-BPh.sub.3 adduct (FIG. 1B).

TABLE-US-00003 TABLE 3 XRD experimental detail for 9 and 14. 9 14 Empirical formula C62 H112 Cl2 Fe2 N2 O P2 Si4 C40 H68 Fe N3 P Si Formula weight (g/mol) 1258.43 705.88 Temperature (K) 100(2) 100(2) Wavelength () 0.71073 0.71073 Crystal system Monoclinic Monoclinic Space group P2.sub.1/c P2.sub.1/c a() a = 14.622(3) 19.3088(14) b () b = 16.267(3) 13.7666(7) c () c = 15.612(4) 31.174(2) () a = 90 90 () b = 101.476(11) 90.076(7) () g = 90 90 Volume (.sup.3) 3639.1(14) 8286.6(9) Z 2 8 Density (calculated) (Mg/m.sup.3) 1.148 1.132 Absorption coefficient (mm.sup.1) 0.618 0.461 F(000) 1356 3072 Crystal size (mm.sup.3) 0.200 0.150 0.150 0.124 0.095 0.042 Theta range for data collection () 2.663 to 25.348 3.494 to 27.483 Reflections collected 48148 81114 Independent reflections 6667 [R(int) = 0.0474] 18937 [R(int) = 0.0792] Completeness (to theta = ) 99.8% (25.242) 99.7% (25.242) Absorption correction Semi-empirical from equivalents Analytical Max. and min. transmission 0.9088 and 0.8809 0.993 and 0.981 Refinement method Full-matrix least-squares on F.sup.2 Full-matrix least-squares on F.sup.2 Data/restraints/parameters 6667/0/390 18937/0/853 Goodness-of-fit on F.sup.2 1.145 1.078 Final R indices [I > 2sigma(I)] R1 = 0.0612, wR2 = 0.1346 R1 = 0.0782, wR2 = 0.1559 R indices (all data) R1 = 0.0759, wR2 = 0.1432 R1 = 0.1234, wR2 = 0.1718 Extinction coefficient n/a n/a Largest diff. peak and hole (e .Math. .sup.3) 0.564 and 0.593 0.981 and 0.616
Formation of 9 from 14 by the Addition of BPh.sub.3:

[0259] A J. Young NMR tube was charged with 12(3.2 mg, 0.0050 mmol), and 0.5 mL CD.sub.6. To the brown solution was then added BPh.sub.3 (1.7 mg, 0.0070 mmol). The solution was mixed by shaking the tube at r.t. Upon mixing, the solution color turned dark red. .sup.1H NMR spectra taken after 5 min showed complete conversion of 14 to 9 along with formation of BPh.sub.3-DMAP adduct [H. Tobita, K. Ishiyama, Y. Kawano, S. Inomata, H. Ogino, Organometallics 17, 789 (1998)](confirmed by .sup.11B NMR).

Example 4

Polymerization of Olefins Using the Catalysts of this Invention

General Procedure for Polymerization of Olefins

[0260] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with stock solution of a catalyst (1.0 ml, 0.005 mmol), and the appropriate olefin (1 mmol). The solution was stirred for hours indicated in Table 4 below at 25 C. The reaction was quenched by addition of 1 mL THF. The polymer was washed three times with 4 mL each of pentane, and died under vacuum (<0.1 mbar) to form a white solid of polymers. In case of polymerization of exo/endo-5-trimethylsilyl-2-norbornene and 3-phenyl-cyclopropene, MeOH was used in place of THF and pentane as the product is soluble in these solvents.

TABLE-US-00004 TABLE 4 ROMP of cyclic olefins catalyzed by iron complex of the invention Entry Catalyst Olefin Polymer Time (hours) Isolated yield (%) 1 9 [00039] [00040] 12 100 2 10 [00041] [00042] 12 98 3 12 [00043] [00044] 14 98 4 11 [00045] [00046] 30 2 5 14 [00047] n.a. 23 0 6.sup. 14 [00048] [00049] 16 84 7 9 [00050] [00051] 16 53 8 9 [00052] [00053] 16 99 9 9 [00054] n.a. 16 0 R = COOEt, OH, Si(OEt).sub.3, CONH.sub.2 10 9 [00055] n.a. 65 0 11 9 [00056] [00057] 20 80 12.sup. 9 [00058] [00059] 16 100 *Catalyst (0.010 mmol) and olefin (1 mmol) were stirred in benzene (1 mL) under N.sub.2 at 25 C. Ph: phenyl, Et: ethyl. .sup.BPh.sub.3 (0.009 mmol) was added. .sup.9 (0.01 mmol), water (0.0036 mmol), norbornene (5 mmol), and benzene (5 ml) were used.

Poly(exo/endo-5-trimethylsilyl-2-norbornene) (ISiMe.SUB.3.)

##STR00060##

[0261] Off-white solid.

[0262] .sup.1H NMR (300.13 MHz, CDCl.sub.3, 293 K) 0.05 and 0.03 (9H, s, SiMe.sub.3), 0.86-2.00 (5H, br, 2CH.sub.2 and CHSiMe.sub.3), 2.36 and 2.75 (2H, br, 2CH), 5.28 (2H, br, olefinic 2CH).

Poly(exo-5-phenyl-2-norbornene) (I-Ph)

##STR00061##

[0263] Off-white solid.

[0264] .sup.1H NMR (300.13 MHz, CDCl.sub.3, 293 K) 1.3-3.5 (7H, broad peaks, 3CH and 2CH.sub.2), 5.26 (2H, br m, olefinic 2CH), 6.9-7.5 (5H, broad peaks, aromatic 5CH).

Poly(3-phenyl-cyclopropene) (poly-CP)

##STR00062##

[0265] Off-white solid. .sup.1H NMR (300.13 MHz, CDCl.sub.3, 293 K) 1.4 (5H, br, CH.sub.3 and 2CH), 6.99 (5H, br, aromatic 5CH).

[0266] When 100 equiv. of norbornene were added to a benzene solution of 9 at 25 C., an insoluble polymer formed quickly around the magnetic stirring bar. After 12 h at 25 C., the polymer was isolated in 100% yield (FIG. 3A, Table 4, entry 1). Characterization of the polymer was done in CDCl.sub.3 at 100 C. under 5 bar of N.sub.2. Based on comparison of .sup.1H and .sup.13C{.sup.1H}NMR of completely dissolved polymer with polynorbornene prepared using the Grubbs I catalyst, the polymer was determined to be a highly stereoregular ROMP polymer, I, that contains trans-CC bonds exclusively. The infrared (IR) spectrum of the bulk solid polymer also supports that I is pure trans-polynorbornene. The exclusive trans-selective olefin metathesis from cis-olefins is unprecedented, despite recent progress in stereoretentive trans-selective cross metathesis reactions. Further, .sup.1H-.sup.1H gCOSY NMR spectra of partially epoxidized I enabled to determine I as an isotactic polymer (FIG. 3C). Thus, I is an unprecedented trans-isotactic polynorbornene. The cis-syndiotactic form of I was obtained using Mo, W, or Ru catalysts, and using Mo or W catalysts the cis-isotactic form of I was obtained. The solubility of the polymer improves upon storing the polymer for ca. 2 weeks in air under ambient conditions, or under oxygen, due to partial oxidation of the CC bonds. Molecular weight determination of I by gel permeation chromatography (GPC) was not possible due to the low solubility of I in common GPC solvents. The molecular weight of I was estimated using dynamic light scattering (DLS) measurement of a chloroform solution of I and polystyrene standards. DLS measurement of I (prepared as shown in FIG. 3A) in two different dilutions, 0.058 and 0.012 mg/mL, showed monodisperse size distributions with mean hydrodynamic radii of 205.3 and 202.7 nm respectively. In comparison, DLS measurement of polystyrene standard with weight average molecular weight (M.sub.w) of 0.92510.sup.6, 6.2810.sup.6 and 12.910.sup.6 Da revealed smaller mean hydrodynamic radii of 38.1, 47.9 and 53.6 nm respectively in chloroform. Furthermore, TEM image of dried 0.058 mg/mL chloroform solution of I showed spherical molecule of I with a mean radius of 123.8 nm for the TEM detectable core part of the sphere (FIG. 3B). Thus, based on size analysis, the molecular weight of I is most likely larger than 12.910.sup.6 Da. Low polydispersity indexes of 0.089 and 0.025 were obtained based on DLS and TEM measurements, respectively.

Polymerization of Norbornene Catalyzed by 9.

##STR00063##

[0267] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with a stock solution of 9 (1.0 ml, 0.010 mmol). To the dark red solution was added solid norbornene (97.6 mg, 1.04 mmol). Polymeric material started to form around the stirring bar as soon as norbornene was added. After 12 h of stirring at 25 C., all solution solidified due to absorption of C.sub.6H.sub.6 by the product polymer. The reaction was quenched by addition of 1 mL THF. The polymer was washed three times with 4 mL each of pentane, and dried under vacuum (<0.1 mbar) to form a white solid of I. Yield: 98.2 mg, quantitative. The polymer was dissolved in trichloroethylene at 90 C., and analyzed by .sup.1H NMR and IR (thin film). The bulk polymer was grinded with KBr in the glove box and analyzed by IR (KBr pellet). .sup.13C{.sup.1H}NMR was measured using the polymer stored in air to increase solubility in CDCl.sub.3.

[0268] .sup.1H NMR (400.36 MHz, trichloroethylene (6.43 ppm with respect to TMS), 298 K): 1.11 (1H, pseudo q, J.sub.HH=10.2, 12.5 Hz, CH.sub.2), 1.40 (2H, m, CH.sub.2), 1.79 (2H, m, CH.sub.2), 1.91 (1H, m, CH.sub.2), 2.46 (2H, br, 2CH), 5.39 (2H, dd, J.sub.HH=1.7, 3.8 Hz, 2CH).

[0269] .sup.13C{.sup.1H}NMR (100.67 MHz, CDCl.sub.3, 291 K): 32.2 (CH.sub.2), 41.4 (CH.sub.2), 43.1 (CH), 133.0 (CH).

[0270] IR (KBr, thin film, cm.sup.1): 666 (s, CH.sub.2 rocking), 694 (s, olefinic trans-CH out-of-plane vibration).

[0271] IR (KBr pellet, cm.sup.1): 694 (s, olefinic trans-CH out-of-plane vibration).

Polymerization of Norbornene Catalyzed by 10.

##STR00064##

[0272] Using the same procedure described above, 91.7 mg (98% yield) of I was obtained the using stock solution of 10 (1.0 ml, 0.010 mmol) and norbornene (93.2 mg, 0.99 mmol).

Polymerization of Norbornene Using 14.

[0273] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with 14 (6.2 mg, 0.0098 mmol), and 1.0 mL C.sub.6H.sub.6. To the solution was added solid norbornene (95.9 mg, 1.02 mmol). No formation of polymer was observed upon stirring the solution for 23 h at 25 C.

Polymerization of Norbornene Using 14 and BPh.SUB.3..

[0274] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with 14 (6.0 mg, 0.0095 mmol), BPh.sub.3 (2.1 mg, 0.0087 mmol), and 1.0 mL n-pentane. The brown suspension was stirred for 5 h at r.t., filtered using Celite, and the Celite was washed with 1.0 mL n-pentane. A white powder of BPh.sub.3-DMAP complex [H. Tobita, K. Ishiyama, Y. Kawano, S. Inomata, H. Ogino, Organometallics 17, 789 (1998)](confirmed by .sup.1H and .sup.11B NMR) was collected on the Celite. The pentane solution was concentrated to dryness, and dissolved in 1.0 mL C.sub.6H.sub.6. To the solution was added solid norbornene (96.6 mg, 1.03 mmol). After 16 h of stirring at 25 C., all solution solidified due to absorption of C.sub.6H.sub.6 by the product polymer. The reaction was quenched by addition of 1 mL THF. The polymer was washed three times with 4 mL each of pentane, and dried under vacuum (<0.1 mbar) to form a white solid of I. Yield: 80.9 mg, 84%.

Oxidation of Polynorbornene (I).

[0275] Upon standing in air for ca. two weeks, the polymer became soluble in CDCl.sub.3. In a control experiment, I was kept under 2 bar of O.sub.2 for 9 days and became soluble in CDCl.sub.3. IR spectra of the oxidized polymer showed new CO stretches around 1700 cm.sup.1, however .sup.1H NMR and .sup.13C{.sup.1H}NMR did not detect structural changes resulting from exposure to air or O.sub.2.

[0276] .sup.1H NMR (400.36 MHz, CDCl.sub.3, 298 K): 1.05 (1H, pseudo q, J.sub.HH=10.7, 12.1 Hz, CH.sub.2), 1.34 (2H, m, CH.sub.2), 1.76 (2H, m, CH.sub.2), 1.86 (1H, dt, J.sub.HH=6.6, 12.3 Hz, CH.sub.2), 2.42 (2H, br, 2CH), 5.34 (2H, m, 2CH).

[0277] .sup.13C{.sup.1H}NMR (100.67 MHz, CDCl.sub.3, 291 K): 32.2 (CH.sub.2), 41.4 (CH.sub.2), 43.1 (2CH), 133.0 (2CH).

[0278] IR (KBr, thin film, cm.sup.1): 666 (w, CH.sub.2 rocking), 694 (s, olefinic trans-CH out-of-plane vibration), 1717 (s, CO stretching).

Determination of Tacticity of I. (Prepared Using Complex 9)

[0279] In a nitrogen glove box, to a NMR tube equipped with a septa were added I (1.5 mg, contains 0.016 mmol CC bonds, stored under air to increase solubility), and 0.50 mL CDCl.sub.3. The purity of I was confirmed by .sup.1H NMR before addition of meta-chloroperbenzoic acid (m-CPBA). To the solution was then added a stock solution of m-CPBA in CDCl.sub.3 (prepared using 1.5 mg of 77% m-CPBA (Aldrich)) and 0.50 mL CDCl.sub.3, 0.013 M, 0.1 mL, 0.0013 mmol). .sup.1H NMR spectra after 1 h showed epoxidation of 5% of the CC bonds in I and formation of meta-chlorobenzoic acid. .sup.1H NMR spectra showed -hydrogens of the resulting epoxide at 2.60 ppm as a pseudo triplet. Upon decoupling of -hydrogens at 1.87 ppm, the pseudo triplet signal was resolved to two broad singlet signals at 2.61 and 2.59 ppm. .sup.1H-.sup.1H-gCOSY spectra showed coupling between these two signals. Based on this observation, the tacticity of I was determined to be isotactic.

Epoxydation of I to Form Trans-Polyepoxide II.

##STR00065##

[0280] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with a chunk of I (46.2 mg, 0.5 mmol), m-CPBA (77%, 136.6 mg, 0.6 mmol), and 4 mL dichloromethane. The suspension of I was stirred for 48 h at r.t. to form a white precipitate and a colorless solution. The solution was concentrated to form a white solid. The solid was washed five times with 10 mL each of ether to remove meta-chlorobenzoic acid and excess m-CPBA. The resulting colourless oil was dried to form a colorless film. Yield: 62.7 mg, quantitative. Based on comparison of .sup.1H, and .sup.13C{.sup.1H}NMR spectra with cis/trans mixture of II (see next experiment), the polymer was assigned as an atactic trans-polyepoxide II.

[0281] .sup.1H NMR (400.36 MHz, CDCl.sub.3, 298 K): 1.20 (1H, pseudo q, CH.sub.2), 1.49 (2H, br, CH.sub.2), 1.75 (2H, br, CH.sub.2), 1.86 (3H, br, 2CH.sub.2), 2.62 (2H, br, 2CH).

[0282] .sup.13C{.sup.1H}NMR (100.67 MHz, CDCl.sub.3, 298 K): 28.0 and 28.2 (CH.sub.2), 32.1 and 32.2 (CH.sub.2), 41.16 to 41.54 (4 peaks, 2CH), 60.65 to 61.15 (4 peaks, 2CH).

[0283] IR (KBr, thin film, cm.sup.1): 730 (s, symmetric epoxide ring deformation), 892 (s, asymmetric epoxide ring deformation).

Analysis of the Reaction Solution after Polymerization.

[0284] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with a stock solution of 9 (1.0 ml, 0.010 mmol, containing 0.01 mmol of mesitylene as an internal standard). To the dark red solution was added a solid norbornene (96.0 mg, 1.02 mmol). After 16 h of stirring at 25 C., most of the solution solidified due to absorption of C.sub.6H.sub.6 by the product polymer. A part of the reaction solution was extracted by C.sub.6H.sub.6 and analyzed by .sup.1H and .sup.31P{1H}NMR. .sup.1H NMR spectra showed virtually no consumption of the complex 10 based on integration value with respect to internal standard. The polymer was washed three times with 4 mL each of pentane, and dried under vacuum (<0.1 mbar) to form a white solid of I. Yield: 95.5 mg, 99%.

Reuse of the Reaction Solution after Polymerization of Norbornene.

[0285] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with a stock solution of 9 (1.0 ml, 0.010 mmol). To the dark red solution was added solid norbornene (99.7 mg, 1.06 mmol). After 19 h of stirring at 25 C., most of the solution solidified due to absorption of C.sub.6H.sub.6 by the product polymer. The polymer was washed three times with 2 mL each of pentane, and dried under vacuum (<0.1 mbar) to form a white solid of I (96.2 mg, 96%). To the collected reaction solution in a mixture of pentane (6 mL) and C.sub.6H.sub.6(1 mL) was added solid norbornene (97.0 mg, 1.03 mmol). After 16 h of stirring at 25 C., white chunky precipitate of I was formed. The polymer was washed three times with 2 mL each of pentane, and dried under vacuum (<0.1 mbar) to form a white solid of I (108 mg, quantitative).

Example 5

Catalytic Activity of the Complexes of this Invention

[0286] The catalytic activity of compounds of formula A2 was examined. 10 and 12 showed similar catalytic activity as 9. By contrast, complex 11 formed only 2% yield of the polymer after 30 h (Table 4, entries 2-4), likely due to steric crowding around the iron center. Complex 14 was inactive towards ROMP (Table 4, entry 5). However, significantly, 14 became catalytically active upon abstraction of the DMAP ligand by the addition of 1 equiv BPh.sub.3, generating 9 and the DMAP-BPh.sub.3 adduct (Table 4, entry 6). The catalytic inactivity of 14 supports the requirement of 3-coordinate iron complexes for ROMP activity.

[0287] ROMP of other cyclic alkenes was examined using 1 mol % of 9. The SiMe.sub.3- and phenyl-functionalized norbornene were polymerized in moderate to high yields (Table 2, entry 7 and 8). The presence of oxygen or nitrogen functionality is detrimental for the catalysis (Table 4, entry 9), likely due to the coordination of these functionalities to 9 to form complexes similar to the DMAP complex 14. Peculiarly, norbornadiene did not undergo polymerization despite its structural similarity to norbornene (Table 4, entry 10). Cyclooctene and cyclopentene did not undergo polymerization, whereas the more strained cyclopropene polymerized via an addition-polymerization mechanism to generate a saturated polymer (Table 4, entry 11).

[0288] Along the course of the study, we found that addition of less than 1 equiv./iron of water to a solution of complex 9 generates a more active catalyst, whereas addition of more than 1 equiv. of water deactivates the catalyst. Thus, when 0.5 equiv. of water was added to a solution of complex 9 and 200 equiv of norbornene, turnover number (TON) of 62 was observed in 10 min, while TON of <4 was observed in 10 min without addition of water or with addition of 1.25 equiv of water. In the presence of 0.75 equiv of water, 0.1 mol % of 9 polymerized norbornene in 100% yield in 16 hours (Table 4, entry 12).

Example 6

Effect of Water on the Catalytic Activity of the Catalysts of this Invention

[0289] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with a sample of the stock solution of 9 (0.50 ml, 0.010 M in C.sub.6H.sub.6, 0.0050 mmol), appropriate amount of H.sub.2O (0.025 M in C.sub.6H.sub.6), and appropriate amount of C.sub.6H.sub.6 to maintain constant concentration of norbornene (0.50 M) in the reaction mixture between each entry. The solution was then stirred for 10 min at r.t. To the solution was then added a sample of the stock solution of norbornene (1.0 M, 1.0 mL, 1.0 mmol), and the solution was stirred for 10 min, and quenched by addition of 1 mL THF. The polymer was washed three times with 4 mL each of pentane, and dried under vacuum (<0.1 mbar) to form a white solid of I. Table 5 shows the effect of water on the catalytic activity of 9.

TABLE-US-00005 TABLE 5 Effect of water on catalytic activity of 9. entry H.sub.2O (mmol) C.sub.6H.sub.6 (mL) Yield of I (%) 1 0 0.5 2 2 0.00125 0.45 17 3 0.0025 0.4 31 4 0.00375 0.35 30 5 0.0050 0.3 7 6 0.00625 0.25 0

Example 7

Decomposition Experiment of the Catalysts of this Invention

[0290] In a nitrogen glove box, to a J. Young NMR tube was added a sample from the stock solution of 9 (0.60 ml, 0.010 M in C.sub.6H.sub.6, 0.006 mmol). The tube was then heated at 90 C. for 16 h. .sup.1H NMR showed formation of free PN ligand, however no new paramagnetic species were detected. Analysis of decomposition products by GC-MS showed formation of SiMe.sub.3OH, trans-bis(trimethylsilyl)ethene, and bis(trimethylsilyl)ethane.

Example 8

Ru Based CatalystComparative Activity

Preparation of Ru Complex, [RuCl.sub.2(PNdipp-iPr)].sub.2 (Corresponds to A2 Disclosed Herein)

##STR00066##

[0291] In a nitrogen glove box, a 50 mL Schlenk tube equipped with a Teflon coated stirring bar was charged with [RuCl.sub.2(p-cymene)].sub.2 (30.9 mg, 0.0505 mmol), PNdipp-.sup.iPr (37.5 mg, 0.101 mmol), and 3 mL CH.sub.2Cl.sub.2. The solution was stirred for 20 h at 60 C. outside the box to form a clear dark brown solution. In a nitrogen glove box, the solution was concentrated to dryness and dissolved in 4 mL C.sub.6H.sub.6. The clear dark brown solution was then stirred for 2 weeks at 90 C. outside the box to form a dark brown suspension. In a nitrogen glove box, the suspension was passed through Celite using C.sub.6H.sub.6 to obtain a clear brown solution and dark brown solid. The solid was washed with C.sub.6H.sub.6, and extracted by CH.sub.2Cl.sub.2. Concentration of the extract gave the Ru complex[RuCl.sub.2(PNdipp-iPr)].sub.2 as a dark brown solid. Yield: 48.1 mg, 88%.

[0292] .sup.1H NMR (400.36 MHz, CDCl.sub.3, 298 K): 0.65 (6H, dd, .sup.3J.sub.HH=6.5 Hz, .sup.3J.sub.HP=15.7 Hz, 2PCH(CH.sub.3).sub.2), 0.85 (12H, m, 2CH(CH.sub.3).sub.2), 1.2-1.5 (30H, overlapping m, 2CH(CH.sub.3).sub.2 and 4PCH(CH.sub.3).sub.2), 2.01 (2H, septet, .sup.3J.sub.HH=6.5 Hz, 2CH(CH.sub.3).sub.2), 2.19 (2H, m, 2PCH(CH.sub.3).sub.2), 2.40 (2H, m, 2PCH(CH.sub.3).sub.2), 2.80 (2H, septet, .sup.3J.sub.HH=6.5 Hz, 2CH(CH.sub.3).sub.2), 3.23 (2H, pseudo t, CH.sub.2), 3.66 (2H, dd, .sup.2J.sub.HH=10.2 Hz, .sup.2J.sub.HP=16.2 Hz, CH.sub.2), 6.83 (2H, d, .sup.3J.sub.HH=7.2 Hz, aromatic 2CH), 7.18 (2H, m, aromatic 2CH), 7.29 (4H, overlapping with CHCl.sub.3 peak, aromatic 4CH), 7.40 (2H, d, .sup.3J.sub.HH=8.5 Hz, aromatic 2CH), 7.52 (2H, br t, .sup.3J.sub.HH=7.5 Hz aromatic 2CH).

[0293] .sup.13C{.sup.1H}NMR (100.67 MHz, CDCl.sub.3, 298 K): 17.5 (s, PCH(CH.sub.3).sub.2), 17.8 (d, .sup.2J.sub.CP=7.0 Hz, PCH(CH.sub.3).sub.2), 19.1 (s, PCH(CH.sub.3).sub.2), 20.2 (s, PCH(CH.sub.3).sub.2), 21.8 (s, CH(CH.sub.3).sub.2), 22.6 (s, CH(CH.sub.3).sub.2), 24.1 (d, .sup.1J.sub.CP=29.9 Hz, 2PCH(CH.sub.3).sub.2), 26.4 (s, CH(CH.sub.3).sub.2), 26.7 (s, CH(CH.sub.3).sub.2), 30.2 (d, .sup.1J.sub.CP=29.2 Hz, 2PCH(CH.sub.3).sub.2), 30.6 (s, 2CH(CH.sub.3).sub.2), 30.8 (s, 2CH(CH.sub.3).sub.2), 32.5 (d, .sup.1J.sub.CP=24.2 Hz, CH.sub.2), 120.1 (d, .sup.3J.sub.CP=10.0 Hz, aromatic), 122.4 (s, aromatic), 123.3 (s, aromatic), 124.9 (s, aromatic), 129.3.6 (s, aromatic), 132.3 (s, aromatic), 135.3 (s, aromatic, ipso), 148.2 (s, aromatic, ipso), 148.7 (s, aromatic, ipso), 165.4 (s, aromatic, ipso), 166.3 (s, aromatic, ipso).

[0294] .sup.31P{.sup.1H}NMR (121.50 MHz, CDCl.sub.3, 292 K): 125.7.

[0295] HRMS (ESI.sup.+) m/z caled for C.sub.48H.sub.72Cl.sub.4N.sub.2P.sub.2Ru.sub.2+([M].sup.+): 1082.2012. Found: 1082.1997.

[0296] Examination of the catalytic activity of [RuCl.sub.2(PNdipp-iPr)]2 towards ROMP of norbornene.

[0297] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with [RuCl.sub.2(PNdipp-iPr)].sub.2 (2.7 mg, 0.0025 mmol), trimethylsilylmethyllithium (1.0 mg, 0.011 mmol), and 0.55 mL C.sub.6D.sub.6. The solution was stirred for 15 h at 25 C. NMR analysis of the solution after 15 hours showed complete conversion of [RuCl.sub.2(PNdipp-iPr)]2 to new unidentified complex(es). To the stirred solution was then added solid norbornene (91.2 mg, 0.969 mmol) and 0.45 mL C.sub.6H.sub.6. The solution was stirred for 25 h at 25 C. No formation of polymer was observed before or after concentration of the solution.

Example 9

The Effect of the Ligand Structure of the Catalyst of This Invention

[0298] The effect of the PN ligand structure was studied by screening several FeCl.sub.2(PN) complexes. Substitution of P.sup.iPr.sub.2 group by P.sup.tBu.sub.2, PEt.sub.2, and PPh.sub.2 group, as well as substitution of the 2,6-.sup.iPr.sub.2C.sub.6H.sub.3 group by the 2,4,6-Me.sub.3C.sub.6H.sub.2 group resulted in an inactive catalyst (complex 5 and 6). Thus, fine tuning of steric and electronic factors of the ligand is essential for the catalytic activity. Significantly, a complex with CMe.sub.2P.sup.iPr group, (Complex 4) also resulted in formation of an inactive catalyst. This result indicates that dearomatization of the PN ligand is essential for the formation of active catalyst, however the inactivity can also be due to steric effect of the methyl groups as in the case of 11.

General Procedure for Screening of FeCl.SUB.2.(PN) Complexes.

[0299] In a nitrogen glov.sub.e box, a 20 mL vial equipped with .sup.a T.sub.eflon coated st.sub.irring bar was c.sub.harged with the appropriate FeCl.sub.2(PN) complex (0.05 mmol), and trimethylsi.sub.ly.sub.lm.sub.ethyllithium (0.10 mmol). 5.00 mL C.sub.6H.sub.6 was then added to the vial. The solution was stirred at r.t. for 6-19 h to form 0.01 M stock solution of the catalyst. Another 20 mL vial equipped with a Teflon coated stirring bar was charged with the stock solution of the appropriate catalyst (1.0 mL, 0.01 mmol). Solid norbornene (1.0 mmol) was then added to the vial, and the solution was stirred for 16 to 30 h. The reaction was quenched by addition of 1 mL THF. The polymer was washed three times with 4 mL each of pentane, and dried under vacuum (<0.1 mbar). Table 6 shows the catalytic activity of FeCl.sub.2(PN) complexes towards ROMP of norbornene.

TABLE-US-00006 TABLE 6 Screening of FeCl.sub.2(PN) complexes for ROMP of norbornene. entry FeCl.sub.2(PN) complexes time (h) Yield of polymer (%) 1 3 30 2 2 5 16 trace 3 6 16 trace 4 7 16 trace 5 4 12 0

Example 10

Polymerization of Norbornene in the Presence of Equimolar Amount of Styrene

##STR00067##

[0300] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with a stock solution of complex 9 (1.0 ml, 0.010 mmol), styrene (104.3 mg, 1.00 mmol), and mesitylene (119.9 mg, 0.998 mmol). To the stirred dark red solution was added solid norbornene (97.6 mg, 1.04 mmol). The vial was sealed tightly using an electrical tape and a plastic cap to avoid loss of norbornene and placed close to the magnetic stirring plate to ensure stirring of the polymer around the stirring bar. After 24 h of stirring at 25 C., viscous solution and precipitation of the polymer were obtained. An aliquot of the reaction mixture was taken to a J. Young NMR tube and diluted by ca. 0.5 mL C.sub.6H.sub.6. The .sup.1H NMR spectra of the crude mixture showed full conversion of norbornene and formation of polymer containing I, Va-Vd. Virtually no conversion of styrene was observed using mesitylene internal standard. The reaction was quenched by addition of 1 mL THF. The polymer was concentrated to dryness and washed three times with 4 mL each of n-pentane by vigorous stirring of the polymer/n-pentane suspension and dried under vacuum (<1 mbar) to form a white solid of I, Va-Vd. Yield: 88.1 mg, 90%. The polymer was completely dissolved in CDCl.sub.3 and analyzed by .sup.1H NMR at 25 C. .sup.1H NMR of the concentrated sample of I, Va-Vd is used to analyze end groups of the polymer. The identity of the end group was determined to be methylene.sup.33 and trans-phenylmethylene groups based on DOSY, .sup.1H-.sup.1H-gCOSY, and .sup.1H-.sup.1H coupling constant analysis. A thin film of the polymer for thin film IR analysis was prepared in a nitrogen glove box by depositing dichloromethane solution of I, Va-Vd on KBr disk. Stereochemistry of the polymer was determined using .sup.1H NMR, IR, and partial epoxidation of the polymer.

[0301] .sup.1H NMR of the polymer chain (500.08 MHz, CDCl.sub.3, 298 K): 1.06 (1H, pseudo q, CH.sub.2), 1.35 (2H, br, CH.sub.2), 1.77 (2H, br, CH.sub.2), 1.86 (1H, m, CH.sub.2), 2.43 (2H, br, 2CH), 5.34 (2H, br, 2CH).

[0302] .sup.1H NMR of the polymer end groups (500.08 MHz, CDCl.sub.3, 298 K): 4.86 (1H, d, .sup.3J.sub.HH=10.6 Hz, methylene CH), 4.96 (1H, d, .sup.3J.sub.HH=17.2 Hz, methylene CH), 5.79 (1H, m, methylene CH), 6.19 (1H, dd, .sup.3J.sub.HH=7.9, 15.5 Hz, trans-phenylmethyl CH), 6.35 (1H, d, .sup.3J.sub.HH=15.5 Hz, trans-phenylmethyl CH), 7.17 (1H, br t, trans-phenylmethylene aromatic CH), 7.28 (2H, overlapping with CHCl.sub.3 peak, trans-phenylmethylene aromatic 2CH), 7.34 (2H, m, trans-phenylmethylene aromatic 2CH).

[0303] Diffusion coefficient of the polymer chain (C.sub.6D.sub.6, 298 K): 3.210.sup.11 m.sup.2/s.

[0304] Diffusion coefficient of the end group (C.sub.6D.sub.6, 298 K): 7.010.sup.11 m.sup.2/s.

[0305] Diffusion coefficient of residual n-pentane (C.sub.6D.sub.6, 298 K): 2.110.sup.9 m.sup.2/s.

[0306] .sup.13C{.sup.1H}NMR (125.75 MHz, CDCl.sub.3, 298 K): 632.2 (CH.sub.2), 41.4 (CH.sub.2), 43.1 (CH), 133.0 (CH).

[0307] IR (KBr, thin film, cm.sup.1): 666 (s, CH.sub.2 rocking), 964 (s, olefinic trans-CH out-of-plane vibration).

[0308] GPC: M.sub.w=24430 Da, M.sub.n=6719 Da, =3.63.

[0309] .sup.1H, .sup.13C{.sup.1H}, .sup.1H-.sup.1H-gCOSY NMR, and IR spectra of I, Va-Vd, and, .sup.1H-.sup.1H-gCOSY NMR spectrum of partially epoxidized I, Va-Vd are shown in FIGS. 9A-9E.

Example 11

Polymerization of Norbornene in the Presence of Equimolar Amount of Styrene

##STR00068##

[0310] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with a stock solution of complex 10 (0.50 ml, 0.005 mmol, 0.05 mol %), styrene (1.0436 g, 10.0 mmol), and 4.50 mL C.sub.6H.sub.6. To the stirred pale red solution was added solid norbornene (943.0 mg, 10.0 mmol). The vial was sealed tightly using an electrical tape and a plastic cap to avoid loss of norbornene and placed close to the magnetic stirring plate to ensure stirring of the polymer around the stirring bar. After 48 h of stirring at 25 C., the reaction was quenched by the addition of 1 mL THF, and the reaction mixture was concentrated to dryness. The resulting solid was washed three times with 4 mL each of n-pentane and dried under vacuum (<1 mbar). The solid was completely dissolved in ca. 8 mL boiling CHCl.sub.3 and passed through a plug of silica gel. Concentration of CHCl.sub.3 solution gave faint yellow solid. Yield: 59.1 mg. The polymer was completely dissolved in CDCl.sub.3 and analysed by .sup.1H NMR at 25 C. .sup.1H NMR showed formation of trans-polynorbornene along with broad signals in 6.3-7.3 and 1.2-2 ppm region which indicate formation of polystyrene. The ratio of polynorbornene and polystyrene was about 1:6 based on integration of a .sup.1H NMR spectrum.

Example 12

Monitoring of M.SUB.w .of I During the Polymerization in the Presence of Styrene

##STR00069##

[0311] In a nitrogen glove box, 10.0 mL of a 0.010 M solution of Complex 10 was prepared in a 20 mL vial equipped with a Teflon coated stirring bar using 50.1 mg Complex 1, 16.2 mg LiCH.sub.2CMe.sub.3 and 10 mL C.sub.6H.sub.6 as described in Example 3. To the stirred dark red solution at 25 C. was added styrene (1.0419 g, 10.0 mmol), and then solid norbornene (952.9 mg, 10.0 mmol). The vial was sealed tightly using an electrical tape and a plastic cap to avoid loss of norbornene and placed close to the magnetic stirring plate to ensure stirring of the polymer around the stirring bar. Approximately 2 mL of the reaction mixture were taken from the vial after 5, 10, and 21 h, and the catalyst in the collected reaction mixture was quickly deactivated by adding ca. 0.5 mL THF. Aliquot (about one drop) of the collected solution was taken to an NMR tube and dissolved in 0.50 mL CDCl.sub.3. Conversions of norbornene were determined by .sup.1H NMR using styrene as internal standard (as conversion of styrene is virtually 0%). The remaining collected solutions were concentrated to dryness and dissolved in hot CHCl.sub.3 outside the glovebox. The CHCl.sub.3 solutions were passed through plug of silica gel to remove decomposed iron catalyst. Concentration of CHCl.sub.3 solutions gave colorless films of polymers I, Va-Vd. .sup.1H NMR spectra of the polymer in CDCl.sub.3 showed clean formation of I, Va-Vd. The polymers were then analysed by GPC as described below. The results of GPC analysis are summarized in Table 7.

TABLE-US-00007 TABLE 7 Summary of GPC analysis of polynorbornene (I) prepared using 1 mol % complex 10 in the presence of styrene. Reaction time (h) Conversion (%) M.sub.w (Da) M.sub.n (Da) 5 68 31850 8276 3.85 10 79 29680 7603 4.40 21 86 22800 8846 2.57 * the conversion refers to the conversion of norborene.

[0312] GPC measurement of I, prepared in the presence of styrene or 4-(diphenylphosphino)styrene.

[0313] GPC samples were prepared by stirring about 80 mg of the polymer (prepared as described above) in 1,2,4-trichlorobenzene at 160 C. Complete dissolution of the polymer was observed. Molecular weights and molecular weight dispersities () of polymers were determined by the GPC method on the Waters-Alliance 2000 instrument using three Agilent PLgel-Olexis columns (dimensions: 7.5300 mm, nominal particle size: 13 m, MW range: 2000 to 10000000 Da), DRI detector, and 1,2,4-trichlorobenzene (with 0.0125% BHT) as the mobile phase at 160 C. and flow rate of 1.00 mL/min. Narrow dispersity polystyrene standards (915000 to 580 Da) were used for the standard calibration curve of the GPC at the same temperature.

Example 13

Polymerization of Norbornene in the Presence of 4-(diphenylphosphino)styrene

##STR00070##

[0314] In a nitrogen glove box, a 20 mL vial equipped with a Teflon coated stirring bar was charged with a stock solution of Complex 10 (1.0 ml, 0.010 mmol) and 4-(diphenylphosphino)styrene (143.7 mg, 0.498 mmol). To the stirred dark red solution was added solid norbornene (94.4 mg, 1.00 mmol). The vial was sealed tightly using an electrical tape and a plastic cap to avoid loss of norbornene and placed close to the magnetic stirring plate to ensure stirring of the polymer around the stirring bar. After 40 h of stirring at 25 C., viscous solution and precipitation of the polymer were obtained. The reaction was quenched by addition of 1 mL THF. The polymer was concentrated to dryness and washed five times with 4 mL each of n-pentane by vigorous stirring of the polymer/n-pentane suspension and dried under vacuum (<1 mbar) to form a pink solid of I. Yield: 67.7 mg, 72%. The polymer was completely dissolved in CDCl.sub.3 and analysed by .sup.1H NMR at 25 C. .sup.1H NMR of the concentrated sample enable us to analyse end groups of the polymer. The identity of the end group was determined to be methylene and trans-phenylmethylene groups based on .sup.1H-.sup.1H-gCOSY, and .sup.31P{.sup.1H}NMR analysis. Stereochemistry of the polymer was determined by comparing .sup.1H, .sup.13C{.sup.1H}NMR, and IR spectra with those of trans, isotactic I prepared in the absence of 4-(diphenylphosphino)styrene (m.sub.5 in the scheme is as defined for m.sub.1).

[0315] .sup.1H NMR of the polymer chain (500.13 MHz, CDCl.sub.3, 298 K): 1.05 (1H, pseudo q, CH.sub.2), 1.35 (2H, br, CH.sub.2), 1.76 (2H, br, CH.sub.2), 1.86 (1H, br m, CH.sub.2), 2.42 (2H, br, 2CH), 5.34 (2H, br, 2CH).

[0316] .sup.1H NMR of the polymer end groups (500.13 MHz, CDCl.sub.3, 298 K): 4.86 (1H, d, .sup.3J.sub.HH=9.50 Hz, methylene CH), 4.96 (1H, d, .sup.3J.sub.HH=16.5 Hz, methylene CH), 5.79 (1H, m, methylene CH), 6.23 (1H, dd with roofing, .sup.3J.sub.HH=7.8, 15.5 Hz, trans-4-(diphenylphosphino)phenylmethylene CH), 6.34 (1H, d, .sup.3J.sub.HH=15.5 Hz, trans-4-(diphenylphosphino)phenylmethylene CH), 7.23-7.32 (br, overlapping with CHCl.sub.3 peak, trans-4-(diphenylphosphino)phenylmethylene aromatic CH).

[0317] .sup.13C{.sup.1H}NMR (125.75 MHz, CDCl.sub.3, 298 K): 32.2 (CH.sub.2), 41.4 (CH.sub.2), 43.1 (CH), 133.0 (CH).

[0318] .sup.31P{.sup.1H}NMR (202.46 MHz, CDCl.sub.3, 298 K): 6.06 (PPh.sub.2).

[0319] IR (KBr, thin film, cm.sup.1): 964 (s, olefinic trans-CH out-of-plane vibration).

[0320] GPC: M.sub.w=18758 Da, M.sub.n=5656 Da, =3.30.

Example 14

Trapping of Iron-Carbene Intermediate by 2-chlorostyrene

##STR00071##

[0321] In a nitrogen glove box, to a 20 mL vial equipped with a Teflon coated magnetic stirring bar was weighed 2-chlorostyrene (28.9 mg, 0.209 mmol). Complex 12 (2.0 mL, 0.010 M C.sub.6H.sub.6 solution, 0.020 mmol) and norbornene (27.8 mg, 0.295 mmol) were then added to the vial. The solution was stirred for 48 h and concentrated to dryness. The product was extracted with n-pentane, passed through Celite, and concentrated to ca. 0.1 mL. XRD quality of crystals of 50 were formed upon keeping the solution at 28 C. XRD measurement showed formation of 50. Polynorbornene I (14.2 mg, 51% yield) was obtained in this procedure.

Example 15

Trapping of Iron-Carbene Intermediate by 2,3,4,5,6-pentafluorostyrene

##STR00072##

[0322] In a nitrogen glove box, to a J. Young NMR tube containing complex 12 (0.020 mmol, prepared using 11.0 mg complex 8 and 4.1 mg LiCH.sub.2SiMe.sub.3 in 0.7 mL C.sub.6D.sub.6) were added 2,3,4,5,6-pentafluorostyrene (50.9 mg, 0.262 mmol) and norbornene (45.8 mg, 0.486 mmol). The solution was left for 70 h at 25 C. .sup.1H NMR analysis of the resulting red solution showed formation of new paramagnetic species and conversion of most of complex 12. Small amount of insoluble polymer was observed. C.sub.6D.sub.6 was evaporated and the product was extracted with n-pentane, passed through Celite, and concentrated to ca. 0.1 mL. XRD quality of red crystals of 30 were formed upon keeping the solution at 35 C. XRD measurement showed formation of 30.

[0323] While certain features of the invention have been illustrated and described herein, many modifications, substitutions, changes, and equivalents will now occur to those of ordinary skill in the art. It is, therefore, to be understood that the appended claims are intended to cover all such modifications and changes as fall within the true spirit of the invention.