Aqueous binder compositions with reduced rates of salt precipitation are described. The compositions may include a carbohydrate and a sequestrant for sequestering one or more multivalent ions (e.g., Ca.sup.2+, Mg.sup.2+, Ba.sup.2+, Al.sup.3+, Fe.sup.2+, Fe.sup.3+, etc.). The sequestrant reduces a precipitation rate for the multivalent ions from the aqueous binder composition. Methods of reducing salt precipitation from a binder composition are also described. The methods may include the steps of providing an aqueous binder solution having one or more carbohydrates. They may also include adding a sequestrant for one or more multivalent ions to the aqueous binder solution. The sequestrant reduces a precipitation rate for the multivalent ions from the binder composition.

The present invention relates to a thermosetting binder composition containing water and a water-soluble oligomeric ester of at least one saccharide chosen from reducing sugars, non-reducing sugars and hydrogenated sugars, the hydrogenated sugars being chosen from the group consisting of erythritol, arabitol, xylitol, sorbitol, mannitol, iditol, maltitol, isomaltitol, lactitol, cellobitol, palatinitol, maltotritol and hydrogenation products of hydrolyzates of starch or of lignocellulose materials, and of at least one polycarboxylic acid, the binder composition having a dry matter content of between 50% and 80% by weight, the water-soluble oligomeric ester representing at least 80% by weight, preferably at least 90% by weight, of the cry matter content of the thermosetting binder composition, and the thermosetting binder composition containing less than 10% by weight, preferably less than 5% by weight, with respect to its dry matter content, of free sorbitol. It also relates to the use of such a binder composition for the manufacture of a product based on mineral or organic fibers which are bonded by an insoluble organic binder.

The present invention relates to a thermosetting binder composition containing water and a water-soluble oligomeric ester of at least one saccharide chosen from reducing sugars, non-reducing sugars and hydrogenated sugars, the hydrogenated sugars being chosen from the group consisting of erythritol, arabitol, xylitol, sorbitol, mannitol, iditol, maltitol, isomaltitol, lactitol, cellobitol, palatinitol, maltotritol and hydrogenation products of hydrolyzates of starch or of lignocellulose materials, and of at least one polycarboxylic acid, the binder composition having a dry matter content of between 50% and 80% by weight, the water-soluble oligomeric ester representing at least 80% by weight, preferably at least 90% by weight, of the cry matter content of the thermosetting binder composition, and the thermosetting binder composition containing less than 10% by weight, preferably less than 5% by weight, with respect to its dry matter content, of free sorbitol. It also relates to the use of such a binder composition for the manufacture of a product based on mineral or organic fibers which are bonded by an insoluble organic binder.

The present invention relates to a thermosetting binder composition containing water and a water-soluble oligomeric ester of at least one saccharide chosen from reducing sugars, non-reducing sugars and hydrogenated sugars, the hydrogenated sugars being chosen from the group consisting of erythritol, arabitol, xylitol, sorbitol, mannitol, iditol, maltitol, isomaltitol, lactitol, cellobitol, palatinitol, maltotritol and hydrogenation products of hydrolyzates of starch or of lignocellulose materials, and of at least one polycarboxylic acid, the binder composition having a dry matter content of between 50% and 80% by weight, the water-soluble oligomeric ester representing at least 80% by weight, preferably at least 90% by weight, of the cry matter content of the thermosetting binder composition, and the thermosetting binder composition containing less than 10% by weight, preferably less than 5% by weight, with respect to its dry matter content, of free sorbitol.

It also relates to the use of such a binder composition for the manufacture of a product based on mineral or organic fibers which are bonded by an insoluble organic binder.

The present invention relates to a thermosetting binder composition containing water and a water-soluble oligomeric ester of at least one saccharide chosen from reducing sugars, non-reducing sugars and hydrogenated sugars, the hydrogenated sugars being chosen from the group consisting of erythritol, arabitol, xylitol, sorbitol, mannitol, iditol, maltitol, isomaltitol, lactitol, cellobitol, palatinitol, maltotritol and hydrogenation products of hydrolyzates of starch or of lignocellulose materials, and of at least one polycarboxylic acid, the binder composition having a dry matter content of between 50% and 80% by weight, the water-soluble oligomeric ester representing at least 80% by weight, preferably at least 90% by weight, of the cry matter content of the thermosetting binder composition, and the thermosetting binder composition containing less than 10% by weight, preferably less than 5% by weight, with respect to its dry matter content, of free sorbitol.

It also relates to the use of such a binder composition for the manufacture of a product based on mineral or organic fibers which are bonded by an insoluble organic binder.

A fiber structure for a fiber-reinforced composite material includes a section in which a width varies continuously along a central axis in a plan view. In a section in which the width increases continuously along the central axis, discontinuous fibers are aligned radially along the central axis, and both a thickness of the fiber structure and a density of the discontinuous fibers are uniform.

A fiber structure for a fiber-reinforced composite material includes a section in which a width varies continuously along a central axis in a plan view. In a section in which the width increases continuously along the central axis, discontinuous fibers are aligned radially along the central axis, and both a thickness of the fiber structure and a density of the discontinuous fibers are uniform.

Aqueous binder compositions with reduced rates of salt precipitation are described. The compositions may include a carbohydrate and a sequestrant for sequestering one or more multivalent ions (e.g., Ca.sup.2+, Mg.sup.2+, Ba.sup.2+, Al.sup.3+, Fe.sup.2+, Fe.sup.3+, etc.). The sequestrant reduces a precipitation rate for the multivalent ions from the aqueous binder composition. Methods of reducing salt precipitation from a binder composition are also described. The methods may include the steps of providing an aqueous binder solution having one or more carbohydrates. They may also include adding a sequestrant for one or more multivalent ions to the aqueous binder solution. The sequestrant reduces a precipitation rate for the multivalent ions from the binder composition.

Aqueous binder compositions with reduced rates of salt precipitation are described. The compositions may include a carbohydrate and a sequestrant for sequestering one or more multivalent ions (e.g., Ca.sup.2+, Mg.sup.2+, Ba.sup.2+, Al.sup.3+, Fe.sup.2+, Fe.sup.3+, etc.). The sequestrant reduces a precipitation rate for the multivalent ions from the aqueous binder composition. Methods of reducing salt precipitation from a binder composition are also described. The methods may include the steps of providing an aqueous binder solution having one or more carbohydrates. They may also include adding a sequestrant for one or more multivalent ions to the aqueous binder solution. The sequestrant reduces a precipitation rate for the multivalent ions from the binder composition.

Embodiments of the present invention include a grafted aqueous carboxymethyl cellulose (CMC) binder comprising CMC chemically bonded with a monomer, where the CMC has a weight ratio of water to CMC of from about 99.9:0.1 to about 1,000:500, wherein the monomer is characterized by a weight ratio of monomer to CMC of from about 1:1 to about 1:1,000, and non-woven fabrics and articles including CMC binders, and methods of manufacture of the same. Aspects of the invention include a method of synthesizing a grafted aqueous carboxymethyl cellulose (CMC), the method comprising: contacting CMC with water to form a CMC solution. contacting the CMC solution with an initiator; contacting the CMC solution with a monomer to start grafting polymerization reaction between the CMC and a monomer. In some embodiments, the binder and non-woven fabrics including the same are non-toxic and biodegradable.