D06P1/6428

INK SET

An ink set includes a combination of: a first ink composition containing a white pigment, and an alkali-soluble resin having an acid value of 200 mgKOH/g or higher or a crosslinked product thereof, which accounts for 1.0% by mass or more in the first ink composition, and further containing water; and a second ink composition to be printed over a printing layer constituted by the first ink composition, containing a colored pigment, and an alkali-soluble resin having an acid value of 200 mgKOH/g or higher or a crosslinked product thereof, which accounts for 1.0% by mass or more in the second ink composition, and further containing an amphoteric surfactant, a water-dispersible resin, and water. The ink set is intended to achieve good printability even when a volatile acid is used in a pretreatment solution for the ink set.