An additive for lubricating oil may include a phosphite ester compound (A) having a specific structure and a phosphite ester compound (B) having a specific structure, wherein the (A):(B) mass ratio of the phosphite ester compound (A) to the phosphite ester compound (B) is in a range of from 99:1 to 80:20. Such an additive may be provided to a lubricating oil, capable of imparting wear resistance and demulsibility with respect to a base oil for lubricating oil, and to impart durability even in the presence of water.

A lubricating composition includes at least one base oil, at least one borated dispersant, at least two antioxidants selected from amine antioxidants, phenolic antioxidants substituted with one or more linear or branched alkyl groups having from 1 to 30 carbon atoms, and mixtures thereof, and at least one phosphite polymer having the formula (I) wherein: each of the R.sup.1, R.sup.2, R.sup.3 and R.sup.4 can be independently selected from the C1-C20 alkyl, C3-C22 alkenyl, C6-C40 cycloalkyl, C7-C40 cycloalkenyl, C1-20 methoxy alkyl glycol ethers and YOH groups; Y is selected from C2-C40 alkylene, C2-C40 alkyl lactone, R.sup.7N(R.sup.8)R.sup.9 groups, in which R.sup.7, R.sup.8 and R.sup.9 are independently selected from hydrogen, C1-C20 alkyl, C3-C22 alkenyi, C6-C40 cycloalkyl, C7-C40 cycloalkenyl, C1-20 methoxy alkyl glycol ethers; m is an integer from 2 to 100; n is an integer from 1 to 1000.

Disclosed is a lubricating oil composition comprising an oil of lubricating viscosity and an oil soluble synergistic mixture of antioxidants, said mixture comprising: a) a hindered amine antioxidant according to formula (I) ##STR00001## wherein each R.sup.1 is independently selected from a substituted or unsubstituted, branched or linear, C.sub.1-C.sub.20 hydrocarbyl group; R.sup.2 is selected from the group consisting of a hydrogen atom or a, substituted or unsubstituted, branched or linear, C.sub.1-C.sub.20 hydrocarbyl group; each R.sup.3 is independently selected from the group consisting of a hydrogen atom or a, substituted or unsubstituted, branched or linear, C.sub.1-C.sub.20 hydrocarbyl group; each R.sup.4 is independently selected from the group consisting of a hydrogen atom or a, substituted or unsubstituted, branched or linear, C.sub.1-C.sub.20 hydrocarbyl group; n is an integer from 1 to 4; and m is an integer from 1 to 5; and b) a molybdenum succinimide complex.

The present invention relates to an antiwear agent and lubricating compositions thereof. The invention further provides for a method of lubricating a driveline device application by employing a lubricating composition containing the antiwear agent.

The present invention relates to novel aminobisphosphonate compounds useful as antiwear and/or friction modifier additive components, lubricant additive compositions and lubricant compositions each comprising such compounds, and methods for making and using the same.

The present invention relates to a refrigerant composition, including difluoromethane (HFC-32), pentafluoroethane (HFC-125), and trifluoroiodomethane (CF.sub.3I) for use in a heat exchange system, including air conditioning and refrigeration applications and in particular aspects to the use of such compositions as a replacement of the refrigerant R-410A for heating and cooling applications and to retrofitting heat exchange systems, including systems designed for use with R-410A.

A composition having a compound having the structure:

##STR00001##

wherein each R is an independently selected alkylphenol-free moiety that is a C.sub.1-20 alkyl, C.sub.2-22 alkenyl, C.sub.6-40 cycloalkyl, C.sub.7-40 cycloalkylene, C.sub.3-20 methoxy alkyl glycol ether, C.sub.3-20 alkyl glycol ether, or YOH moiety; wherein each Y is an independently selected alkylphenol-free moiety that is a C.sub.2-40 alkylene, C.sub.7-40 cycloalkylene, or C.sub.3-40 alkyl lactone moiety; wherein m is an integer ranging from 1 to 100; and wherein x is an integer ranging from 1 to 1000.

The invention is directed to a zinc-free lubricating composition for an internal combustion engine containing a phosphorus anti-wear agent, an ashless antioxidant, and a metal-free basic detergent. The lubricating composition provides wear protection, deposit control, and improved acid control with reduced levels of metal-containing additives.

A lubricating oil composition includes: a lubricating base oil; a component (A) that is a metal detergent having a base value of less than 100 mgKOH/g; a component (B) that is a metal detergent having a base value of 100 mgKOH/g or more; a component (C) that is a tertiary amine represented by a formula (1) below, ##STR00001##
in which R.sup.1 is a hydrocarbon group having 4 carbon atoms or more, and R.sup.2 and R.sup.3 each are a hydrocarbon group having 4 carbon atoms or less; and a component (D) that is at least one of acid phosphate and acid phosphite.

A metal surface coating composition including a high-consistency material containing a lubricant base oil and an amide compound, and a composition of a phosphorus compound containing one or more compounds represented by the below formulae and a metal, wherein the ratio (a/b) of the number of amide groups (a) and the number of acidic groups (b) is within a range of 1.1 to 6.0:

##STR00001## where X.sup.1 to X.sup.7 represent an oxygen atom or a sulfur atom, R.sup.11 to R.sup.13 represent a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms, wherein at least one of them is a hydrocarbon group having 1 to 30 carbon atoms, and R.sup.14 to R.sup.16 represent a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms wherein at least one of them is a hydrocarbon group having 1 to 30 carbon atoms.